Given aromatic amine has to be named as derivative of aniline. Concept Introduction: IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine. Longest carbon chain has to be identified that is attached to nitrogen atom. Suffix “-e” in name of the parent chain alkane is replaced by “-amine”. Numbering of the carbon chain is done from the end that is near the nitrogen atom. Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name. In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name. If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N -substituted primary amines. Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine. Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

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Answer 1

Question

Chapter 17, Problem 17.22EP

(a)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(b)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(c)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(d)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

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Draw the major organic substitution product or products for (2R,3S)-2-bromo-3-methylpentane reacting with the given nucleophile. Clearly drawn the stereochemistry, including a wedged bond, a dashed bond and two in-plane bonds at each stereogenic center. Omit any byproducts. Bri CH3CH2O- (conc.) Draw the major organic product or products.

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Answer 2

Question

Chapter 17, Problem 17.22EP

(a)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(b)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(c)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(d)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

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Answer 3

Question

Chapter 17, Problem 17.22EP

(a)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(b)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(c)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(d)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

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Answer 4

Question

Chapter 17, Problem 17.22EP

(a)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(b)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(c)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(d)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

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Answer 5

Chapter 17, Problem 17.22EP

(a)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(b)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(c)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(d)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 6

Chapter 17, Problem 17.22EP

(a)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 7

Chapter 17, Problem 17.22EP

(a)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 17.1 - Prob. 1QQ Ch. 17.1 - Prob. 2QQ Ch. 17.2 - Prob. 1QQ Ch. 17.2 - Prob. 2QQ Ch. 17.2 - Prob. 3QQ Ch. 17.2 - Prob. 4QQ Ch. 17.3 - Prob. 1QQ Ch. 17.3 - Prob. 2QQ Ch. 17.3 - Prob. 3QQ Ch. 17.3 - Prob. 4QQ

Solution Summary: The author explains the IUPAC nomenclature for an amine. The longest carbon chain has to be identified that is attached to nitrogen atom.

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Chapter 17 Solutions