(a) Interpretation: The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl 2 is to be drawn. Concept introduction: In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

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Answer 1

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.46P

Interpretation Introduction

(a)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Interpretation Introduction

(b)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Interpretation Introduction

(c)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.46P

Interpretation Introduction

(a)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Interpretation Introduction

(b)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Interpretation Introduction

(c)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.46P

Interpretation Introduction

(a)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Interpretation Introduction

(b)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Interpretation Introduction

(c)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.46P

Interpretation Introduction

(a)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Interpretation Introduction

(b)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Interpretation Introduction

(c)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

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Answer 5

Chapter 21, Problem 21.46P

Interpretation Introduction

(a)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Interpretation Introduction

(b)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Interpretation Introduction

(c)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Answer 6

Chapter 21, Problem 21.46P

Interpretation Introduction

(a)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Answer 7

Chapter 21, Problem 21.46P

Interpretation Introduction

(a)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of carboxylic acid that would produce the given acid chloride when treated with SOCl2 is to be drawn.

Concept introduction:

In the reaction between a carboxylic acid and thionyl chloride to yield an acid chloride. In this reaction the bonds around the C=O and C-OH are broken and C=O and C-Cl are formed. Therefore, the original carbon skeleton remains unchanged.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

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Chapter 21 Solutions