The VSEPR formula of ClO 2 − has to be given. Concept Introduction: Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows: Steric number Number of lone pairs Molecular geometry Bond angles 2 0 Linear 180 ° 3 0 1 Trigonal planar Bent 120 ° 4 0 1 2 Tetrahedral Trigonal pyramidal Bent 109.5 ° 5 0 1 2 3 Trigonal Bi-pyramidal See-Saw T-shaped Linear 90 ° ,120 ° , 180 ° 6 0 1 2 Octahedral Square pyramidal Square planar 90 ° , 180 °

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Answer 1

Question

Chapter 2, Problem 2E.3BST

(b)

Interpretation Introduction

Interpretation:

The VSEPR formula of ClO2− has to be given.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

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> You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: 1. ☑ CI 2. H3O+ O Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. Explanation Check ? DO 18 Ar B © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility

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Consider a solution of 0.00304 moles of 4-nitrobenzoic acid (pKa = 3.442) dissolved in 25 mL water and titrated with 0.0991 M NaOH. Calculate the pH at the equivalence point

Answer 2

Question

Chapter 2, Problem 2E.3BST

(b)

Interpretation Introduction

Interpretation:

The VSEPR formula of ClO2− has to be given.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

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Answer 3

Question

Chapter 2, Problem 2E.3BST

(b)

Interpretation Introduction

Interpretation:

The VSEPR formula of ClO2− has to be given.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

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See solution

Answer 4

Question

Chapter 2, Problem 2E.3BST

(b)

Interpretation Introduction

Interpretation:

The VSEPR formula of ClO2− has to be given.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

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Answer 5

Chapter 2, Problem 2E.3BST

(b)

Interpretation Introduction

Interpretation:

The VSEPR formula of ClO2− has to be given.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 2, Problem 2E.3BST

(b)

Interpretation Introduction

Interpretation:

The VSEPR formula of ClO2− has to be given.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

Answer 7

Chapter 2, Problem 2E.3BST

(b)

Interpretation Introduction

Interpretation:

The VSEPR formula of ClO2− has to be given.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

Answer 8

(b)

Interpretation Introduction

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 2 - Prob. 2A.1AST Ch. 2 - Prob. 2A.1BST Ch. 2 - Prob. 2A.2AST Ch. 2 - Prob. 2A.2BST Ch. 2 - Prob. 2A.3AST Ch. 2 - Prob. 2A.3BST Ch. 2 - Prob. 2A.4AST Ch. 2 - Prob. 2A.4BST Ch. 2 - Prob. 2A.1E Ch. 2 - Prob. 2A.2E

Solution Summary: The author explains that the Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion.

Concept explainers

Videos

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Want to see the full answer?

Chapter 2 Solutions

Solution Summary: The author explains that the Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion.

Concept explainers

Videos

Interpretation: The electron arrangement of ClO2− has to be predicted. Concept Introduction: Refer to part (a).

Interpretation: The shape of ClO2− has to be predicted. Concept Introduction: Refer to part (a).

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Chapter 2 Solutions

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).