(a)
Interpretation:
For the given set of
Concept introduction:
Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.
Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.
Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.
Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.
(b)
Interpretation:
For the given set of chemical reactions the electrophile and the nucleophile should be determined and the curved arrows that denote the bond making and breaking should be indicated.
Concept introduction:
Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.
Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.
Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.
Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.
(c)
Interpretation:
For the given set of chemical reactions the electrophile and the nucleophile should be determined and the curved arrows that denote the bond making and breaking should be indicated.
Concept introduction:
Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.
Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.
Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.
Chemical reaction involves bond making and breaking of two or more reactants in order to attain products from the reactants.
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Chapter 6 Solutions
EBK ORGANIC CHEMISTRY
- What are the species type of I and II (nucleophile or electrophile)?arrow_forwardgive an example of a nucleophilic substitution reaction with chlorohexanearrow_forwardDraw the structure of the organic product formed when the given compounds undergo the three-step reaction sequence indicated. Select Draw Rings More Erase C Br 1. NaOC,H5. C,H5OH 2. NaOH, H2O 3. H3O*, heatarrow_forward
- Consider the molecular models in Figure 12. In which case will a nucleophile react more readily with the carbonyl group? Your answer Figure 12 A carbonyl group H :0: H H:O: | || HICH H-C-C-O-C-H H |||| H-C-C―CI: Н H Barrow_forwardHand written solution is not allowed jiger...arrow_forwardShow how the reactant can be converted to the product in two steps.arrow_forward
- Payalbenarrow_forwardZaitsev's rule is useful in selecting which carbon adjacent to a carbocation will form the double bond in the alkene product. True or Falsearrow_forwardComplete the following reversible reaction and draw the mechanism of formation ofproducts. Indicate using the arrows of unequal length whether the shift in equilibrium will favor the reactants or the products. give 2 reasonsarrow_forward
- Draw the most stable resonance form for the intermediate in the following electrophilic substitution reaction.arrow_forwardCurved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the first step of this reaction sequence. Be sure to account for all bond-breaking and bond- making steps. I H BH₂ H B H Select to Add Arrows > H Bll H BH₂arrow_forwardOa) An amine can be formed when 2-iodopentane is heated with ammonia in a sealed tube. This is an example of a nucleophilic substitution reaction. i) Provide a full equation (using condensed formula) for this reaction. You should name the reactants and the overall products as part of your response. ii) Name the organic product formed from this reaction and draw it's displayed structure. iii) Provide a 'curly arrow' mechanism (in displayed formula) with an accompanying explanation for this process. iv) Describe a characteristic test (with the result that would be observed) to show the presence of the amine produced upon completion of the nucleophilic substitution reaction. b) The amine produced in the above reaction forms a mixture of two optical isomers. i) Draw the 3D structures of the two isomers of the amine product that you named and produced a drawing of in part a ii). ii) With reference to a different named example, explain the term 'optical isomer'. You should draw the 3D…arrow_forward
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