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Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions

Section: Chapter Questions

Problem 20.27P

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Outline a detailed mechanism for the reaction below. Identify the abbreviation for the reaction mechanism. OH H PO4
2NO2(g) + F2(g) -> NO2F(g) H°rxn = -284 kJ/molrxn NO2(g) and F2(g) can reactto produce NO2F(g), as represented above. A proposed mechanism for the reaction has two elementary steps, as shown below. Step 1: NO2 + F2 -> NO2F + F (slow) Step 2: NO2 + F -> NO2F (fast) a.) Write a rate law for the overall reaction that is consistent with the proposed mechanism. b.) On the incomplete reaction energy diagram below, draw a curve that shows the following two details. The relative activation energies for the two elementary steps The enthalpy change of the overall reaction Can all of them be solved please, and thank you very much!
4. Explain why the rate of formation of 1-azidopropane is different depending on which halopropane (X = F, Cl, Br, I) is used. Explain which halopropane will react fastest? ~X X = F, Cl, Br, I NaN №3 1-azidopropane
Can you show the appropriate reactants and which reactions is appropriate and show the mechanism
Chemistry Q5. A possible ion-molecule reaction mechanism for the synthesis of ammonia in interstellar gas clouds is shown below. N+ + H2 ® NH+ + H k1 NH+ + H2 ® NH2+ + H k2 NH2+ + H2 ® NH3+ + H k3 NH3+ + H2 ® NH4+ + H k4 NH4+ + e- ® NH3 + H k5 NH4+ + e- ® NH2 + 2H k6 Use the steady-state approximation to derive equations for the concentrations of the intermediates NH+, NH2+, NH3+ and NH4+ in terms of the reactant concentrations [N+], [H2] and [e-]. Treat the electrons as you would any other reactant. b) Show that the overall rate of productionmjngbh of NH3 is given by d[NH3]/dt = (k1k5/k5+k6) [N+][H2] c) What is the origin of the activation energy in a chemical reaction? d) The rates of many ion-molecule reactions show virtually no dependence on temperature. (i) What does this imply about their activation energy? (ii) What relevance does this have to reactions…
In a hydrocarbon solution, the gold compound (CH3)3AUPH3 decomposes into ethane (C2H6) and a different gold compound, (CH3)AUPH3. The following mechanism has been proposed for the decomposition of (CH3)3AUPH3: Step 1: (CH3)3 AuPH; (CH3);Au + PH3 (fast) Step 2: (CH3)3 Au 4, C,H, + (CH;)Au (slow) Step 3: (CH3)Au + PH3 (CH3)AUPH3 (fast) (a) What is the overall reaction? (b) What are the inter- mediates in the mechanism? (c) What is the molecular- ity of each of the elementary steps? (d) What is the rate- determining step? (e) What is the rate law predicted by this mechanism? (f) What would be the effect on the reac- tion rate of adding PH3 to the solution of (CH3)3AUPH3?
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To answer this question, you'll need to engage with Reaction Explorer. To begin work, click on the link below: Mechanism Explorer: Alcohol Reaction with HBr
115. Subject :- Chemistry

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