The number of carbon‑nitrogen bonds present in primary amine has to be given. Concept Introduction: Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

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Answer 1

Question

Chapter 17, Problem 17.4EP

(a)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in primary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(b)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in secondary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(c)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in tertiary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

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a) Explain why product 1 is the kinetic product and product 2 is the thermodynamic product. b) Draw the reaction coordinate diagram for the reaction pathway generating each product. c) State the Arrhenius Equation and explain the terms with their physical significance. d) State and explain which reaction pathway has a higher rate constant. What happens to the rate constant if the temperature has increased?

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QUESTION 1 Write the IUPAC names for the following compounds. (a) (b) 2 H₂C CH (c) Br (d) HO (e) COOH

Answer 2

Question

Chapter 17, Problem 17.4EP

(a)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in primary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(b)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in secondary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(c)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in tertiary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

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Answer 3

Question

Chapter 17, Problem 17.4EP

(a)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in primary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(b)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in secondary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(c)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in tertiary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

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Answer 4

Question

Chapter 17, Problem 17.4EP

(a)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in primary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(b)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in secondary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(c)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in tertiary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

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Answer 5

Chapter 17, Problem 17.4EP

(a)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in primary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(b)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in secondary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

(c)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in tertiary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

Answer 6

Chapter 17, Problem 17.4EP

(a)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in primary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

Answer 7

Chapter 17, Problem 17.4EP

(a)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in primary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

Answer 8

(b)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in secondary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

Answer 9

(b)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in secondary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

Answer 10

(c)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in tertiary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

Answer 11

(c)

Interpretation Introduction

Interpretation:

The number of carbon‑nitrogen bonds present in tertiary amine has to be given.

Concept Introduction:

Amine is an organic derivative. If in ammonia one or more alkyl, cycloalkyl, or aryl groups are substituted instead of hydrogen atom then it is known as amine. Depending on the number of substitution the amines are classified as primary, secondary or tertiary amine. Primary amine is the one in which only one hydrogen atom in ammonia is replaced by a hydrocarbon group. Secondary amine is the one in which only two hydrogen atoms in ammonia is replaced by a hydrocarbon group. Tertiary amine is the one in which all three hydrogen atoms in ammonia is replaced by a hydrocarbon group. The generalized structural formula for all the amines is,

Answer 12

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Answer 13

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Answer 15

Ch. 17.1 - Prob. 1QQ Ch. 17.1 - Prob. 2QQ Ch. 17.2 - Prob. 1QQ Ch. 17.2 - Prob. 2QQ Ch. 17.2 - Prob. 3QQ Ch. 17.2 - Prob. 4QQ Ch. 17.3 - Prob. 1QQ Ch. 17.3 - Prob. 2QQ Ch. 17.3 - Prob. 3QQ Ch. 17.3 - Prob. 4QQ

Solution Summary: The author explains that the number of carbonnitrogen bonds present in primary amine is given.

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