The strucutral formula of the given compound K has to be decucted with the help of the given 1 H, 13 C NMR spectral datas. Concept Introduction: The 1 H N M R spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule. The splitting of signals by the ( N+1 ) rule predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. With this information, the structure of the compound can be predicted. Chemical shift: The NMR spectrum of any compound is taken with reference to a standard compound called reference compound. Generally, tetramethylsilane (TMS) is taken as the reference compound. The methyl protons of TMS are equivalent and produces only one sharp peak at the rightmost end of the scale. 13 C NMR Spectroscopy: This type of NMR splitting of signals tells us numbers of hydrogens atoms are attached to each carbon. The triangle rule (n+1) C. The chemical shift explains the different hybridization ( s p 3 , s p 2 , s p . , ) of each carbon atoms. Moreover the chemical shift in carbon NMR spectra arises in the same way as in the 1 H NMR spectrum.

Question

110. Compare the pressures given by (a) the ideal gas law, (b) the van der Waals equation, and (c) the Redlic-Kwong equation for propane at 400 K and p = 10.62 mol dm³. The van der Waals parameters for propane are a = 9.3919 dm6 bar mol-2 and b = 0.090494 dm³ mol−1. The Redlich-Kwong parameters are A = 183.02 dm bar mol-2 and B = 0.062723 dm³ mol-1. The experimental value is 400 bar.

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Question

Chapter 21, Problem 21.29P

Interpretation Introduction

Interpretation:

The strucutral formula of the given compound K has to be decucted with the help of the given 1H, 13C NMR spectral datas.

Concept Introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule. The splitting of signals by the (N+1) rule predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. With this information, the structure of the compound can be predicted.

Chemical shift: The NMR spectrum of any compound is taken with reference to a standard compound called reference compound. Generally, tetramethylsilane (TMS) is taken as the reference compound. The methyl protons of TMS are equivalent and produces only one sharp peak at the rightmost end of the scale.

¹³C NMR Spectroscopy: This type of NMR splitting of signals tells us numbers of hydrogens atoms are attached to each carbon. The triangle rule (n+1) C. The chemical shift explains the different hybridization (sp3, sp2, sp.,) of each carbon atoms. Moreover the chemical shift in carbon NMR spectra arises in the same way as in the ¹H NMR spectrum.

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