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- 4. Isomers and Stereocenters ( (a) Assign each set of molecules as constitutional isomers, conformational isomers, enantiomers, diastereomers, or identical. Please write the full name for the type. Molecules Type (b) H₂Ca HgC.. CH3 OCH₂ CH3 af OCH, SP H₂C**** H₂C H₂C NGOCH, H.C_OCKS OCH₂ CH₂ H₁C HC H*** CI H H CI Br H3C CH₂ Br (d) E) (0) For each of the following molecules, write the number of stereocenters and circle the center of any stereocenters. (i) (ii) H₂C (онт (eg 5) (b) -CH3 Isegna CH3 on mots eno H₂C CH3H3C --CH3 Which structure(s) below represent(s) the diastereoisomer(s) of the compound on the picture? Br CH3 C CH3 A B CH3 H3C 'Br Br CH3 H3C Br CH3 E CH3 --CH3 H3C.. Br Br Br H3C -.None
- Draw a formula for the lowest molecular weight compound that contains C, H, and possibly O, N or 5, is a chiral compound, contains ONLY one functional group, and is a sulfide. Use the wedge/hash bond tools to indicate stereochemistry where it exists. Include H atoms at chiral centers only. If a group is achiral, do not use wedged or hashed bonds on it. Alkene or alkyne groups are considered to be functional groups. 98 4 - /IP ChemDoodleNone* How many maximum numbers of stereoisomers with respect to chiral centers exist? * How many chirality centers exist on the molecule above? identify them
- C. IDENTIFYING STEREOISOMERS: Label each pair of molecules below as enantiomers, diastereomers or identical CO₂H HO HC но-- н H -.Н CH3 OH CH₂OH HO™ H₂OC H₂C Н-- HO Н CH3 OHH CH₂OH HOC-... HOCH₂. H OH H OH HO H CHO COzH ОНС но с HO H COzH Н ОН НО Н CH₂OHBetween these 2 compounds, which one will be (R) and which one is (S) configuration? Please draw to explain your answer in detailed..Which pair of structures are enantiomers? COOH CH3 H HO HOOC OH CH3 H CH2CH3 Br H CH2CH3 Br cl H CH2CH3 CH3 H CH3 HO HO H CH2CH3 II, III I, II, III |, ||| I, II

