Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 5, Problem 7CTQ

On which do you expect to have a more intense and concentrated “hotspot” of negative charge: methoxideion or bicarbonate ion?

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Provide the correct IUPAC name for HBrO₂(aq).     (I) (II) (III) (IV) tri- hepta- penta- mono- octa- di- hexa- tetra- hypobromic hypobromous hydrobromic bromic hydrobromous perbromic perbromous bromous hydrate acid Delete
The bond length of the indicated C-C single bond in hexa-1,3,5-triene is about 146 pm, which is considerably shorter than that in ethane, H3C-CH3. (a) How much shorter is it? Hint: See Figure 14-2, page 685. (b) Which occupied T MOS (obtained in Problem 14.32) help decrease this bond length? (c) If an electron were promoted from the HOMO to the LUMO, would the length of the C-C single bond increase, decrease, or stay roughly the same? Explain. 146 pm
3. According to the Hammond Postulate, what does transition state 3 (TS3) most closely resemble? First choice: Second choice: AG (a) TS2 (b) P (c) 12 (d) 11 TS2 TS1 M 11 Reaction Coordinate 12 TS3

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Organic Chemistry: A Guided Inquiry

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