Chemistry in Context
Chemistry in Context
8th Edition
ISBN: 9780073522975
Author: American Chemical Society
Publisher: McGraw-Hill Education
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Chapter 11.4, Problem 11.8CT

(a)

Interpretation Introduction

Interpretation:

The major component is whether likely to be safflower oil, canola oil, or soybean oil has to be identified and explained.

Concept introduction:

Fats are triglycerides made up of one glycerol molecule and three fatty acid molecules. They are also considered as the hydrophobic substances which are soluble in the organic solvents and insoluble in water.

Saturated fats are the one which contain saturated fatty acids in it and it cannot be hydrogenated.

Unsaturated fats are the one which contain unsaturated fatty acids in it and it can be hydrogenated further.

(b)

Interpretation Introduction

Interpretation:

Vitamin E is whether a part of the oil itself oran added component has to be given.

Concept introduction:

According to the solubility, vitamins can be classified into two:

  • • Water soluble vitamin
  • • Fat soluble vitamin

Water soluble vitamin:

  • • Found in the aqueous environment inside the cells.
  • • They have OH,COOH or other polar groups which make them water soluble.
  • • Some water soluble vitamins are incorporated into coenzymes.

Fat-soluble vitamin:

  • • Mainly they are stored in the body’s fat deposits.
  • • Vitamins A, D, E and K are examples.
  • • Over dose of these vitamins is hazardous since they accumulate in body fats.

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What are the IUPAC Names of all the compounds in the picture?
1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)
19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Chapter 11 Solutions

Chemistry in Context

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