Methylamine will be present as liquid or gas at room temperature has to be indicated. Concept Introduction: Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Question

Q5: Label each chiral carbon in the following molecules as R or S. Make sure the stereocenter to which each of your R/S assignments belong is perfectly clear to the grader. (8pts) R OCH 3 CI H S 2pts for each R/S HO R H !!! I OH CI HN CI R H

Answer 1

Question

Chapter 17, Problem 17.34EP

(a)

Interpretation Introduction

Interpretation:

Methylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(b)

Interpretation Introduction

Interpretation:

Propylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(c)

Interpretation Introduction

Interpretation:

Trimethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(d)

Interpretation Introduction

Interpretation:

Pentylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

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Q5: Label each chiral carbon in the following molecules as R or S. Make sure the stereocenter to which each of your R/S assignments belong is perfectly clear to the grader. (8pts) R OCH 3 CI H S 2pts for each R/S HO R H !!! I OH CI HN CI R H

Calculate the proton and carbon chemical shifts for this structure

A. B. b. Now consider the two bicyclic molecules A. and B. Note that A. is a dianion and B. is a neutral molecule. One of these molecules is a highly reactive compound first characterized in frozen noble gas matrices, that self-reacts rapidly at temperatures above liquid nitrogen temperature. The other compound was isolated at room temperature in the early 1960s, and is a stable ligand used in organometallic chemistry. Which molecule is the more stable molecule, and why?

Answer 2

Question

Chapter 17, Problem 17.34EP

(a)

Interpretation Introduction

Interpretation:

Methylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(b)

Interpretation Introduction

Interpretation:

Propylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(c)

Interpretation Introduction

Interpretation:

Trimethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(d)

Interpretation Introduction

Interpretation:

Pentylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

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Answer 3

Question

Chapter 17, Problem 17.34EP

(a)

Interpretation Introduction

Interpretation:

Methylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(b)

Interpretation Introduction

Interpretation:

Propylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(c)

Interpretation Introduction

Interpretation:

Trimethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(d)

Interpretation Introduction

Interpretation:

Pentylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

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Answer 4

Question

Chapter 17, Problem 17.34EP

(a)

Interpretation Introduction

Interpretation:

Methylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(b)

Interpretation Introduction

Interpretation:

Propylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(c)

Interpretation Introduction

Interpretation:

Trimethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(d)

Interpretation Introduction

Interpretation:

Pentylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

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Answer 5

Chapter 17, Problem 17.34EP

(a)

Interpretation Introduction

Interpretation:

Methylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(b)

Interpretation Introduction

Interpretation:

Propylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(c)

Interpretation Introduction

Interpretation:

Trimethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

(d)

Interpretation Introduction

Interpretation:

Pentylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 6

Chapter 17, Problem 17.34EP

(a)

Interpretation Introduction

Interpretation:

Methylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 7

Chapter 17, Problem 17.34EP

(a)

Interpretation Introduction

Interpretation:

Methylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Propylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Propylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Trimethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Trimethylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Pentylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Pentylamine will be present as liquid or gas at room temperature has to be indicated.

Concept Introduction:

Amines are compounds that contain nitrogen atom bonded to a hydrocarbon group. Methylamines and ethylamines are gases at room temperature. Apart from these, the other amines have raw fish odor.

Answer 14

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Answer 25

Ch. 17.1 - Prob. 1QQ Ch. 17.1 - Prob. 2QQ Ch. 17.2 - Prob. 1QQ Ch. 17.2 - Prob. 2QQ Ch. 17.2 - Prob. 3QQ Ch. 17.2 - Prob. 4QQ Ch. 17.3 - Prob. 1QQ Ch. 17.3 - Prob. 2QQ Ch. 17.3 - Prob. 3QQ Ch. 17.3 - Prob. 4QQ

Solution Summary: The author explains that amines are compounds that contain nitrogen atom bonded to a hydrocarbon group.

Chapter 17 Solutions