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(a)
Interpretation:
Given
Concept Introduction:
- Longest carbon chain has to be identified that is attached to nitrogen atom.
- Suffix “-e” in name of the parent chain
alkane is replaced by “-amine”. - Numbering of the carbon chain is done from the end that is near the nitrogen atom.
- Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.
- In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.
If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary
Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.
Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.
(b)
Interpretation:
Given aromatic amine has to be named as derivative of aniline.
Concept Introduction:
IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.
- Longest carbon chain has to be identified that is attached to nitrogen atom.
- Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.
- Numbering of the carbon chain is done from the end that is near the nitrogen atom.
- Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.
- In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.
If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.
Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.
Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.
(c)
Interpretation:
Given aromatic amine has to be named as derivative of aniline.
Concept Introduction:
IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.
- Longest carbon chain has to be identified that is attached to nitrogen atom.
- Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.
- Numbering of the carbon chain is done from the end that is near the nitrogen atom.
- Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.
- In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.
If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.
Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.
Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.
(d)
Interpretation:
Given aromatic amine has to be named as derivative of aniline.
Concept Introduction:
IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.
- Longest carbon chain has to be identified that is attached to nitrogen atom.
- Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.
- Numbering of the carbon chain is done from the end that is near the nitrogen atom.
- Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.
- In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.
If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.
Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.
Simplest aromatic amine is aniline. Amino group attached to a benzene ring is known as aniline.
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Chapter 17 Solutions
General, Organic, and Biological Chemistry Seventh Edition
- Nonearrow_forward3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward
- 6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below. a) SiF5 (4 points) b) IOF4 (4 points)arrow_forward5. Complex anion [AuCl2]¯ belongs to Doh symmetry point group. What is the shape of this ion? (4 points)arrow_forward
- 4. Assign the following molecules to proper point groups: Pyridine N 1,3,5-triazine N Narrow_forward7. a) Under normal conditions (room temperature & atmospheric pressure) potassium assumes bcc lattice. Atomic radius for 12-coordinate K atom is listed as 235 pm. What is the radius of potassium atom under normal conditions? (3 points) b) Titanium metal crystallyzes in hcp lattice. Under proper conditions nitrogen can be absorbed into the lattice of titanium resulting in an alloy of stoichiometry TiNo.2. Is this compound likely to be a substitutional or an interstitial alloy? (Radius of Ti (12-coordinate) is 147 pm; radius of N atom is 75 pm. (3 points)arrow_forwardcan someone answer the questions and draw out the complete mechanismarrow_forward
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