Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Question
Chapter 22, Problem 8RQ
(I)
Interpretation Introduction
Interpretation: The answers of various questions based upon reactions in aliphatic and
Concept introduction: The organic compounds containing carbon and hydrogen are known as hydrocarbons. They can be further classified as saturated and
To determine: The answers of various questions based upon reactions in aliphatic and aromatic compounds.
(a)
Interpretation Introduction
Interpretation: The answers of various questions based upon reactions in aliphatic and aromatic compounds are to be stated.
Concept introduction: The organic compounds containing carbon and hydrogen are known as hydrocarbons. They can be further classified as saturated and unsaturated hydrocarbons. Saturated hydrocarbons contain only single bond between atoms while unsaturated hydrocarbons contains double or triple bonds between the atoms of the molecule.
To determine: An example that illustrate the formation alcohol by addition of water to an
(b)
Interpretation Introduction
Interpretation: The answers of various questions based upon reactions in aliphatic and aromatic compounds are to be stated.
Concept introduction: The organic compounds containing carbon and hydrogen are known as hydrocarbons. They can be further classified as saturated and unsaturated hydrocarbons. Saturated hydrocarbons contain only single bond between atoms while unsaturated hydrocarbons contains double or triple bonds between the atoms of the molecule.
To determine: An example that illustrates the oxidation of primary alcohols to
(c)
Interpretation Introduction
Interpretation: The answers of various questions based upon reactions in aliphatic and aromatic compounds are to be stated.
Concept introduction: The organic compounds containing carbon and hydrogen are known as hydrocarbons. They can be further classified as saturated and unsaturated hydrocarbons. Saturated hydrocarbons contain only single bond between atoms while unsaturated hydrocarbons contains double or triple bonds between the atoms of the molecule.
To determine: An example that illustrates the oxidation of secondary alcohols to
(d)
Interpretation Introduction
Interpretation: The answers of various questions based upon reactions in aliphatic and aromatic compounds are to be stated.
Concept introduction: The organic compounds containing carbon and hydrogen are known as hydrocarbons. They can be further classified as saturated and unsaturated hydrocarbons. Saturated hydrocarbons contain only single bond between atoms while unsaturated hydrocarbons contains double or triple bonds between the atoms of the molecule.
To determine: An example illustrating the reaction of an alcohol with a carboxylic acid.
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Students have asked these similar questions
1. Which of the following formulas is incorrect?a. CaNO3b. MgSc. AlBr3d. Li2Oe. NaOH
2. Part of an organic molecule where most of its chemical reactions occur.a. Substrateb. Productc. Reactantsd. Functional Group
3. An acyclic unsaturated hydrocarbon that contains one or more carbon-carbon triple bonds. As the family name alkyne indicates the characteristics ending associated with a triple bond. It has a general formula of one triple bond is CnH2n-2.a. Alkenesb. Alkynesc. Aromatic compoundd. Cycloalkane
Alkenes and alkynes react similarly to each other. Hydrogenation,
halogenation, and hydration reactions are all types of addition
reactions in which the reagent adds across the multiple bond of the
reactant
• Hydrogenation is the addition of hydrogen gas in the
presence of a catalyst such as platinum, palladium, or
nickel.
• Halogenation involves a reaction with a halogen such as
Cl₂ or Br₂ to produce a dihaloalkane or dihaloalkene
product.
Hydration reactions take place when alkenes or alkynes
react with water in the presence of a strong acid catalyst
to yield an alcohol.
▼
Part A
Predict the product of the reaction of 1-butene with bromine.
Enter the IUPAC name.
▸ View Available Hint(s)
Submit
▾ Part B
An alkyne undergoes hydrogenation to produce an alkane as follows:
04
RC=CR + 2H₂
Q
Pd
catalyst
alkane
Predict the product and draw it.
Draw the molecule by placing atoms on the grid and connecting them with bonds. Include all hydrogen atoms. To add an R group, double click an
while…
Is the reaction between an alkene and a halogen a substitution reaction or some other reaction? Explain the reaction mechanism by giving an example.
Chapter 22 Solutions
Chemistry
Ch. 22 - What is a hydrocarbon? What is the difference...Ch. 22 - Prob. 2RQCh. 22 - What are aromatic hydrocarbons? Benzene exhibits...Ch. 22 - Summarize the nomenclature rules for alkanes,...Ch. 22 - What functional group distinguishes each of the...Ch. 22 - Distinguish between isomerism and resonance....Ch. 22 - Prob. 7RQCh. 22 - Prob. 8RQCh. 22 - Prob. 9RQCh. 22 - Prob. 10RQ
Ch. 22 - Prob. 11RQCh. 22 - Describe the structural differences between DNA...Ch. 22 - Prob. 1QCh. 22 - Prob. 2QCh. 22 - Prob. 3QCh. 22 - Prob. 4QCh. 22 - Prob. 5QCh. 22 - Prob. 6QCh. 22 - Prob. 7QCh. 22 - Give an example reaction that would yield the...Ch. 22 - Prob. 9QCh. 22 - Prob. 10QCh. 22 - Prob. 11QCh. 22 - Prob. 12QCh. 22 - Is the primary, secondary, or tertiary structure...Ch. 22 - Prob. 14QCh. 22 - Prob. 15ECh. 22 - Prob. 16ECh. 22 - Draw all the structural isomers for C8H18 that...Ch. 22 - Draw all the structural isomers for C8H18 that...Ch. 22 - Prob. 19ECh. 22 - Prob. 20ECh. 22 - Draw the structural formula for each of the...Ch. 22 - Prob. 22ECh. 22 - Prob. 23ECh. 22 - Name each of the following cyclic alkanes, and...Ch. 22 - Prob. 25ECh. 22 - Draw the structures for two examples of...Ch. 22 - Name each of the following alkenes. a. CH2 = CH ...Ch. 22 - Name each of the following alkenes or alkynes. a....Ch. 22 - Prob. 29ECh. 22 - Give the structure for each of the following. a....Ch. 22 - Prob. 31ECh. 22 - Cumene is the starting material for the industrial...Ch. 22 - Name each of the following. a. b. CH3CH2CH2CCl3 c....Ch. 22 - Prob. 34ECh. 22 - There is only one compound that is named...Ch. 22 - Prob. 36ECh. 22 - Prob. 37ECh. 22 - Prob. 38ECh. 22 - Draw all the structural isomers of C5H10. Ignore...Ch. 22 - Prob. 40ECh. 22 - Draw all the structural and geometrical (cistrans)...Ch. 22 - Draw all the structural and geometrical (cistrans)...Ch. 22 - Draw all structural and geometrical (cistrans)...Ch. 22 - Prob. 44ECh. 22 - Prob. 45ECh. 22 - Prob. 46ECh. 22 - Prob. 47ECh. 22 - Prob. 48ECh. 22 - If one hydrogen in a hydrocarbon is replaced by a...Ch. 22 - There are three isomers of dichlorobenzene, one of...Ch. 22 - Identify each of the following compounds as a...Ch. 22 - Prob. 52ECh. 22 - Mimosine is a natural product found in large...Ch. 22 - Minoxidil (C9H15N5O) is a compound produced by...Ch. 22 - For each of the following alcohols, give the...Ch. 22 - Prob. 56ECh. 22 - Prob. 58ECh. 22 - Prob. 59ECh. 22 - Prob. 60ECh. 22 - Prob. 61ECh. 22 - Prob. 62ECh. 22 - Prob. 63ECh. 22 - Prob. 64ECh. 22 - Prob. 65ECh. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - Prob. 71ECh. 22 - Prob. 72ECh. 22 - Prob. 73ECh. 22 - Prob. 74ECh. 22 - Prob. 75ECh. 22 - Prob. 76ECh. 22 - Prob. 77ECh. 22 - Prob. 78ECh. 22 - Super glue contains methyl cyanoacrylate, which...Ch. 22 - Prob. 80ECh. 22 - Prob. 81ECh. 22 - Prob. 82ECh. 22 - Prob. 83ECh. 22 - Prob. 84ECh. 22 - Prob. 85ECh. 22 - Prob. 86ECh. 22 - Prob. 87ECh. 22 - Prob. 88ECh. 22 - Prob. 89ECh. 22 - Prob. 90ECh. 22 - Aspartame, the artificial sweetener marketed under...Ch. 22 - Prob. 92ECh. 22 - Prob. 93ECh. 22 - Draw the structures of the tripeptides glyalaser...Ch. 22 - Prob. 95ECh. 22 - Prob. 96ECh. 22 - Prob. 97ECh. 22 - In general terms, what does the tertiary structure...Ch. 22 - Give an example of amino acids that could give...Ch. 22 - What types of interactions can occur between the...Ch. 22 - Prob. 101ECh. 22 - Prob. 102ECh. 22 - Prob. 103ECh. 22 - Prob. 104ECh. 22 - Prob. 105ECh. 22 - Prob. 106ECh. 22 - Prob. 107ECh. 22 - Prob. 108ECh. 22 - Prob. 109ECh. 22 - Prob. 110ECh. 22 - Prob. 111ECh. 22 - Prob. 114ECh. 22 - Prob. 115ECh. 22 - Prob. 116ECh. 22 - Prob. 117ECh. 22 - Prob. 118ECh. 22 - The base sequences in mRNA that code for certain...Ch. 22 - Prob. 120ECh. 22 - Prob. 121AECh. 22 - Prob. 122AECh. 22 - Prob. 123AECh. 22 - Prob. 124AECh. 22 - Prob. 125AECh. 22 - Prob. 126AECh. 22 - Prob. 127AECh. 22 - Prob. 128AECh. 22 - Explain why methyl alcohol is soluble in water in...Ch. 22 - Prob. 130AECh. 22 - Prob. 131AECh. 22 - Prob. 132AECh. 22 - Prob. 133AECh. 22 - Prob. 134AECh. 22 - Prob. 135AECh. 22 - Prob. 136AECh. 22 - Prob. 137AECh. 22 - Prob. 138AECh. 22 - Prob. 139AECh. 22 - Prob. 140AECh. 22 - Prob. 141AECh. 22 - a. Use bond energies (see Table 3-3) to estimate H...Ch. 22 - Prob. 143AECh. 22 - Prob. 144AECh. 22 - All amino acids have at least two functional...Ch. 22 - Prob. 146AECh. 22 - Prob. 147AECh. 22 - In glycine, the carboxylic acid group has Ka = 4.3...Ch. 22 - Name each of the following alkanes. a....Ch. 22 - Prob. 150CWPCh. 22 - Name each of the following cyclic alkanes. a. b....Ch. 22 - Name each of the following alkenes and alkynes. a....Ch. 22 - a. Name each of the following alcohols. b. Name...Ch. 22 - Prob. 154CWPCh. 22 - Prob. 155CWPCh. 22 - Prob. 156CWPCh. 22 - Prob. 157CPCh. 22 - Estimate H for the following reactions using bond...Ch. 22 - Prob. 159CPCh. 22 - Prob. 160CPCh. 22 - Prob. 161CPCh. 22 - Consider a sample of a hydrocarbon at 0.959 atm...Ch. 22 - Prob. 163CPCh. 22 - Prob. 164CPCh. 22 - Prob. 165CPCh. 22 - Prob. 166CPCh. 22 - Prob. 167CPCh. 22 - Prob. 168CPCh. 22 - Prob. 169CPCh. 22 - Alcohols are very useful starting materials for...Ch. 22 - A chemical breathalyzer test works because ethanol...Ch. 22 - Estradiol is a female hormone with the following...Ch. 22 - Prob. 173IPCh. 22 - Prob. 174IPCh. 22 - Prob. 175MPCh. 22 - Prob. 176MP
Knowledge Booster
Similar questions
- What are aromatic hydrocarbons? Benzene exhibits resonance. Explain. What are the bond angles in benzene? Give a detailed description of the bonding in benzene. The electrons in benzene are delocalized, while the electrons in simple alkenes and alkynes are localized. Explain the difference.arrow_forwardSummarize the nomenclature rules for alkanes, alkenes, alkynes, and aromatic compounds. Correct the following false statements regarding nomenclature of hydrocarbons. a. The root name for a hydrocarbon is based on the shortest continuous chain of carbon atoms. b. The suffix used to name all hydrocarbons is -ane. c. Substituent groups are numbered so as to give the largest numbers possible. d. No number is required to indicate the positions of double or triple bonds in alkenes and alkynes. e. Substituent groups get the lowest number possible in alkenes and alkynes. f. The ortho- term in aromatic hydrocarbons indicates the presence of two substituent groups bonded to carbon- 1 and carbon-3 in benzene.arrow_forwardDistinguish between isomerism and resonance. Distinguish between structural and geometric isomerism. When writing the various structural isomers, the most difficult task is identifying which are different isomers and which are identical to a previously written structurethat is, which are compounds that differ only by the rotation of a carbon single bond. How do you distinguish between structural isomers and those that are identical? Alkenes and cycloalkanes are structural isomers of each other. Give an example of each using C4H8. Another common feature of alkenes and cycloalkanes is that both have restricted rotation about one or more bonds in the compound, so both can exhibit cis- trans isomerism. What is required for an alkene or cycloalkane to exhibit cis-trans isomerism? Explain the difference between cis and trans isomers. Alcohols and ethers are structural isomers of each other, as are aldehydes and ketones. Give an example of each to illustrate. Which functional group in Table 21-4 can be structural isomers of carboxylic acids? What is optical isomerism? What do you look for to determine whether an organic compound exhibits optical isomerism? 1-Bromo-1-chloroethane is optically active whereas 1-bromo-2-chloroethane is not optically active. Explain.arrow_forward
- Select those compounds that can be correctly called unsaturated and classify each one as an alkene or an alkyne: a.CH3CH2CH3f. b.CH3CH=CHCH3g. c.h.CH2=CHCH2CH3 d.i. e.arrow_forwardAlcohols A, B and C all have the composition C4H 100. Molecules of alcohol A contain a branched carbon chain and can be oxidized to an aldehyde; molecules of alcohol B contain a linear carbon chain and can be oxidized to a ketone; and molecules of alcohol C can be oxidized to neither an aldehyde nor a ketone. Write the Lewis structures of these molecules.arrow_forwardAlcohols are very useful starting materials for the production of many different compounds. The following conversions, starting with 1-butanol, can be carried out in two or more steps. Show the steps (reactants/catalysts) you would follow to carry out the conversions, drawing the formula for the organic product in each step. For each step, a major product must be produced. (See Exercise 62.) (Hint: In the presence of H+, an alcohol is converted into an alkene and water. This is the exact reverse of the reaction of adding water to an alkene to form an alcohol.) a. 1-butanol butane b. 1-butanol 2-butanonearrow_forward
- What is the difference in bonding and in the general molecular formula between an alkene and an alkane with the same number of carbon atoms?arrow_forwardIs the reaction between an alkene and a halogen a substitution reaction(displacement reaction) or another reaction? Explain the reaction mechanism by giving an example.arrow_forwardMineral oil and Vaseline are both mixtures of alkanes, but mineral oil is a liquid at room temperature and Vaseline is a solid. Which product is composed of alkanes that contain a larger number of carbon atoms? Explain your choice.arrow_forward
- State whether the statements are true or false. 1. Unsaturated hydrocarbons must contain at least one carbon-carbon double triple bond. 2. Aromatic compounds usualky undergo addition reactions. 3. Carboxylic acid molecules are much less polar than the corresponding alkane molecules. 4. Marikovnikov's rule states that, in an addition reaction involving a hydrogen atom, the hydrogen atom will usually bond to the carbon atom with the fewest hydrogen atoms attached. 5. But-1-ene and 2-ene are structural isomers of each other. 6. Aldehydes contain a carbonyl group on the terminal carbon atom.arrow_forwardPetroleum products such as kerosene and gasoline are separated using fractional distillation. Each of them has their own properties and usage. Why can't we use one petroleum product as a substitute for the other when they are composed majority of alkanes?arrow_forwardPetrol is a complex mix of light hydrocarbons. Petrol with octane number 95 contains 95% 2,2,4-trimethylpentane. This compound can be obtained by breaking up a large hydrocarbon molecule such as dodecane, C12H26 using a catalyst such as zeolite. a) name the process where a large hydrocarbon molecule is broken into smaller molecules b) write an equation for the breaking up of dodecane into 2,2,4-trimethylpentane if another branched hydrocarbon compound is formed at the same time. c) what is the other hydrocarbon obtained ? d) draw the structural formula of 2,2,4-trimethylpentane.arrow_forward
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