The synthesis of atenolol has to be shown. Concept introduction: Esterification: Esterification reaction is the reaction of acid react with excess of alcohol in the presence of either acid or base catalyst to forms an ester.

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Answer 1

Question

Chapter 21, Problem 21.59P

(a)

Interpretation Introduction

Interpretation:

The synthesis of atenolol has to be shown.

Concept introduction:

Esterification: Esterification reaction is the reaction of acid react with excess of alcohol in the presence of either acid or base catalyst to forms an ester.

(b)

Interpretation Introduction

Interpretation:

The reason is to be explained for the amination of ester rather than acid chloride to ester.

(c)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

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Will NBS (and heat or light) work for this reaction, or do we have to use Br2?

HAND DRAW

Predict the major products of the following organic reaction: Some important notes: Δ CN ? • Draw the major product, or products, of the reaction in the drawing area below. • If there aren't any products, because no reaction will take place, check the box below the drawing area instead. Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. ONO reaction. Click and drag to start drawing a structure.

Answer 2

Question

Chapter 21, Problem 21.59P

(a)

Interpretation Introduction

Interpretation:

The synthesis of atenolol has to be shown.

Concept introduction:

Esterification: Esterification reaction is the reaction of acid react with excess of alcohol in the presence of either acid or base catalyst to forms an ester.

(b)

Interpretation Introduction

Interpretation:

The reason is to be explained for the amination of ester rather than acid chloride to ester.

(c)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

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Answer 3

Question

Chapter 21, Problem 21.59P

(a)

Interpretation Introduction

Interpretation:

The synthesis of atenolol has to be shown.

Concept introduction:

Esterification: Esterification reaction is the reaction of acid react with excess of alcohol in the presence of either acid or base catalyst to forms an ester.

(b)

Interpretation Introduction

Interpretation:

The reason is to be explained for the amination of ester rather than acid chloride to ester.

(c)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

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Answer 4

Question

Chapter 21, Problem 21.59P

(a)

Interpretation Introduction

Interpretation:

The synthesis of atenolol has to be shown.

Concept introduction:

Esterification: Esterification reaction is the reaction of acid react with excess of alcohol in the presence of either acid or base catalyst to forms an ester.

(b)

Interpretation Introduction

Interpretation:

The reason is to be explained for the amination of ester rather than acid chloride to ester.

(c)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

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Answer 5

Chapter 21, Problem 21.59P

(a)

Interpretation Introduction

Interpretation:

The synthesis of atenolol has to be shown.

Concept introduction:

Esterification: Esterification reaction is the reaction of acid react with excess of alcohol in the presence of either acid or base catalyst to forms an ester.

(b)

Interpretation Introduction

Interpretation:

The reason is to be explained for the amination of ester rather than acid chloride to ester.

(c)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Answer 6

Chapter 21, Problem 21.59P

(a)

Interpretation Introduction

Interpretation:

The synthesis of atenolol has to be shown.

Concept introduction:

Esterification: Esterification reaction is the reaction of acid react with excess of alcohol in the presence of either acid or base catalyst to forms an ester.

Answer 7

Chapter 21, Problem 21.59P

(a)

Interpretation Introduction

Interpretation:

The synthesis of atenolol has to be shown.

Concept introduction:

Esterification: Esterification reaction is the reaction of acid react with excess of alcohol in the presence of either acid or base catalyst to forms an ester.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The reason is to be explained for the amination of ester rather than acid chloride to ester.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The reason is to be explained for the amination of ester rather than acid chloride to ester.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21.2 - Construct a Frost circle for a planar...Ch. 21.2 - Which compound gives a signal in the 1H-NMR...Ch. 21.2 - Prob. 21.3P Ch. 21.2 - Prob. 21.4P Ch. 21.3 - Prob. 21.5P Ch. 21.4 - Arrange these compounds in order of increasing...Ch. 21.4 - Prob. AQ Ch. 21.4 - Prob. BQ Ch. 21.4 - Prob. CQ Ch. 21.5 - Prob. 21.7P

The synthesis of atenolol has to be shown. Concept introduction: Esterification: Esterification reaction is the reaction of acid react with excess of alcohol in the presence of either acid or base catalyst to forms an ester.

Interpretation: The synthesis of atenolol has to be shown. Concept introduction: Esterification: Esterification reaction is the reaction of acid react with excess of alcohol in the presence of either acid or base catalyst to forms an ester.

Interpretation: The reason is to be explained for the amination of ester rather than acid chloride to ester.

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Chapter 21 Solutions

Interpretation:

The synthesis of atenolol has to be shown.

Concept introduction:

Esterification: Esterification reaction is the reaction of acid react with excess of alcohol in the presence of either acid or base catalyst to forms an ester.

Interpretation:

The reason is to be explained for the amination of ester rather than acid chloride to ester.