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- Following is the Structural formal of Chloropropane H H H 2. H Draw Newman projections for all staggered and eclipsed conformation formed by rotation about C1 - C2 bond from 0° to 360°. b) Which Staggered conformation(s) has the lowest energy; which has the highest energy? c) Which eclipsed conformation(s) has the lowest energy, which has thhe highest energy?Considering structures below, which of the following statements is true? O I H-C-O-CH₂ CH₂OH O || II HOCH₂CH₂-C-OH III HOCH₂CH₂-O-C-H A) I and II have different molecular formulas. B) I and III are structural isomers of each other. C) II and III are stereoisomers of each other. D) II and III are different conformations of the same compound. E) I and III are the same compound.For 1,2-dichloroethane: (a) Draw Newman projections for all eclipsed conformations formed by rotation from 0 to 360° about the carbon-carbon single bond. (b) Which eclipsed conformation(s) has the lowest energy? Which has the highest energy? (c) Which, if any, of these eclipsed conformations are related by reflection?
- Prautice qt#12 For the following compound, draw the appropriate Newman projection along the C1-C2 bond of the following: HE Су a) The most stable conformer and name the conformer. b) The least stable conformer and name the conformer. c) The second most stable conformer and name the conformer.ÇI CH3CH=CHCHCH3 4-chloro-2-pentene Four stereoisomers exist for 4-chloro-2-pentene. Draw the structure of the isomer that has the E configuration around the double bond and the S configuration at the chiral center. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • You do not have to explicitly draw H atoms. • If a group is achiral, do not use wedged or hashed bonds on it.Acetylcholine is a neurotransmitter in the central nervous system in humans. Sighting along the C-C bond, draw Newman projection formulas for all the eclipsed and staggered conformers of acetylcholine. Which among the conformers is the least stable? The most stable? Plot a conformational analysis for these conformers.
- Draw the conformational isomers of 1-bromo-2-chloroethane by rotating C-C single bond with dihedral angel 60°. AndWhy conformational isomers generally can not be separated from one another at room temperature?Use Newman Projections to represent the conformers of 1,2-dichloropropane and 2-bromo-3-methybutane. (Draw the Newman Projections of these conformers and add respective photos in the space provided below) Conformers of 1,2-dichloropropane 2. Conformers of 2-bromo-3-methylbutaneFor 1,2-dichloroethane: a.Draw Newman projections for all eclipsed conformations formed by rotation from 0° to 360° about the carbon-carbon single bond. b.Which eclipsed conformation(s) has (have) the lowest energy? Which has (have) the highest energy? c.Which, if any, of these eclipsed conformations are related by reflection?
- Draw the structure for the most stable chair conformation of trans-1-tert-butyl-3-chlorocyclohexane. Use the cyclohexane conformation drawing tool and guide points to draw each structure. C1 M C™ X ĈChemistry Determine how many substituents in the axial position does the most stable conformer of (1R,2S,4R)-4-bromo-1,2-dimethylcyclohexane have?OH CHзCH-CHCHCH-CHз 4-hexen-3-ol Four stereoisomers exist for 4-hexen-3-ol. Draw the structure of the isomer that has the Z configuration around the double bond and the R configuration at the chiral center. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. You do not have to explicitly draw H atoms. • If a group is achiral, do not use wedged or hashed bonds on it. opy aste Previous Next