(a) Explanation The molecular electronic configuration of CF is, CF= ( σ1s ) 2 ( σ * 1s ) 2 ( σ2s ) 2 ( σ * 2s ) 2 ( σ2p ) 2 ( π2p x ) 2 = ( π2p y ) 2 ( π2p x ) 1 The bond order of CF is calculated as, Bond order= 10-5 2 Bond order= 2 .5 The bond order of CF is 2 (b) Interpretation Introduction Interpretation: The species that may be diamagnetic has to be predicted and the reason has to be explained.

Chemical Principles: The Quest for Insight

7th Edition

ISBN: 9781464183959

Author: Peter Atkins, Loretta Jones, Leroy Laverman

Publisher: W. H. Freeman

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Quantum Mechanical Treatment of the Valence Bond Theory

Quantum mechanical treatment of valence bond theory refers to the relationship established between the quantum mechanical theory and the valence bond theory to describe the chemical bonding in a particular molecule.

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Chapter 2, Problem 2.33E

(a)

Interpretation Introduction

Interpretation:

The molecules (CF+,CF,CF-) have to arranged in the increasing C-F bond length.

(b)

Interpretation Introduction

Interpretation:

The species that may be diamagnetic has to be predicted and the reason has to be explained.

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Chapter 2, Problem 2.32E

Chapter 2, Problem 2.34E

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Question 4 Determine the rate order and rate constant for sucrose hydrolysis. Time (hours) [C6H12O6] 0 0.501 0.500 0.451 1.00 0.404 1.50 0.363 3.00 0.267 First-order, k = 0.210 hour 1 First-order, k = 0.0912 hour 1 O Second-order, k = 0.590 M1 hour 1 O Zero-order, k = 0.0770 M/hour O Zero-order, k = 0.4896 M/hour O Second-order, k = 1.93 M-1-hour 1 10 pts

Determine the rate order and rate constant for sucrose hydrolysis. Time (hours) [C6H12O6] 0 0.501 0.500 0.451 1.00 0.404 1.50 0.363 3.00 0.267

Chapter 2 Solutions

Chemical Principles: The Quest for Insight

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The molecules ( CF + ,CF,CF - ) have to arranged in the increasing C-F bond length.

Solution Summary: The author explains that the molecules C-F have to be arranged in the increasing bond length.

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Interpretation:

The molecules (CF+,CF,CF-) have to arranged in the increasing C-F bond length.

Interpretation:

The species that may be diamagnetic has to be predicted and the reason has to be explained.

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Chapter 2 Solutions

The molecules ( CF + ,CF,CF - ) have to arranged in the increasing C-F bond length.

Solution Summary: The author explains that the molecules C-F have to be arranged in the increasing bond length.

Concept explainers

Videos

Interpretation: The molecules (CF+,CF,CF-) have to arranged in the increasing C-F bond length.

Interpretation: The species that may be diamagnetic has to be predicted and the reason has to be explained.

Want to see the full answer?

Chapter 2 Solutions

Interpretation:

The molecules (CF+,CF,CF-) have to arranged in the increasing C-F bond length.

Interpretation:

The species that may be diamagnetic has to be predicted and the reason has to be explained.