Chemical Principles
8th Edition
ISBN: 9781337247269
Author: Steven S. Zumdahl; Donald J. DeCoste
Publisher: Cengage Learning US
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Chapter 21, Problem 25E
Interpretation Introduction
Interpretation: The cis and trans isomers of
Concept introduction: Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.
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You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products:
xi
1. ☑
2. H₂O
хе
i
Draw the missing reagent X you think will make this synthesis work in the drawing area below.
If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank.
Click and drag to start drawing a
structure.
There is no reagent that will make this synthesis work without complications.
: ☐
S
☐
Predict the major products of this organic reaction:
H
OH
1. LiAlH4
2. H₂O
?
Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry.
Click and drag to start drawing a
structure.
G
C
टे
For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first
stable product you expect to form in solution.
NH2
CI
MgCl
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
G
टे
Chapter 21 Solutions
Chemical Principles
Ch. 21 - Prob. 1ECh. 21 - Prob. 2ECh. 21 - Why are cyclopropane and cyclobutane so reactive?Ch. 21 - Prob. 4ECh. 21 - Prob. 5ECh. 21 - Prob. 6ECh. 21 - Prob. 7ECh. 21 - Name the five structural isomers of C6H14 .Ch. 21 - Draw the structural formula for each of the...Ch. 21 - Prob. 10E
Ch. 21 - Prob. 11ECh. 21 - Name each of the following cyclic alkanes, and...Ch. 21 - Prob. 13ECh. 21 - Prob. 14ECh. 21 - Prob. 15ECh. 21 - Prob. 16ECh. 21 - Prob. 17ECh. 21 - Prob. 18ECh. 21 - Prob. 19ECh. 21 - Prob. 20ECh. 21 - Prob. 21ECh. 21 - Prob. 22ECh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Name the following compounds.Ch. 21 - Prob. 32ECh. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Prob. 38ECh. 21 - Prob. 39ECh. 21 - Prob. 40ECh. 21 - Prob. 41ECh. 21 - Draw structural formulas for each of the following...Ch. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - Prob. 45ECh. 21 - Prob. 46ECh. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - Prob. 53ECh. 21 - Prob. 54ECh. 21 - Prob. 55ECh. 21 - Prob. 56ECh. 21 - Prob. 57ECh. 21 - Prob. 58ECh. 21 - Prob. 59ECh. 21 - Give an example reaction that would yield the...Ch. 21 - Prob. 61ECh. 21 - Prob. 62ECh. 21 - Prob. 63ECh. 21 - Prob. 64ECh. 21 - Prob. 65ECh. 21 - Prob. 66ECh. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Prob. 69ECh. 21 - Prob. 70ECh. 21 - Prob. 71ECh. 21 - Prob. 72ECh. 21 - Prob. 73ECh. 21 - Prob. 74ECh. 21 - Prob. 75ECh. 21 - Prob. 76ECh. 21 - Prob. 77ECh. 21 - Prob. 78ECh. 21 - Prob. 79ECh. 21 - Prob. 80ECh. 21 - Prob. 81ECh. 21 - Prob. 82ECh. 21 - Prob. 83ECh. 21 - Prob. 84ECh. 21 - Prob. 85ECh. 21 - Prob. 86ECh. 21 - Prob. 87ECh. 21 - Prob. 88ECh. 21 - Prob. 89ECh. 21 - Prob. 90ECh. 21 - Prob. 91ECh. 21 - Prob. 92ECh. 21 - Prob. 93ECh. 21 - Prob. 94ECh. 21 - Prob. 95ECh. 21 - Draw the structures of the tripeptides gly-ala-ser...Ch. 21 - Prob. 97ECh. 21 - Prob. 98ECh. 21 - What types of interactions can occur between the...Ch. 21 - Prob. 100ECh. 21 - Prob. 101ECh. 21 - Prob. 102ECh. 21 - Prob. 103ECh. 21 - Prob. 104ECh. 21 - Prob. 105ECh. 21 - Prob. 106ECh. 21 - Prob. 107ECh. 21 - Prob. 108ECh. 21 - Prob. 109ECh. 21 - Prob. 110ECh. 21 - Prob. 111ECh. 21 - Prob. 112ECh. 21 - Prob. 113ECh. 21 - Prob. 114ECh. 21 - Prob. 115ECh. 21 - Prob. 116ECh. 21 - Prob. 117ECh. 21 - Prob. 118ECh. 21 - Prob. 119ECh. 21 - Prob. 120ECh. 21 - Prob. 121ECh. 21 - Prob. 122ECh. 21 - Prob. 123ECh. 21 - Prob. 124ECh. 21 - Prob. 125ECh. 21 - Prob. 126ECh. 21 - Prob. 127AECh. 21 - Prob. 128AECh. 21 - Prob. 129AECh. 21 - Prob. 130AECh. 21 - Prob. 131AECh. 21 - Prob. 132AECh. 21 - Prob. 133AECh. 21 - Prob. 134AECh. 21 - Prob. 135AECh. 21 - Prob. 136AECh. 21 - Prob. 137AECh. 21 - Prob. 138AECh. 21 - Prob. 139AECh. 21 - Prob. 140AECh. 21 - Prob. 141AECh. 21 - Prob. 142AECh. 21 - Prob. 143AECh. 21 - Prob. 144AECh. 21 - Prob. 145AECh. 21 - Prob. 146AECh. 21 - Prob. 147AECh. 21 - Prob. 148AECh. 21 - Prob. 149AECh. 21 - Prob. 150AECh. 21 - Prob. 151AECh. 21 - Prob. 152AECh. 21 - Prob. 153AECh. 21 - Prob. 154AECh. 21 - Prob. 155AECh. 21 - Prob. 156AECh. 21 - Prob. 157AECh. 21 - Prob. 158AECh. 21 - Prob. 159AECh. 21 - Prob. 160AECh. 21 - Prob. 161AECh. 21 - Name each of the following cyclic alkanes.Ch. 21 - Prob. 163AECh. 21 - Prob. 164AECh. 21 - Prob. 165AECh. 21 - Prob. 166AECh. 21 - Prob. 167AECh. 21 - Prob. 168AECh. 21 - Prob. 169CPCh. 21 - Prob. 170CPCh. 21 - Prob. 171CPCh. 21 - Prob. 172CPCh. 21 - Prob. 173CPCh. 21 - Prob. 174CP
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- For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. དྲ。 ✗MgBr ? O CI Will the first product that forms in this reaction create a new C-C bond? Yes No • ? Will the first product that forms in this reaction create a new CC bond? Yes No × : ☐ Xarrow_forwardPredict the major products of this organic reaction: OH NaBH4 H ? CH3OH Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. ☐ : Sarrow_forwardPredict the major products of this organic reaction: 1. LIAIHA 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. X : ☐arrow_forward
- For each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 tu ? ? OH Will the first product that forms in this reaction create a new CC bond? Yes No Will the first product that forms in this reaction create a new CC bond? Yes No C $ ©arrow_forwardAs the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C-C bond as its major product: 1. MgCl ? 2. H₂O* If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new CC bond. G marrow_forwardIncluding activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M NH4 Ksp Hg2Br2 = 5.6×10-23.arrow_forward
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