a) Interpretation: Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated. Concept introduction: In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect. Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating. To state: Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Question

Use the expression below to ⚫ calculate its value and report it to the proper number of significant digits (you may need to round your answer). ⚫ calculate the % error (or % relative error or % inherent error) ⚫ calculate the absolute error. (20.54±0.02 × 0.254±0.003) / (3.21±0.05) = Value: % Error: Absolute error: ± | % (only 1 significant digit) (only 1 significant digit)

Answer 1

Question

Chapter 16.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Interpretation Introduction

b)

Interpretation:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

c)

Interpretation:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

d)

Interpretation:

Whether the carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director.

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Use the expression below to ⚫ calculate its value and report it to the proper number of significant digits (you may need to round your answer). ⚫ calculate the % error (or % relative error or % inherent error) ⚫ calculate the absolute error. (20.54±0.02 × 0.254±0.003) / (3.21±0.05) = Value: % Error: Absolute error: ± | % (only 1 significant digit) (only 1 significant digit)

In each case (more ductile, more brittle, more tough or resistant), indicate which parameter has a larger value. parameter Elastic limit Tensile strength more ductile Strain at break Strength Elastic modulus more fragile more tough or resistant

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Answer 2

Question

Chapter 16.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Interpretation Introduction

b)

Interpretation:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

c)

Interpretation:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

d)

Interpretation:

Whether the carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director.

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Answer 3

Question

Chapter 16.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Interpretation Introduction

b)

Interpretation:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

c)

Interpretation:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

d)

Interpretation:

Whether the carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director.

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Answer 4

Question

Chapter 16.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Interpretation Introduction

b)

Interpretation:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

c)

Interpretation:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

d)

Interpretation:

Whether the carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director.

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Answer 5

Chapter 16.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Interpretation Introduction

b)

Interpretation:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

c)

Interpretation:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director.

Interpretation Introduction

d)

Interpretation:

Whether the carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director.

Answer 6

Chapter 16.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Answer 7

Chapter 16.SE, Problem 46AP

Interpretation Introduction

a)

Interpretation:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether N,N-dimethylamino group is an activator or deactivator and whether it is a, o-, p-director or m-director.

Answer 8

Interpretation Introduction

b)

Interpretation:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director.

Answer 9

Interpretation Introduction

b)

Interpretation:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether cyclopentyl group is an activator or deactivator and whether it is an o-, p-director or m-director.

Answer 10

Interpretation Introduction

c)

Interpretation:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director.

Answer 11

Interpretation Introduction

c)

Interpretation:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether ethoxy group is an activator or deactivator and whether it is an o-, p-director or m-director.

Answer 12

Interpretation Introduction

d)

Interpretation:

Whether the carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director.

Answer 13

Interpretation Introduction

d)

Interpretation:

Whether the carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director is to be stated.

Concept introduction:

In aromatic substitution reactions the activating or deactivating and orienting effects of a substituent attached to the benzene ring can be decided from its resonance and inductive effects. The orientation is decided by the resonance effect while the activating or deactivating effect is decided both by resonance and inductive effects. Both effects may reinforce or oppose each other. However the resonance effect is much stronger than the inductive effect.

Electron releasing groups, except halogens, normally are activators and ortho & para directors. Electron withdrawing groups normally are deactivators and meta directors. Halogens are ortho & para directing but are deactivating.

To state:

Whether carbonyl group is an activator or deactivator and whether it is a o-, p-director or m-director.

Answer 14

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Ch. 16.1 - Prob. 1P Ch. 16.2 - Propose a mechanism for the electrophilic...Ch. 16.2 - How many products might be formed on chlorination...Ch. 16.2 - When benzene is treated with D2SÅª4. deuterium...Ch. 16.3 - Prob. 5P Ch. 16.3 - What is the major monosubstitution product from...Ch. 16.3 - Identify the carboxylic acid chloride that might...Ch. 16.4 - Rank the compounds in each of the following groups...Ch. 16.4 - Predict the major products of the following...Ch. 16.4 - Prob. 10P

Chapter 16 Solutions