Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 5, Problem 23CTQ
Interpretation Introduction
Interpretation: Whether
Concept introduction: The dissociation constant of acid represents strength of acid in solution. It is denoted by
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hydrogens on a carbon adjacent to a carbonyl group are far
more acidic than those not adjacent to a carbonyl group. The anion derived from acetone,
for example, is more stable than is the anion derived from ethane. Account for the greater
stability of the anion from acetone.
CH,ČCH, H
CH,CH, H
Acetone
Ethane
pK, 20.2
pK, 51
Between the compounds A and B, which one has lower pKa value and why?
Hc Hc
Ha Ha
A
6. Which of the following compounds has the lowest pKa ?
A
OH
NH
B
XOH
OH
C
X
D
NH₂
Chapter 5 Solutions
Organic Chemistry: A Guided Inquiry
Ch. 5 - Which elements on the periodic table (other than...Ch. 5 - You will not find “hydroxide” in the stockroom,...Ch. 5 - Prob. 3CTQCh. 5 - Prob. 4CTQCh. 5 - Prob. 5CTQCh. 5 - Prob. 6CTQCh. 5 - On which do you expect to have a more intense and...Ch. 5 - Prob. 8CTQCh. 5 - Prob. 9CTQCh. 5 - Prob. 10CTQ
Ch. 5 - Prob. 11CTQCh. 5 - Prob. 12CTQCh. 5 - Prob. 13CTQCh. 5 - Prob. 14CTQCh. 5 - Prob. 15CTQCh. 5 - Prob. 16CTQCh. 5 - For each proposed set of resonance structures: a....Ch. 5 - Consider the polarization of the C=O bond in the...Ch. 5 - The C=O double bond is called a “carbonyl bond.”...Ch. 5 - Prob. 20CTQCh. 5 - Prob. 21CTQCh. 5 - Prob. 22CTQCh. 5 - Prob. 23CTQCh. 5 - Prob. 24CTQCh. 5 - Prob. 25CTQCh. 5 - Prob. 26CTQCh. 5 - Prob. 27CTQCh. 5 - Prob. 28CTQCh. 5 - Prob. 29CTQCh. 5 - Prob. 30CTQCh. 5 - Prob. 31CTQCh. 5 - Confirm that there is no legitimate Lewis...Ch. 5 - Draw all resonance structures of the molecule...Ch. 5 - Prob. 34CTQCh. 5 - Prob. 35CTQCh. 5 - Prob. 36CTQCh. 5 - Occasionally, we will see an ionic compound that...Ch. 5 - Prob. 2ECh. 5 - Prob. 3ECh. 5 - Prob. 4ECh. 5 - Is it possible to draw a resonance structure of...Ch. 5 - Prob. 6ECh. 5 - Prob. 7ECh. 5 - Prob. 8ECh. 5 - Phenol (shown below) has a pKa10 . a. Based on pKa...Ch. 5 - Use curved arrows to show the most likely...Ch. 5 - Prob. 12ECh. 5 - Complete each Lewis structure, draw all important...Ch. 5 - Use curved arrows to show the most likely...Ch. 5 - Construct an explanation for why sulfuric acid is...Ch. 5 - Prob. 16ECh. 5 - Prob. 17ECh. 5 - Prob. 18E
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- For each molecule below, draw the conjugate acid or conjugate base or both if the molecule hasboth a conjugate acid and a conjugate base (e.g., water).arrow_forwardPlease don't provide handwriting solutionarrow_forwardUsing pKa Values to Determine Relative Acidity and Basicity Rank the following compounds in order of increasing acidity, and then rank their conjugate bases in order of increasing basicity.arrow_forward
- For the following acid-base reaction, predict the position of the equilibrium and identify the most stable base. + NaOH || A. favor the right side with compound I being the most stable base B. favor the right side with compound II being the most stable base OC. favor the right side with compound III being the most stable base OD. favor the left side with compound I being the most stable base E. favor the left side with compound II being the most stable base سمیر ||| + H₂O IVarrow_forwardMcq also give some explanationarrow_forwardI need help with thisarrow_forward
- Predict the intermediate (A) and Reagent (B) in the reaction sequence below.arrow_forwardWhat is the conjugate base of the following acids? 7) HSO4^1- 8) H2PO4^1- 9) H2SO3arrow_forwardConsider two acids: C,H5CO,H (benzoic acid, pK = 4.2) and HCO,H (formic acid, pK=3.8). Which acid is the stronger acid? Select the single best answer. formic acid benzoic acidarrow_forward
- 2. Consider the following equilibrium: H₂O(l) + HC₂H₂O₂(aq)=H₂O*(aq) + C₂H₂O₂(aq) Why will the addition of NaOH to a solution of acetic acid cause the concentration of the acetate ion to increase? ringarrow_forwardWhich cation, Q or R, do you think is the stronger acid? Why?arrow_forwardUse the information in the pK table to rank the molecules in order of decreasing basicity. For example, select "1" in the second column for the strongest base a and "2" for the next strongest base and so on. CH3 HS F CH,CO, Molecules (Choose one) (Choose one) (Choose one) (Choose one) X Ś CHA 4 NH₂ H₂ CH3NH₂ 2 48 38 36 33 pk table pKa CH,NH, CH₂SH 10.4 H₂O* HCN + 10.6 9.4 NH H₂O 15.7 H₂S CH₂OH 15.5 CH,CO,H 4.76 9.2 7.00 HF CH₂OH₂ H₂SO4 HC1 HBr 3.17 -1.7 -2.2 -3.0 -7 -9arrow_forward
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