The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Question

Want to see the full answer?

Answer 1

Question

Chapter 21, Problem 21.57P

(a)

Interpretation Introduction

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

(b)

Interpretation Introduction

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

(c)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

(d)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

(e)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

PLEASE READ!!! I DONT WANT EXAMPLES, I DONT WANT WORDS OR PARAGRAPHS!!! PLEASE I UNDERSTAND THE BASICS BUT THIS IS AN EXCEPTION THAT EVEN THE INTERNET CANT HELP!!!! THIS IS THE THIRD TIME I'VE SENT THOSE QUESTIONS SO PLEASE DONT RESEND THE SAME STUFF, ITS NOT HELPING ME!!! I ALSO ALREADY TRIED TO DRAW THE MECHANISM MYSELF, SO IF ITS RIGHT PLEASE TELL ME OR TELL ME WHAT I HAVE TO CHANGE!!! First image: I have to SHOW (DRAWING) the mechanism (with arows and structures of molecules) NOT WORDS PLEASE! of the reaction at the bottom. Also I have to show by mecanism why the reaction wouldn't work if the alcohol was primary Second image: I have to show the mechanism (IMAGE) (with arrows and structures of the molecules) NOT WORDS PLEASE !! for the reaction on the left, where the alcohol A is added fast in one portion HOMEWORK, NOT EXAM!! ALL DETAILS ARE IN THE IMAGES PLEASE LOOK AT THE IMAGES, DONT LOOK AT THE AI GENERATED TEXT!!!

Write the molecular formula for a compound with the possible elements C, H, N and O that exhibits a molecular ion at M+ = 85.0899. Exact Masses of the Most Abundant Isotope of Selected Elements Isotope Natural abundance (%) Exact mass 1H 99.985 1.008 12C 98.90 12.000 14N 99.63 14.003 160 99.76 15.995 Molecular formula (In the order CHNO, with no subscripts)

Use the data below from an electron impact mass spectrum of a pure compound to deduce its structure. Draw your structure in the drawing window. Data selected from the NIST WebBook, https://webbook.nist.gov/chemistry/ m/z Relative intensity 59 3.0 58 64 43 100 15 23 • You do not have to consider stereochemistry. •You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. + n[] 85 // ? CH4 Previous Next

Answer 2

Question

Chapter 21, Problem 21.57P

(a)

Interpretation Introduction

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

(b)

Interpretation Introduction

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

(c)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

(d)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

(e)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 21, Problem 21.57P

(a)

Interpretation Introduction

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

(b)

Interpretation Introduction

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

(c)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

(d)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

(e)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 21, Problem 21.57P

(a)

Interpretation Introduction

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

(b)

Interpretation Introduction

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

(c)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

(d)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

(e)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 21, Problem 21.57P

(a)

Interpretation Introduction

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

(b)

Interpretation Introduction

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

(c)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

(d)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

(e)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Answer 6

Chapter 21, Problem 21.57P

(a)

Interpretation Introduction

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Answer 7

Chapter 21, Problem 21.57P

(a)

Interpretation Introduction

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Answer 16

Expert Solution & Answer

Answer 17

Expert Solution & Answer

Answer 18

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 19

Ch. 21.2 - Construct a Frost circle for a planar...Ch. 21.2 - Which compound gives a signal in the 1H-NMR...Ch. 21.2 - Prob. 21.3P Ch. 21.2 - Prob. 21.4P Ch. 21.3 - Prob. 21.5P Ch. 21.4 - Arrange these compounds in order of increasing...Ch. 21.4 - Prob. AQ Ch. 21.4 - Prob. BQ Ch. 21.4 - Prob. CQ Ch. 21.5 - Prob. 21.7P

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Solution Summary: The author explains the mechanism for the conversion of A to B and B to C, and the importance of introducing benzyl group in chloramine.

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

Want to see the full answer?

Chapter 21 Solutions

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Solution Summary: The author explains the mechanism for the conversion of A to B and B to C, and the importance of introducing benzyl group in chloramine.

Interpretation: The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Interpretation: The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

Interpretation: The reagent has to be proposed for the conversion of D to E for removing benzyl group. Concept introduction: Hydrogenolysis: Amine or alcohol reaction with H2 in the presence of a transition Metal catalyst gives the corresponding amine or alcohol.

Interpretation: The reagent has to be proposed for the conversion of E to bidisomide.

Want to see the full answer?

Chapter 21 Solutions

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.