A
Interpretation : The structure of the product of the given reaction needs to be determined.
Concept Introduction : The reaction is substitution reaction in which one group of the compound is replaced by the other group or atom.
B
Interpretation : The structure of the product of the given reaction needs to be determined.
Concept Introduction : The reaction is substitution reaction in which one group of the compound is replaced by the other group or atom.
C
Interpretation : The structure of the product of the given reaction needs to be determined.
Concept Introduction : The reaction is substitution reaction in which one group of the compound is replaced by the other group or atom.
D
Interpretation : The structure of the product of the given reaction needs to be determined.
Concept Introduction : The reaction is substitution reaction in which one group of the compound is replaced by the other group or atom.
E
Interpretation : The structure of the product of the given reaction needs to be determined.
Concept Introduction : The reaction is substitution reaction in which one group of the compound is replaced by the other group or atom.
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Chapter 21 Solutions
Chemical Principles
- Alcohols are very useful starting materials for the production of many different compounds. The following conversions, starting with 1-butanol, can be carried out in two or more steps. Show the steps (reactants/catalysts) you would follow to carry out the conversions, drawing the formula for the organic product in each step. For each step, a major product must be produced. (See Exercise 62.) (Hint: In the presence of H+, an alcohol is converted into an alkene and water. This is the exact reverse of the reaction of adding water to an alkene to form an alcohol.) a. 1-butanol butane b. 1-butanol 2-butanonearrow_forward. With very reactive agents, such as the halogen elements, alkanes undergo reactions, whereby a new atom rep laces one or more hydrogen atoms of the alkane.arrow_forward. Write the equation for the synthesis of ethanol from ethylene. What are some commercial uses of ethanol made by this process?arrow_forward
- For each of the following alcohols, give the systematic name and specify whether the alcohol is primary, secondary, or tertiary. a. b. c.arrow_forwardWrite the structure of the product formed in the following oxidation-reduction reactions. Label the functional group in the reactant that changes, and identify the new functional group in the product. If the functional group is an alcohol, identify the type of alcohol. If there is no reaction, state so. 54 Ac a. H. ОНН Н [O] Н-С-С—С-С-Н of H. ННН b. НННС 84 Н-С-С-С--С--Н ННН C. НННН [0] form НО-С-С-С-С-Н H HH H Hd. HO [H] pertortm e. [0] ОН কনarrow_forwardBased on the choices presented below (labeled for your convenience) which alcohol is a "Tertiary" alcohol? HỌ CHO A B OA. Compound #A O B. Compound #B OC. Compound #C -OH OH 8/0 Uarrow_forward
- Predict the products of the following reaction. If no reaction will occur, use the NO REACTION button. Be sure your chemical equation is balanced! CH₂CH₂(CH) CH₂CH₂(1) + O₂(g) → [] 00 X NO REACTION Sarrow_forwardIdentify the following reaction as addition, elimination, substitution, oxidation or reduction (please explain)arrow_forward22 The oxidation of glucose with a weak oxidizing agent (Benedict) results in the formation of a primary alcohol on carbon #1 (CH,OH) a carboxylic acid at carbon #6 (COOH) O a bydrogenated carbon at carbon #1 (CH,OH) a carboxylic acid at carbon #1 (COOH) a carboxylic acid at both carbons #1 and #6 (COOH)arrow_forward
- ORGANIC CHEMISTRY Explain the following transformations.arrow_forwardA. Indicate the appropriate chemical name for each of the following structures. OMe a) Et- (CH2)&CO(CH2).CHO H b) Me(CH2)6C=C(CH2)10CON-Buarrow_forward1. Dehydration: 2. Oxidation: This is a reaction where an alcohol loses a water molecule to form an alkene. For example, when ethanol is treated with an acidic catalyst, such as sulfuric acid, it undergoes dehydration to form ethene (CH2=CH2) and water. ALCOHOLS In this reaction, an alcohol is converted to either a carbonyl compound or a carboxylic acid. 3. Esterification: Types of Reaction (s) For example, primary alcohols can be oxidized to aldehydes or carboxylic acids, while secondary alcohols can be oxidized to ketones. Tertiary alcohols are usually not affected by oxidations 4. Substitution: The conversion of an alcohol and a carboxylic acid to an ester and water, in the presence of an acid catalyst. The reaction between methanol and acetic acid to form methyl acetate: CH3OH + CH3COOH CH3COOCH3 + H2O Click to add speaker notes ME Substitution reactions in organic chemistry involve the replacement of one atom or group of atoms with another atom or group of atoms in a molecule. 1.…arrow_forward
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