Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Textbook Question
Chapter 22, Problem 153CWP
a. Name each of the following alcohols.
b. Name each of the following alcohols, including the stereochemistry if cis-trans isomers are possible.
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1.
a. Draw the structures of the two isomers of dibromoethane. Name them by the IUPAC system.
b. Draw out the structures of the two isomers of iodopropane. Name them by the IUPAC system.
c. Draw the structures of the three isomers of dichloroethene. Name each one by the IUPAC system, indicating stereochemistry where relevant.
This is no multiple questions please answer only draw structure all
C. Nomenclature of Cylic Alkanes:
If a ring is present in a molecule, the ring is almost always considered the parent chain.
Use the word cyclo as a prefix before the alkane name to indicate it is a cyclic parent chain
Number the carbons that bear substituents starting with one, and number around the ring towards the closest carbon
that bears another substituent group to give all substituents lowest possible numbering.
If there are two or more substituents, use alphabetical order to determine where to start numbering.
Critical Thinking Question (CTQ):
11. Give the correct IUPAC name for the remaining three compounds below.
H,C
CH-CH,
l-isopropyl-3-methylcycloherane
12. Draw the structures that correspond to the following names:
a. 3-ethylheptane
b. 1,1-diethylcyclopropane
c. 4-sec-butyl-1-isobutyl-2-methylcylcohexane
13. Mono-substituted cycloalkanes do not include the "1" locant. Thus, 1-methylcyclohexane is inaccurate.
Draw methylcyclohexane; explain why adding a locant does not add…
Chapter 22 Solutions
Chemistry
Ch. 22 - What is a hydrocarbon? What is the difference...Ch. 22 - Prob. 2RQCh. 22 - What are aromatic hydrocarbons? Benzene exhibits...Ch. 22 - Summarize the nomenclature rules for alkanes,...Ch. 22 - What functional group distinguishes each of the...Ch. 22 - Distinguish between isomerism and resonance....Ch. 22 - Prob. 7RQCh. 22 - Prob. 8RQCh. 22 - Prob. 9RQCh. 22 - Prob. 10RQ
Ch. 22 - Prob. 11RQCh. 22 - Describe the structural differences between DNA...Ch. 22 - Prob. 1QCh. 22 - Prob. 2QCh. 22 - Prob. 3QCh. 22 - Prob. 4QCh. 22 - Prob. 5QCh. 22 - Prob. 6QCh. 22 - Prob. 7QCh. 22 - Give an example reaction that would yield the...Ch. 22 - Prob. 9QCh. 22 - Prob. 10QCh. 22 - Prob. 11QCh. 22 - Prob. 12QCh. 22 - Is the primary, secondary, or tertiary structure...Ch. 22 - Prob. 14QCh. 22 - Prob. 15ECh. 22 - Prob. 16ECh. 22 - Draw all the structural isomers for C8H18 that...Ch. 22 - Draw all the structural isomers for C8H18 that...Ch. 22 - Prob. 19ECh. 22 - Prob. 20ECh. 22 - Draw the structural formula for each of the...Ch. 22 - Prob. 22ECh. 22 - Prob. 23ECh. 22 - Name each of the following cyclic alkanes, and...Ch. 22 - Prob. 25ECh. 22 - Draw the structures for two examples of...Ch. 22 - Name each of the following alkenes. a. CH2 = CH ...Ch. 22 - Name each of the following alkenes or alkynes. a....Ch. 22 - Prob. 29ECh. 22 - Give the structure for each of the following. a....Ch. 22 - Prob. 31ECh. 22 - Cumene is the starting material for the industrial...Ch. 22 - Name each of the following. a. b. CH3CH2CH2CCl3 c....Ch. 22 - Prob. 34ECh. 22 - There is only one compound that is named...Ch. 22 - Prob. 36ECh. 22 - Prob. 37ECh. 22 - Prob. 38ECh. 22 - Draw all the structural isomers of C5H10. Ignore...Ch. 22 - Prob. 40ECh. 22 - Draw all the structural and geometrical (cistrans)...Ch. 22 - Draw all the structural and geometrical (cistrans)...Ch. 22 - Draw all structural and geometrical (cistrans)...Ch. 22 - Prob. 44ECh. 22 - Prob. 45ECh. 22 - Prob. 46ECh. 22 - Prob. 47ECh. 22 - Prob. 48ECh. 22 - If one hydrogen in a hydrocarbon is replaced by a...Ch. 22 - There are three isomers of dichlorobenzene, one of...Ch. 22 - Identify each of the following compounds as a...Ch. 22 - Prob. 52ECh. 22 - Mimosine is a natural product found in large...Ch. 22 - Minoxidil (C9H15N5O) is a compound produced by...Ch. 22 - For each of the following alcohols, give the...Ch. 22 - Prob. 56ECh. 22 - Prob. 58ECh. 22 - Prob. 59ECh. 22 - Prob. 60ECh. 22 - Prob. 61ECh. 22 - Prob. 62ECh. 22 - Prob. 63ECh. 22 - Prob. 64ECh. 22 - Prob. 65ECh. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - Prob. 71ECh. 22 - Prob. 72ECh. 22 - Prob. 73ECh. 22 - Prob. 74ECh. 22 - Prob. 75ECh. 22 - Prob. 76ECh. 22 - Prob. 77ECh. 22 - Prob. 78ECh. 22 - Super glue contains methyl cyanoacrylate, which...Ch. 22 - Prob. 80ECh. 22 - Prob. 81ECh. 22 - Prob. 82ECh. 22 - Prob. 83ECh. 22 - Prob. 84ECh. 22 - Prob. 85ECh. 22 - Prob. 86ECh. 22 - Prob. 87ECh. 22 - Prob. 88ECh. 22 - Prob. 89ECh. 22 - Prob. 90ECh. 22 - Aspartame, the artificial sweetener marketed under...Ch. 22 - Prob. 92ECh. 22 - Prob. 93ECh. 22 - Draw the structures of the tripeptides glyalaser...Ch. 22 - Prob. 95ECh. 22 - Prob. 96ECh. 22 - Prob. 97ECh. 22 - In general terms, what does the tertiary structure...Ch. 22 - Give an example of amino acids that could give...Ch. 22 - What types of interactions can occur between the...Ch. 22 - Prob. 101ECh. 22 - Prob. 102ECh. 22 - Prob. 103ECh. 22 - Prob. 104ECh. 22 - Prob. 105ECh. 22 - Prob. 106ECh. 22 - Prob. 107ECh. 22 - Prob. 108ECh. 22 - Prob. 109ECh. 22 - Prob. 110ECh. 22 - Prob. 111ECh. 22 - Prob. 114ECh. 22 - Prob. 115ECh. 22 - Prob. 116ECh. 22 - Prob. 117ECh. 22 - Prob. 118ECh. 22 - The base sequences in mRNA that code for certain...Ch. 22 - Prob. 120ECh. 22 - Prob. 121AECh. 22 - Prob. 122AECh. 22 - Prob. 123AECh. 22 - Prob. 124AECh. 22 - Prob. 125AECh. 22 - Prob. 126AECh. 22 - Prob. 127AECh. 22 - Prob. 128AECh. 22 - Explain why methyl alcohol is soluble in water in...Ch. 22 - Prob. 130AECh. 22 - Prob. 131AECh. 22 - Prob. 132AECh. 22 - Prob. 133AECh. 22 - Prob. 134AECh. 22 - Prob. 135AECh. 22 - Prob. 136AECh. 22 - Prob. 137AECh. 22 - Prob. 138AECh. 22 - Prob. 139AECh. 22 - Prob. 140AECh. 22 - Prob. 141AECh. 22 - a. Use bond energies (see Table 3-3) to estimate H...Ch. 22 - Prob. 143AECh. 22 - Prob. 144AECh. 22 - All amino acids have at least two functional...Ch. 22 - Prob. 146AECh. 22 - Prob. 147AECh. 22 - In glycine, the carboxylic acid group has Ka = 4.3...Ch. 22 - Name each of the following alkanes. a....Ch. 22 - Prob. 150CWPCh. 22 - Name each of the following cyclic alkanes. a. b....Ch. 22 - Name each of the following alkenes and alkynes. a....Ch. 22 - a. Name each of the following alcohols. b. Name...Ch. 22 - Prob. 154CWPCh. 22 - Prob. 155CWPCh. 22 - Prob. 156CWPCh. 22 - Prob. 157CPCh. 22 - Estimate H for the following reactions using bond...Ch. 22 - Prob. 159CPCh. 22 - Prob. 160CPCh. 22 - Prob. 161CPCh. 22 - Consider a sample of a hydrocarbon at 0.959 atm...Ch. 22 - Prob. 163CPCh. 22 - Prob. 164CPCh. 22 - Prob. 165CPCh. 22 - Prob. 166CPCh. 22 - Prob. 167CPCh. 22 - Prob. 168CPCh. 22 - Prob. 169CPCh. 22 - Alcohols are very useful starting materials for...Ch. 22 - A chemical breathalyzer test works because ethanol...Ch. 22 - Estradiol is a female hormone with the following...Ch. 22 - Prob. 173IPCh. 22 - Prob. 174IPCh. 22 - Prob. 175MPCh. 22 - Prob. 176MP
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- 1. Name each compound and determine the relationship between the pairs of compounds. a. Name: b. Name: Relationship between structures above: Conformational isomer or Structural isomer 2. Name: 3. Is the following structure the cis stereoisomer or the trans stereoisomer?arrow_forwardWhich of the following is true of conformational isomers? O A. They arise from rotation about single bonds. B. They cannot be isolated under ordinary conditions of temperature and pressure. O C. They have the same structural formulas D. all of these E. none of thesearrow_forward1. In dash-wedge-line structure, the dashes represent the: * A. bonds in the plane of the page. B. bonds away from observer. C. bonds towards observer. D. bonds in the plane of the paper. 2. Which of the following is an ACYCLIC SATURATED hydrocarbon? * A. 1-Ethyl-3-methylcyclopentane B. 3-Ethyl-3-methylpentane C. 1,3,5,7-Octatetraene D. 5-Methyl-1,3-cyclopentadiene 3. Which of the following is a CYCLIC SATURATED hydrocarbon? * A. 3-Ethyl-4-methylcyclohexene B. 3,5-Diethyloctane C. 2,2-Dimethyl-3-heptyne D. 3-Butyl-1,1-dimethyl-5-propylcyclohexanearrow_forward
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- Organic Chemistry 15. ADLC Assignment Booklet A3 Decide whether each statement is true (T) or false (F). Place your answer in the blank space given. a. A hydrocarbon molecule with a triple bond is more stable than a hydrocarbon molecule with all single bonds. b. The difference between butter and corn oil is that the hydrocarbon molecule in butter contains a double carbon- carbon bond. c. A bent shape is the property that accounts for many of the healthy properties of oleic acid present in corn oil. d. A diet with no fat is the healthiest diet. e. In an industrially produced trans fat, only the relative position of the hydrogen atoms on either side of the double bond is changed. f. Trans fatty acids have a greater likelihood of clogging arteries because they tend to be solids at room temperature.arrow_forwardSome alkenes have cis-trans isomers because a. the carbon atoms in the double bond are free to rotate. b. one of the carbon atoms in the double bond has two identical groups attached to it. c. all of the carbon atoms in the compound are rigid and cannot rotate. d. each of the carbon atoms in the double bond has four different groups attached to it. e. the carbon atoms in the double bond cannot rotate.arrow_forward1,2-ditert-butylcyclohexane is an interesting case of a conformational study. The cis isomer is more stable than the trans isomer, although the trans isomer presents a conformer with both substituents in equatorial positions. In order to analyze this fact:a. Draw the conformational equilibrium of both compounds. Explain using and drawing the structures why this difference happens (the one described above). b. In the trans isomer, the di-axial conformation is 25.9 kJ / mol more stable than the di-equatorial. Calculate the energy of the di-equatorial conformation.arrow_forward
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