
Interpretation:
The difference between monoatomic and polyatomic ion with example
Concept introduction:
The atoms lose electrons or gain electrons to form ion. Based on the number of atoms present in the ions it is monatomic or polyatomic. Both of these carry charges and can be cation or anion. Both of these forms ionic compounds due to electrostatic forces of attraction between the oppositely charged ions.

Answer to Problem 35SSC
The difference between monoatomic and polyatomic is that monoatomic ions has single atoms while polyatomic ions have more than one atom.
Explanation of Solution
A monoatomic ion is formed when the atom gains or loses electrons. But it will display a net charge as the balance between the number of electrons and number of protons are not balanced. In other words, when comparing with neutral atom, there are extra electrons or less number of electrons resulting in negatively or positively charged ions.
Example: Chlorine in its neutral state has
Cl + e− → Cl−17 electrons 18 electrons17 protons 17 protons
It can be seen that chlorine initially had 17 electrons and after gaining 1 electron will have 18 electrons though the number of protons are the same. But as Chloride ion has extra electron, it has net charge of -1.
A polyatomic ion is formed when group of covalently bonded atoms carries a net charge as there is no balance of charges between the number of protons and number of electrons.
The net charge is equal to the sum of the charges of individual ions present in the molecule.
Example: Hydroxide is polyatomic ion having two atoms, Hydrogen and Oxygen. It is bonded by covalent bond as there is sharing of electrons between oxygen and hydrogen. But, there are three lone pairs of electrons in oxygen. Considering the net charge for hydroxide ion, OH− it is -1.
Differences between Monatomic and Polyatomic ions
Monatomic | Polyatomic |
It is composed of single atom per ion | It is composed of several atoms per ion |
It is formed by the loss or gain of electrons present in outer shell | It is formed by covalent bonds between several atoms |
It does no form any |
It is formed covalent bonds |
Example: Chloride ion, Bromide ion, etc | Example: Hydroxide ion, Nitrate ion, etc |
The difference between monoatomic and polyatomic is that monoatomic ions has single atoms while polyatomic ions have more than one atom.
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Glencoe Chemistry: Matter and Change, Student Edition
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