a) Interpretation: All possible compounds which give benzyl alcohol on reduction with LiAlH 4 are to be given. Concept introduction: All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH 4 . Acids, esters and aldehydes yield a 1 0 alcohol upon reduction with LiAlH 4 , while ketones yield 2 0 alcohols. The reaction is carried out in ether solution as LiAlH 4 reacts violently with water and explodes when heated above 120 o C. To give: All possible compounds which give benzyl alcohol on reduction with LiAlH 4 .

Question

Indicate the correct option.a) Graphite conducts electricity, being an isotropic materialb) Graphite is not a conductor of electricityc) Both are false

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.4, Problem 8P

Interpretation Introduction

a)

Interpretation:

All possible compounds which give benzyl alcohol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give benzyl alcohol on reduction with LiAlH₄.

Interpretation Introduction

b)

Interpretation:

All possible compounds which give 1-phenylethanol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give 1-phenylethanol on reduction with LiAlH₄.

Interpretation Introduction

c)

Interpretation:

All possible compounds which give cyclohexanol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give cyclohexanol on reduction with LiAlH₄.

Interpretation Introduction

d)

Interpretation:

All possible compounds which give isobutyl alcohol on reduction with LiAlH4 are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 10 alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give isobutyl alcohol on reduction with LiAlH4.

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Indicate the correct option.a) Graphite conducts electricity, being an isotropic materialb) Graphite is not a conductor of electricityc) Both are false

(f) SO: Best Lewis Structure 3 e group geometry:_ shape/molecular geometry:, (g) CF2CF2 Best Lewis Structure polarity: e group arrangement:_ shape/molecular geometry: (h) (NH4)2SO4 Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):

1. Problem Set 3b Chem 141 For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the molecule is polar or non-polar (iv) (a) SeF4 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: (b) AsOBr3 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles):

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.4, Problem 8P

Interpretation Introduction

a)

Interpretation:

All possible compounds which give benzyl alcohol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give benzyl alcohol on reduction with LiAlH₄.

Interpretation Introduction

b)

Interpretation:

All possible compounds which give 1-phenylethanol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give 1-phenylethanol on reduction with LiAlH₄.

Interpretation Introduction

c)

Interpretation:

All possible compounds which give cyclohexanol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give cyclohexanol on reduction with LiAlH₄.

Interpretation Introduction

d)

Interpretation:

All possible compounds which give isobutyl alcohol on reduction with LiAlH4 are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 10 alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give isobutyl alcohol on reduction with LiAlH4.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.4, Problem 8P

Interpretation Introduction

a)

Interpretation:

All possible compounds which give benzyl alcohol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give benzyl alcohol on reduction with LiAlH₄.

Interpretation Introduction

b)

Interpretation:

All possible compounds which give 1-phenylethanol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give 1-phenylethanol on reduction with LiAlH₄.

Interpretation Introduction

c)

Interpretation:

All possible compounds which give cyclohexanol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give cyclohexanol on reduction with LiAlH₄.

Interpretation Introduction

d)

Interpretation:

All possible compounds which give isobutyl alcohol on reduction with LiAlH4 are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 10 alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give isobutyl alcohol on reduction with LiAlH4.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.4, Problem 8P

Interpretation Introduction

a)

Interpretation:

All possible compounds which give benzyl alcohol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give benzyl alcohol on reduction with LiAlH₄.

Interpretation Introduction

b)

Interpretation:

All possible compounds which give 1-phenylethanol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give 1-phenylethanol on reduction with LiAlH₄.

Interpretation Introduction

c)

Interpretation:

All possible compounds which give cyclohexanol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give cyclohexanol on reduction with LiAlH₄.

Interpretation Introduction

d)

Interpretation:

All possible compounds which give isobutyl alcohol on reduction with LiAlH4 are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 10 alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give isobutyl alcohol on reduction with LiAlH4.

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Answer 5

Chapter 17.4, Problem 8P

Interpretation Introduction

a)

Interpretation:

All possible compounds which give benzyl alcohol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give benzyl alcohol on reduction with LiAlH₄.

Interpretation Introduction

b)

Interpretation:

All possible compounds which give 1-phenylethanol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give 1-phenylethanol on reduction with LiAlH₄.

Interpretation Introduction

c)

Interpretation:

All possible compounds which give cyclohexanol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give cyclohexanol on reduction with LiAlH₄.

Interpretation Introduction

d)

Interpretation:

All possible compounds which give isobutyl alcohol on reduction with LiAlH4 are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 10 alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give isobutyl alcohol on reduction with LiAlH4.

Answer 6

Chapter 17.4, Problem 8P

Interpretation Introduction

a)

Interpretation:

All possible compounds which give benzyl alcohol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give benzyl alcohol on reduction with LiAlH₄.

Answer 7

Chapter 17.4, Problem 8P

Interpretation Introduction

a)

Interpretation:

All possible compounds which give benzyl alcohol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give benzyl alcohol on reduction with LiAlH₄.

Answer 8

Interpretation Introduction

b)

Interpretation:

All possible compounds which give 1-phenylethanol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give 1-phenylethanol on reduction with LiAlH₄.

Answer 9

Interpretation Introduction

b)

Interpretation:

All possible compounds which give 1-phenylethanol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give 1-phenylethanol on reduction with LiAlH₄.

Answer 10

Interpretation Introduction

c)

Interpretation:

All possible compounds which give cyclohexanol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give cyclohexanol on reduction with LiAlH₄.

Answer 11

Interpretation Introduction

c)

Interpretation:

All possible compounds which give cyclohexanol on reduction with LiAlH₄ are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 1⁰ alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give cyclohexanol on reduction with LiAlH₄.

Answer 12

Interpretation Introduction

d)

Interpretation:

All possible compounds which give isobutyl alcohol on reduction with LiAlH4 are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 10 alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give isobutyl alcohol on reduction with LiAlH4.

Answer 13

Interpretation Introduction

d)

Interpretation:

All possible compounds which give isobutyl alcohol on reduction with LiAlH4 are to be given.

Concept introduction:

All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH₄. Acids, esters and aldehydes yield a 10 alcohol upon reduction with LiAlH₄, while ketones yield 2⁰ alcohols. The reaction is carried out in ether solution as LiAlH₄ reacts violently with water and explodes when heated above 120^oC.

To give:

All possible compounds which give isobutyl alcohol on reduction with LiAlH4.

Answer 14

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Answer 15

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Answer 19

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Answer 22

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Answer 24

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Answer 25

Ch. 17.1 - Give IUPAC names for the following compounds:Ch. 17.1 - Prob. 2P Ch. 17.2 - The following data for isomeric four-carbon...Ch. 17.2 - Rank the following substances in order of...Ch. 17.2 - Prob. 5P Ch. 17.3 - Prob. 6P Ch. 17.4 - What reagent would you use to accomplish each of...Ch. 17.4 - Prob. 8P Ch. 17.5 - Prob. 9P Ch. 17.5 - Prob. 10P

Solution Summary: The author explains that benzyl alcohol can be prepared by reducing Benzaldehyde or benzoic acid or a Benzoyate Ester with LiAlH 4 followed by acidification.

Concept explainers

Chapter 17 Solutions