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Concept explainers
a)
Interpretation:
All possible compounds which give benzyl alcohol on reduction with LiAlH4 are to be given.
Concept introduction:
All carbonyl compounds, including acids, esters,
To give:
All possible compounds which give benzyl alcohol on reduction with LiAlH4.
b)
Interpretation:
All possible compounds which give 1-phenylethanol on reduction with LiAlH4 are to be given.
Concept introduction:
All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH4. Acids, esters and aldehydes yield a 10 alcohol upon reduction with LiAlH4, while ketones yield 20 alcohols. The reaction is carried out in ether solution as LiAlH4 reacts violently with water and explodes when heated above 120oC.
To give:
All possible compounds which give 1-phenylethanol on reduction with LiAlH4.
c)
Interpretation:
All possible compounds which give cyclohexanol on reduction with LiAlH4 are to be given.
Concept introduction:
All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH4. Acids, esters and aldehydes yield a 10 alcohol upon reduction with LiAlH4, while ketones yield 20 alcohols. The reaction is carried out in ether solution as LiAlH4 reacts violently with water and explodes when heated above 120oC.
To give:
All possible compounds which give cyclohexanol on reduction with LiAlH4.
d)
Interpretation:
All possible compounds which give isobutyl alcohol on reduction with LiAlH4 are to be given.
Concept introduction:
All carbonyl compounds, including acids, esters, aldehydes and ketones are reduced by LiAlH4. Acids, esters and aldehydes yield a 10 alcohol upon reduction with LiAlH4, while ketones yield 20 alcohols. The reaction is carried out in ether solution as LiAlH4 reacts violently with water and explodes when heated above 120oC.
To give:
All possible compounds which give isobutyl alcohol on reduction with LiAlH4.
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Chapter 17 Solutions
Organic Chemistry
- Acid-catalyzed hydrolysis of the following epoxide gives a trans diol. Of the two possible trans diols, only one is formed. How do you account for this stereoselectivity?arrow_forwardGive the major organic product of the following reactions. 8 9 10 13 -O #9 answer -O CI (CH3CH₂)₂CuLi HCN LIAIH, THE H₂O KMnO4, H₂O NaOH, H₂O*arrow_forwardShow how the p-nitroaniline can be synthesized from benzene:arrow_forward
- Synthesize the following compounds from 4 carbon or less mono-functional alcohols, benzene, toluene and any organic or inorganic reagents needed, NH2arrow_forwardPrepare the following compounds : 1-Starting with benzene or any other reagents , prepare 3-phenyl -1-propanolarrow_forwardDevise a synthesis of the ketone hexan-3-one, CH3CH2COCH2CH2CH3, from CH3CH2Br as the only organic starting material; that is, all the carbon atoms in hexan-3-one must come from CH3CH2Br. You may use any other neededreagents.arrow_forward
- Please explain and give the correct answerarrow_forwardPropose a synthesis of the topical anesthetic cyclomethycaine from 4-hydroxybenzoic acid, 2-methylpiperidine, and any other necessary reagents. HN' + HO. НО Cyclomethycaine 4-Hydroxybenzoic acid 2-Methylpiperidinearrow_forwardThe following diol is prepared from propanal (CH3CH2CHO) and 3-bromopropanol. Which derivatives will be among intermediate products in this transformation? ОН HOarrow_forward
- QII: Starting from toluene as the only organic reagent you have and use any other inorganic reagents to prepare: ОН -CH НС CH,arrow_forwardWhich of the following reactions will synthesize phenol from benzene? 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) warm H2SO4 and H2O 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) CuCN; 5) dilute acid and heat 1) Acetyl chloride & AlCl3; 2) bleach 1) Ph-N2+ + KI; 2) BrMgCH=CH2 in ether, followed by H3O+; 3) warm, conc'd KMnO4 1) Cl-CH(CH3)-CH2CH2CH3 + FeBr3; 2) hot, conc'd KMnO4arrow_forwardPlease don't provide handwriting solutionarrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
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