The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn. Concept Introduction: Amides are derivatives of carboxylic acid . Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes. Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt. Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

Question

Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 17.139EP

(a)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(b)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(c)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(d)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

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Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 17.139EP

(a)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(b)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(c)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(d)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 17.139EP

(a)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(b)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(c)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(d)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 17.139EP

(a)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(b)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(c)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(d)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

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Answer 5

Chapter 17, Problem 17.139EP

(a)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(b)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(c)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

(d)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

Answer 6

Chapter 17, Problem 17.139EP

(a)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

Answer 7

Chapter 17, Problem 17.139EP

(a)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid. Amides are not much reactive as of carboxylic acids. They are also stable relatively in aqueous solution. But under strenuous conditions amides undergo hydrolysis. The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt. Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine. Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

Answer 14

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Answer 25

Ch. 17.1 - Prob. 1QQ Ch. 17.1 - Prob. 2QQ Ch. 17.2 - Prob. 1QQ Ch. 17.2 - Prob. 2QQ Ch. 17.2 - Prob. 3QQ Ch. 17.2 - Prob. 4QQ Ch. 17.3 - Prob. 1QQ Ch. 17.3 - Prob. 2QQ Ch. 17.3 - Prob. 3QQ Ch. 17.3 - Prob. 4QQ

Solution Summary: The author explains the structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis.

Chapter 17 Solutions