General, Organic, & Biological Chemistry
General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Alkanes and Cycloalkanes
Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atom…
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Chapter 13, Problem 13.40P

Give the IUPAC name for each compound.

Chapter 13, Problem 13.40P, Give the IUPAC name for each compound. d. (CH3)3CCCC(CH3)3 e. (CH3CH2CH2CH2)2C=CHCH3 e.
d. ( C H 3 ) 3 C C ≡ C C ( C H 3 ) 3

e. ( C H 3 C H 2 C H 2 C H 2 ) 2 C = C H C H 3

e. ( C H 3 ) 2 C = C H C H 2 C H 2 C H 2 C H = C ( C H 3 ) 2

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Q8 Conformational Analysis of Cycloalkanes In this question you will look at the conformations of the following molecule: CH3 C В F CH3 D -E A H3C F I II Energy Costs for Interactions in Alkane Conformers: Computed Energy Cost (kJ/mol)* 3.8 Interaction H+H eclipsed H+CH3 eclipsed CH3+CH3 eclipsed CH3+CH3 gauche H»CH(CH3)2 gauche H CH(CH:)2 eclipsed CH3+CH(CH3)2 gauche CH3+CH(CH3)2 eclipsed HeC(CH:)3 eclipsed CH3+C(CH3)3 gauche CH3+C(CH:)3 eclipsed H+I eclipsed I+CH3 gauche I+CH3 eclipsed "Values computed with Gaussian09 using B3LYP/6-31G(d) for structure optimization and B3LYP/6-311+G(2df,3p) for the conformation energy. The calculations were performed in the gas phase (no solvent). *This result for t-butyl is a bit peculiar given that the value is less than that for isopropyl, but there is an explanation that I can tell you about in office hours! 4.8 12.6 3.7 (0.0) 3.1 3.6 17.3 2.8 13.6 18.7 6.7 1.2 15.5 Steric Strain in Monosubstituted Cyclohexanes: 1,3-Diaxial strain Y (kJ/mol)…

Chapter 13 Solutions

General, Organic, & Biological Chemistry

Ch. 13.1 - Convert each condensed structure to a complete...Ch. 13.1 - Prob. 13.2PCh. 13.1 - Complete the structure of zingiberene, a component...Ch. 13.2 - Prob. 13.4PCh. 13.2 - Prob. 13.5PCh. 13.2 - Prob. 13.6PCh. 13.3 - Prob. 13.7PCh. 13.3 - Prob. 13.8PCh. 13.3 - Prob. 13.9PCh. 13.3 - Prob. 13.10P
Ch. 13.3 - Prob. 13.11PCh. 13.3 - Prob. 13.12PCh. 13.3 - Prob. 13.13PCh. 13.4 - Prob. 13.14PCh. 13.6 - Prob. 13.15PCh. 13.6 - Prob. 13.16PCh. 13.6 - Prob. 13.17PCh. 13.6 - Prob. 13.18PCh. 13.6 - Prob. 13.19PCh. 13.7 - Prob. 13.20PCh. 13.8 - Prob. 13.21PCh. 13.8 - Prob. 13.22PCh. 13.10 - Give the IUPAC name of each compound. Ch. 13.10 - Prob. 13.24PCh. 13.11 - Prob. 13.25PCh. 13.12 - Prob. 13.26PCh. 13.13 - Prob. 13.27PCh. 13.13 - Prob. 13.28PCh. 13 - Anethole, the major constituent of anise oil, is...Ch. 13 - Prob. 13.30PCh. 13 - What is the molecular formula for a hydrocarbon...Ch. 13 - Prob. 13.32PCh. 13 - Prob. 13.33PCh. 13 - Prob. 13.34PCh. 13 - Prob. 13.35PCh. 13 - Prob. 13.36PCh. 13 - Give the IUPAC name for each molecule depicted in...Ch. 13 - Give the IUPAC name for each molecule depicted in...Ch. 13 - Give the IUPAC name for each compound. a....Ch. 13 - Give the IUPAC name for each compound. d....Ch. 13 - Prob. 13.41PCh. 13 - Prob. 13.42PCh. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Prob. 13.44PCh. 13 - Each of the following IUPAC names is incorrect....Ch. 13 - Each of the following IUPAC names is incorrect....Ch. 13 - Prob. 13.47PCh. 13 - Prob. 13.48PCh. 13 - Prob. 13.49PCh. 13 - Label the carbon-carbon double bond as cis or...Ch. 13 - Prob. 13.51PCh. 13 - Prob. 13.52PCh. 13 - Prob. 13.53PCh. 13 - Prob. 13.54PCh. 13 - Prob. 13.55PCh. 13 - Prob. 13.56PCh. 13 - Prob. 13.57PCh. 13 - Prob. 13.58PCh. 13 - Prob. 13.59PCh. 13 - Prob. 13.60PCh. 13 - What alkyd halide is formed when each alkene is...Ch. 13 - Prob. 13.62PCh. 13 - Prob. 13.63PCh. 13 - Prob. 13.64PCh. 13 - What alkene is needed as a starting material to...Ch. 13 - Prob. 13.66PCh. 13 - Prob. 13.67PCh. 13 - Prob. 13.68PCh. 13 - Prob. 13.69PCh. 13 - Prob. 13.70PCh. 13 - Prob. 13.71PCh. 13 - Prob. 13.72PCh. 13 - Prob. 13.73PCh. 13 - Prob. 13.74PCh. 13 - Prob. 13.75PCh. 13 - Prob. 13.76PCh. 13 - Prob. 13.77PCh. 13 - Prob. 13.78PCh. 13 - Prob. 13.79PCh. 13 - Prob. 13.80PCh. 13 - Prob. 13.81PCh. 13 - Are o-bromochlorobenzene and m-bromochlorobenzene...Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Prob. 13.85PCh. 13 - Prob. 13.86PCh. 13 - Prob. 13.87PCh. 13 - Prob. 13.88PCh. 13 - Prob. 13.89PCh. 13 - Prob. 13.90PCh. 13 - Prob. 13.91PCh. 13 - Prob. 13.92PCh. 13 - Prob. 13.93PCh. 13 - Eleostearic acid is an unsaturated fatty acid...Ch. 13 - Prob. 13.95PCh. 13 - Prob. 13.96PCh. 13 - Prob. 13.97PCh. 13 - Prob. 13.98PCh. 13 - Prob. 13.99PCh. 13 - Prob. 13.100PCh. 13 - Prob. 13.101PCh. 13 - Prob. 13.102PCh. 13 - Answer the following questions about compound A,...Ch. 13 - Prob. 13.104PCh. 13 - Prob. 13.105PCh. 13 - Prob. 13.106PCh. 13 - Prob. 13.107CPCh. 13 - Prob. 13.108CP
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Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
Chapter 4 Alkanes and Cycloalkanes Lesson 1; Author: Linda Hanson;https://www.youtube.com/watch?v=PPIa6EHJMJw;License: Standard Youtube License