(a) Interpretation: The major product of the given reaction is to be predicted. Concept introduction: The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows: Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(b)

Interpretation:

The major product of the given reaction is to be predicted

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(c)

Interpretation:

The major product of given compound is to be predicted and reaction is shown as.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Label each of the seven designated regions of the following multi-component, solid-liquid phase diagram for the Zinc - Magnesium system.

22

PLEASE READ!!! I DONT WANT EXAMPLES, I DONT WANT WORDS OR PARAGRAPHS FOR THE MECHANISM!!! THANKS First image: QUESTION 6. I have to show, with ARROWS and STRUCTURES, the mechanism of the reaction at the bottom. Also I have to show by mecanism why the reaction wouldn't work if the alcohol was primary. I also tried to draw the mechanism, tell me what to change. Please note that its an AMIDE thats formed not an AMINE the nitrogen has ONE hydrogen and one Phenyl-C-Phenyl. I already asked for this mechanism and got as a final product ...-NH2 not whats shown on the picture, thank you Ths second part. QUESTION 3. I just need a way to synthesize the lactone A, I already started please continue from where I left it Second image: I simply need the products, substrates or reagents, thank you

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(b)

Interpretation:

The major product of the given reaction is to be predicted

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(c)

Interpretation:

The major product of given compound is to be predicted and reaction is shown as.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(b)

Interpretation:

The major product of the given reaction is to be predicted

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(c)

Interpretation:

The major product of given compound is to be predicted and reaction is shown as.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(b)

Interpretation:

The major product of the given reaction is to be predicted

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(c)

Interpretation:

The major product of given compound is to be predicted and reaction is shown as.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(b)

Interpretation:

The major product of the given reaction is to be predicted

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Interpretation Introduction

(c)

Interpretation:

The major product of given compound is to be predicted and reaction is shown as.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Answer 6

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Answer 7

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The major product of the given reaction is to be predicted

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The major product of the given reaction is to be predicted

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The major product of given compound is to be predicted and reaction is shown as.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The major product of given compound is to be predicted and reaction is shown as.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In the Baeyer villiger oxidation oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, only one product is formed, but if ketone or aldehyde is unsymmetric, the major product depends on which group leaves from carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

Want to see the full answer?

Chapter 21 Solutions