(a) Interpretation: The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted. Concept introduction: The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone .

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Answer 1

Question

Chapter 21, Problem 21.64P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted.

Concept introduction:

The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted.

Concept introduction:

The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone.

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Answer 2

Question

Chapter 21, Problem 21.64P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted.

Concept introduction:

The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted.

Concept introduction:

The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone.

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Answer 3

Question

Chapter 21, Problem 21.64P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted.

Concept introduction:

The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted.

Concept introduction:

The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone.

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Answer 4

Question

Chapter 21, Problem 21.64P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted.

Concept introduction:

The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted.

Concept introduction:

The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone.

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Answer 5

Chapter 21, Problem 21.64P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted.

Concept introduction:

The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted.

Concept introduction:

The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone.

Answer 6

Chapter 21, Problem 21.64P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted.

Concept introduction:

The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone.

Answer 7

Chapter 21, Problem 21.64P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted.

Concept introduction:

The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted.

Concept introduction:

The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the following reaction is to be drawn and the major product is to be predicted.

Concept introduction:

The Claisen condensation reaction involves carbon-carbon bond formation. The bond formation takes place between one ester and another carbonyl compound or two esters. The reaction takes place in presence of a strong base. The product formed in this reaction is β-keto ester or a β-diketone.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

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Chapter 21 Solutions