Given aromatic amine has to be named as derivative of aniline. Concept Introduction: IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine. Longest carbon chain has to be identified that is attached to nitrogen atom. Suffix “-e” in name of the parent chain alkane is replaced by “-amine”. Numbering of the carbon chain is done from the end that is near the nitrogen atom. Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name. In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name. If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N -substituted primary amines. Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine. Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Question

In the Thermo Fisher application note about wine analysis (Lesson 3), the following chromatogram was collected of nine components of wine. If peak 3 has a retention time of 3.15 minutes and a peak width of 0.070 minutes, and peak 4 has a retention time of 3.24 minutes and a peak width of 0.075 minutes, what is the resolution factor between the two peaks? [Hint: it will help to review Lesson 2 for this question.] MAU 300 200 T 34 5 100- 1 2 CO 6 7 8 9 0 2.4 2.6 2.8 3.0 3.2 3.4 3.6 3.8 4.0 4.2 4.4 4.6 4.8 5.0 5.2 Minutes 3.22 0.62 1.04 O 1.24

Answer 1

Question

Chapter 17, Problem 17.21EP

(a)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(b)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(c)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(d)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

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In the Thermo Fisher application note about wine analysis (Lesson 3), the following chromatogram was collected of nine components of wine. If peak 3 has a retention time of 3.15 minutes and a peak width of 0.070 minutes, and peak 4 has a retention time of 3.24 minutes and a peak width of 0.075 minutes, what is the resolution factor between the two peaks? [Hint: it will help to review Lesson 2 for this question.] MAU 300 200 T 34 5 100- 1 2 CO 6 7 8 9 0 2.4 2.6 2.8 3.0 3.2 3.4 3.6 3.8 4.0 4.2 4.4 4.6 4.8 5.0 5.2 Minutes 3.22 0.62 1.04 O 1.24

The diagram shows two metals, A and B, which melt at 1000°C and 1400°C. State the weight percentage of the primary constituent (grains of C) that would be obtained by solidifying a 20% alloy of B. 1000°C a+L L+C 900°С 12 α a+C 45 1200 C L+y 140096 C+Y a+ß 800°C 700°C C+B 96 92 a+B 0 10 20 30 40 50 60 70 80 90 100 A % peso B B

8. Choose the compound that will produce the spectrum below and assign the signals to the corresponding protons. 2 4 3 ō (ppm) OH 4 6 6 СОН 2 1 0

Answer 2

Question

Chapter 17, Problem 17.21EP

(a)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(b)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(c)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(d)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

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Answer 3

Question

Chapter 17, Problem 17.21EP

(a)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(b)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(c)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(d)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

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Answer 4

Question

Chapter 17, Problem 17.21EP

(a)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(b)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(c)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(d)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

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Answer 5

Chapter 17, Problem 17.21EP

(a)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(b)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(c)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

(d)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 6

Chapter 17, Problem 17.21EP

(a)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 7

Chapter 17, Problem 17.21EP

(a)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Given aromatic amine has to be named as derivative of aniline.

Concept Introduction:

IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.

Longest carbon chain has to be identified that is attached to nitrogen atom.

Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.

Numbering of the carbon chain is done from the end that is near the nitrogen atom.

Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.

In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.

If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.

Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.

Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.

Answer 14

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Answer 25

Ch. 17.1 - Prob. 1QQ Ch. 17.1 - Prob. 2QQ Ch. 17.2 - Prob. 1QQ Ch. 17.2 - Prob. 2QQ Ch. 17.2 - Prob. 3QQ Ch. 17.2 - Prob. 4QQ Ch. 17.3 - Prob. 1QQ Ch. 17.3 - Prob. 2QQ Ch. 17.3 - Prob. 3QQ Ch. 17.3 - Prob. 4QQ

Chapter 17 Solutions