Given compound has to be classified as an amine, an amide, or both amine and amide. Concept Introduction: Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound. Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines , amides. Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain. One of the carboxylic acid derivatives is amide. In this the carboxyl − OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as, Amides are also classified as primary, secondary, and tertiary amide. Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides. Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides. Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides. Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

Question

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 1

Question

Chapter 17, Problem 17.105EP

(a)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(c)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(d)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

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Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

What is the IUPAC name of the following compound? CH₂CH₂ H CI H₂CH₂C H CH₂ Selected Answer: O (35,4R)-4 chloro-3-ethylpentane Correct

Answer 2

Question

Chapter 17, Problem 17.105EP

(a)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(c)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(d)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

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Answer 3

Question

Chapter 17, Problem 17.105EP

(a)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(c)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(d)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

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Answer 4

Question

Chapter 17, Problem 17.105EP

(a)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(c)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(d)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

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Answer 5

Chapter 17, Problem 17.105EP

(a)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(c)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

(d)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

Answer 6

Chapter 17, Problem 17.105EP

(a)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

Answer 7

Chapter 17, Problem 17.105EP

(a)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide. In this the carboxyl −OH group is replaced by an amino or a substituted amino group. The functional group of amide can be given as,

Amides are also classified as primary, secondary, and tertiary amide.

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides. They are formed by intramolecular condensation. Cyclic amides are also known as lactams.

Answer 14

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Answer 25

Ch. 17.1 - Prob. 1QQ Ch. 17.1 - Prob. 2QQ Ch. 17.2 - Prob. 1QQ Ch. 17.2 - Prob. 2QQ Ch. 17.2 - Prob. 3QQ Ch. 17.2 - Prob. 4QQ Ch. 17.3 - Prob. 1QQ Ch. 17.3 - Prob. 2QQ Ch. 17.3 - Prob. 3QQ Ch. 17.3 - Prob. 4QQ

Solution Summary: The author explains that organic compounds include gasoline, coal, dyes, and clothing fibers.

Chapter 17 Solutions