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a)
Interpretation:
Starting from testosterone how to prepare the compound shown is to be shown.
Concept introduction:
Pyridiniumchlorochromate in dichloromethane oxidizes 10 alcohols to
To show:
Starting from testosterone how to prepare the compound shown is to be stated.
b)
Interpretation:
Starting from testosterone how to prepare the compound shown is to be stated.
Concept introduction:
LiAlH4 in ether reduces unsaturated aldehydes, acids and esters to 10 alcohols. It reduces ketones to 20 alcohols. The double bond remains unaffected during the reduction.
To state:
Starting from testosterone how to prepare the compound shown.
c)
Interpretation:
Starting from testosterone how to prepare the compound shown is to be stated.
Concept introduction:
Pyridiniumchlorochromate in dichloromethane oxidizes 10 alcohols to aldehydes and 20 alcohols to ketones. H2, Pd/C can reduce the double bond in a compound without affecting aldehydic or keto group present in the compound.
To state:
Starting from testosterone how to prepare the compound shown.
d)
Interpretation:
Starting from testosterone how to prepare the compound shown is to be stated.
Concept introduction:
LiAlH4 in ether reduces unsaturated aldehydes, acids and esters to 10 alcohols. It reduces ketones to 20 alcohols. The double bond remains unaffected during the reduction. The double bond can be reduced using H2, Pd/C.
To state:
Starting from testosterone how to prepare the compound shown.
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Chapter 17 Solutions
Organic Chemistry
- Which one? Ca2^- Na2^+ Si2^+ Mg2^- AI2^-arrow_forwardIn general, which is more polar, the stationary phase or the mobile phase? The stationary phase is always more polar The mobile phase is always more polar It depends on our choices for both stationary and mobile phase Their polarity doesn't really matter so we never consider itarrow_forwardPlease helparrow_forward
- Draw the mechanism of aspirin synthesis in an basic medium and in a neutral medium, showing the attacks and the process for the formation of the product.arrow_forwardNa :S f. F NO2arrow_forwardQ1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. + CI OH woཡི།༠w Br H مه D CI ပ။ Br H, Br Br H₂N OMe R IN Ill N S H CI Br CI CI D OH H 1/111arrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
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