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- ol de C 3. Caffeine is an alkaloid, meaning alkali- or base-like. Circle functional groups in the molecule which would make react as a base. CH3 CH3 a. O b. O 4. Write the equations that account for what happens in the hydrolysis of acetamide O || (CH₂C-NH₂) in (a) acid and in (b) base. woled mode) N I T CH3 H Caffeine custom page 1142. State the name of each of the following reactions (acid/base, Lewis acid/base, resolution, epimerization) and draw the products of each reaction. a. Name b. Name C. H₂C. Br Name OH OH OH Racemic mixture CI + NH3 1. 2. Crystallization 3. Separation 4. Neutralization Product 1 Container 1 Product 2 Container 24. For the following question please consider the four chemicals shown below. Me H2N s, NH2 acetaldehyde Chemical 1 methanamine Chemical 2 S-methyl ethanethioate Chemical 3 ethanamine Chemical 4 Chemical 4 will readily react with two other chemicals above. a. What are those two chemicals? b. Provide a chemical structure of formed products along with a probable mechanism using the arrow formalism. c. At which of the following pH's (out of 1,7,14) do you expect each reaction to occur? Why?
- In the space provided, draw the predominant product (including stereochemistry) of the following reaction. (Ph),P- OCH3 HO H НО H. HO HDraw the structure for the principal neutral organic product of the given reaction. Be sure to show stereochemistry when applicable. Br 1. excess NaNH,.NH, Br Br Br 2.H₂ODraw the structure of the product of the reaction between the compound shown below and H,SO. CH3COCH2CH3 • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • If the reaction involves proton transfer, draw the products in separate sketchers. • If the reaction is a Lewis acid-base reaction, draw the product in one sketcher only. CP opy aste 翻 券 網
- Give a complete arrow-pushing mechanism for the following reactions. Show all important resonance structures of the intermediates and show exactly where each proton comes from and goes to. Indicate the Lewis acid and Lewis base (LA or LB) and whether they are also Bronsted acids and bases (BA or BB) for each intermolecular reaction. To preview image Click Here EtOH HCI (cat.) 0 LOEt OEt + H₂OGive the product of the followingChoose a reagent from the table to bring about the following conversion: OHO Br (If more than one step is required, enter the reagents in the order that they are to be used. If more than one answer is possible, just give one.) Reagents available a. NBS, CH₂Cl2, light b. FeBr3 / THF c. HBr, dark e. Br2, CH₂Cl₂2 f. BrCH₂ CH3 d. NBr, acetone g. BBr3 h. NaCl, NaBr, H₂O i. HBr, peroxides Reagent = e