Concept explainers
(a)
Interpretation:
The structural formula for 1-Bromo-2-chloro-4-ethylbenzene has to be drawn.
(b)
Interpretation:
The structural formula for m-Nitrocumene has to be drawn.
(c)
Interpretation:
The structural formula for 4-Chloro-1,2-dimethyl benzene has to be drawn.
(d)
Interpretation:
The structural formula for 3,5-Dinitrotoluene has to be drawn.
(e)
Interpretation:
The structural formula for 2,4,6-Trinitrotoluene has to be drawn.
(f)
Interpretation:
The structural formula for (2S,4R)-4-Phenyl-2-pentanol has to be drawn.
(g)
Interpretation:
The structural formula for p-Cresol has to be drawn.
(h)
Interpretation:
The structural formula for pentachlorophenol has to be drawn.
(i)
Interpretation:
The structural formula for 1-Phenylcyclopropanol has to be drawn.
(j)
Interpretation:
The structural formula for Triphenylmethane has to be drawn.
(k)
Interpretation:
The structural formula for Phenylethylene (styrene) has to be drawn.
(l)
Interpretation:
The structural formula for benzyl bromide has to be drawn.
Concept Introduction:
Structural formula gives information about how the atoms are arranged in a molecule.
(m)
Interpretation:
The structural formula for 1-Phenyl-1-butyne has to be drawn.
(n)
Interpretation:
The structural formula for (E)-3-Phenyl-2-propen-1-ol has to be drawn.
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Chapter 21 Solutions
Organic Chemistry
- Show how you might synthesize the following compounds starting with bromobenzene, andalkyl or alkenyl halides of four carbon atoms or fewer.(a) 3-phenylprop-1-ene (b) 5-methylhex-2-ene *(c) dec-5-enearrow_forward13 Draw a structural formula for each compound. (a) 3-Chloropropene (b) 3-Methylcyclohexene (c) 1,2-Dimethylcyclohexene (d) trans-3,4-Dimethyl-3-heptene (e) Cyclopropene (f) 3-Hexynearrow_forwardWrite the reagent or draw structures of the starting material or organic product(s) in the following reactions. If more than one product is formed, identify the major product where possible. (a) (b) HO OH OH H2SO4 ? Cl₂ ? FeCl3arrow_forward
- (a) Chromic acid oxidation of 4-tert-butyl-1,2-dimethylbenzene yielded a single compound having the molecular formula C12H14O4. What was this compound?(b) What product is expected from chromic acid oxidation of 2,3-dihydroindene?arrow_forwardDraw the structure that corresponds with each name.(a) 3-ethyloctane (b) 4-isopropyldecane (c) sec-butylcycloheptane(d) 2,3-dimethyl-4-propylnonane (e) 2,2,4,4-tetramethylhexane (f) trans-1,3-diethylcyclopentane(g) cis-1-ethyl-4-methylcyclohexane (h) isobutylcyclopentane (i) tert-butylcyclohexane(j) pentylcyclohexane (k) cyclobutylcyclohexane (l) cis-1-bromo-3-chlorocyclohexanearrow_forwardDraw structures corresponding to the following IUPAC names: (a) p-Bromochlorobenzene (c) m-Chloroaniline (b) p-Bromatolvene (d) 1-Chloro-3,5-dimethylbenzenearrow_forward
- Write bond-line formulas for the following: (a) cis-3-Octene (b) trans-2-Hexene (c) 2,4-Dimethyl-2-pentene (d) trans-1-Chlorobut-2-ene (e) 4,5-Dibromo-l-pentenearrow_forwardDraw the structures of the following compounds:(i) 4-chloropentan-2-one (ii) But-2-en-l-alarrow_forwardFor each alkane, which mono brominated derivatives could you form in good yield by free-radical bromination?(a) cyclopentane (b) methylcyclopentane(c) 2-methylpentane (d) 2,2,3,3-tetramethylbutanearrow_forward
- Draw structural formulas of the following in a condensed formarrow_forwardand (ii) KMnO4 in aqueous NaOH: 1. Name the following alkenes, and predict the products of their reaction with (i) KMnO4 in aqueous acid (a) (b) 2. Draw structures corresponding to the following IUPAC names: (a) 3-Ethylhept-1-yne (b) 3,5-Dimethylhex-4-en-1-yne (c) Hepta-1,5-diyne (d) 1-Methylcyclopenta-1,3-diene (1) 3. Draw and name all the possible pentyne isomers, C5H8. H H Ç-H [ Pent-1-yne] (2) 4. Predict the products of the following ring is inert to all the indicated reagents.) 4 H 4- (3) 4-C C = C-4 [3-methylbut -1-4 [Pent-2-yhdioselectivity where relevant. (The aromatic CH=CH2 Styrene (a) Styrene+H2 Pd, ? (c) Styrene+HBr ? (b) Styrene+Br2 → ? (d) Styrene+KMnO4 NaOH, H2O ? 5. Suggest structures for alkenes that give the following reaction products. There may be more than one answer for some cases. HyPd catalyst (a) ? Br₂ in CH2Cl2 (b) ? HBr (c) ? 2-Methylhexane 2,3-Dibromo-5-methylhexane 2-Bromo-3-methylheptane CH3 HO OH CH3CHCH2CHCHCH2CH3 KMnO4OH (d) ? H₂Oarrow_forwardPLEASE HELP WITH A),B) AND C)arrow_forward
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