(a)
Interpretation:
Chemical equation for the conversion of given
Concept Introduction:
The name of the carboxylic acid itself implies that it is acidic. Addition of carboxylic acid to water results in ionization. Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed. Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.
Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid. Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.
Carboxylic acid salts when treated with a strong acid produces carboxylic acid as the product.
Carboxylic acid forms carboxylic acid salt by reacting with a strong base. The general reaction scheme for the formation of carboxylic acid salt is given as shown below,
The reverse of the above reaction is conversion of carboxylic acid salt to carboxylic acid. This is accomplished by using strong acid. The scheme is shown below,
From the above chemical equation it is found that the carboxylic acid salt reacts with strong acid to form carboxylic acid.
(a)
Explanation of Solution
Given carboxylic acid salt is sodium butanoate. The structure of sodium butanoate can be given as shown below,
Carboxylic acid sat is converted to carboxylic acid by reaction with strong acid. In the problem statement it is given that the strong acid is
Chemical equation for the conversion of given carboxylic acid salt to carboxylic acid using hydrochloric acid is written.
(b)
Interpretation:
Chemical equation for the conversion of given carboxylic acid salt to its parent carboxylic acid using
Concept Introduction:
The name of the carboxylic acid itself implies that it is acidic. Addition of carboxylic acid to water results in ionization. Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed. Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.
Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid. Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.
Carboxylic acid salts when treated with a strong acid produces carboxylic acid as the product.
Carboxylic acid forms carboxylic acid salt by reacting with a strong base. The general reaction scheme for the formation of carboxylic acid salt is given as shown below,
The reverse of the above reaction is conversion of carboxylic acid salt to carboxylic acid. This is accomplished by using strong acid. The scheme is shown below,
From the above chemical equation it is found that the carboxylic acid salt reacts with strong acid to form carboxylic acid.
(b)
Explanation of Solution
Given carboxylic acid salt is potassium oxalate. The structure of potassium oxalate can be given as shown below,
Carboxylic acid sat is converted to carboxylic acid by reaction with strong acid. In the problem statement it is given that the strong acid is
Chemical equation for the conversion of given carboxylic acid salt to carboxylic acid using hydrochloric acid is written.
(c)
Interpretation:
Chemical equation for the conversion of given carboxylic acid salt to its parent carboxylic acid using
Concept Introduction:
The name of the carboxylic acid itself implies that it is acidic. Addition of carboxylic acid to water results in ionization. Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed. Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.
Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid. Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.
Carboxylic acid salts when treated with a strong acid produces carboxylic acid as the product.
Carboxylic acid forms carboxylic acid salt by reacting with a strong base. The general reaction scheme for the formation of carboxylic acid salt is given as shown below,
The reverse of the above reaction is conversion of carboxylic acid salt to carboxylic acid. This is accomplished by using strong acid. The scheme is shown below,
From the above chemical equation it is found that the carboxylic acid salt reacts with strong acid to form carboxylic acid.
(c)
Explanation of Solution
Given carboxylic acid salt is calcium malonate. The structure of calcium malonate can be given as shown below,
Carboxylic acid sat is converted to carboxylic acid by reaction with strong acid. In the problem statement it is given that the strong acid is
Chemical equation for the conversion of given carboxylic acid salt to carboxylic acid using hydrochloric acid is written.
(d)
Interpretation:
Chemical equation for the conversion of given carboxylic acid salt to its parent carboxylic acid using
Concept Introduction:
The name of the carboxylic acid itself implies that it is acidic. Addition of carboxylic acid to water results in ionization. Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed. Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.
Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid. Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.
Carboxylic acid salts when treated with a strong acid produces carboxylic acid as the product.
Carboxylic acid forms carboxylic acid salt by reacting with a strong base. The general reaction scheme for the formation of carboxylic acid salt is given as shown below,
The reverse of the above reaction is conversion of carboxylic acid salt to carboxylic acid. This is accomplished by using strong acid. The scheme is shown below,
From the above chemical equation it is found that the carboxylic acid salt reacts with strong acid to form carboxylic acid.
(d)
Explanation of Solution
Given carboxylic acid salt is sodium benzoate. The structure of sodium benzoate can be given as shown below,
Carboxylic acid sat is converted to carboxylic acid by reaction with strong acid. In the problem statement it is given that the strong acid is
Chemical equation for the conversion of given carboxylic acid salt to carboxylic acid using hydrochloric acid is written.
Want to see more full solutions like this?
Chapter 16 Solutions
Bundle: General, Organic, and Biological Chemistry, 7th + OWLv2 Quick Prep for General Chemistry, 4 terms (24 months) Printed Access Card
- 7. Calculate the following for a 1.50 M Ca(OH)2 solution. a. The concentration of hydroxide, [OH-] b. The concentration of hydronium, [H3O+] c. The pOH d. The pHarrow_forwardA first order reaction is 46.0% complete at the end of 59.0 minutes. What is the value of k? What is the half-life for this reaction? HOW DO WE GET THERE? The integrated rate law will be used to determine the value of k. In [A] [A]。 = = -kt What is the value of [A] [A]。 when the reaction is 46.0% complete?arrow_forward3. Provide the missing compounds or reagents. 1. H,NNH КОН 4 EN MN. 1. HBUCK = 8 хно Panely prowseful kanti-chuprccant fad, winddively, can lead to the crading of deduc din-willed, tica, The that chemooices in redimi Грин. " like (for alongan Ridovi MN نيا . 2. Cl -BuO 1. NUH 2.A A -BuOK THE CF,00,H Ex 5)arrow_forward
- 2. Write a complete mechanism for the reaction shown below. NaOCH LOCH₁ O₂N NO2 CH₂OH, 20 °C O₂N NO2arrow_forward4. Propose a synthesis of the target molecules from the respective starting materials. a) b) LUCH C Br OHarrow_forwardThe following mechanism for the gas phase reaction of H2 and ICI that is consistent with the observed rate law is: step 1 step 2 slow: H2(g) +ICI(g) → HCl(g) + HI(g) fast: ICI(g) + HI(g) → HCl(g) + |2(g) (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. + → + (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (4) Complete the rate law for the overall reaction that is consistent with this mechanism. (Use the form k[A][B]"..., where '1' is understood (so don't write it) for m, n etc.) Rate =arrow_forward
- Please correct answer and don't use hand rating and don't use Ai solutionarrow_forward1. For each of the following statements, indicate whether they are true of false. ⚫ the terms primary, secondary and tertiary have different meanings when applied to amines than they do when applied to alcohols. • a tertiary amine is one that is bonded to a tertiary carbon atom (one with three C atoms bonded to it). • simple five-membered heteroaromatic compounds (e.g. pyrrole) are typically more electron rich than benzene. ⚫ simple six-membered heteroaromatic compounds (e.g. pyridine) are typically more electron rich than benzene. • pyrrole is very weakly basic because protonation anywhere on the ring disrupts the aromaticity. • thiophene is more reactive than benzene toward electrophilic aromatic substitution. • pyridine is more reactive than nitrobenzene toward electrophilic aromatic substitution. • the lone pair on the nitrogen atom of pyridine is part of the pi system.arrow_forwardThe following reactions are NOT ordered in the way in which they occur. Reaction 1 PhO-OPh Reaction 2 Ph-O -CH₂ heat 2 *OPh Pho -CH2 Reaction 3 Ph-O ⚫OPh + -CH₂ Reaction 4 Pho Pho + H₂C OPh + CHOPh H₂C -CH₂ Reactions 1 and 3 Reaction 2 O Reaction 3 ○ Reactions 3 and 4 ○ Reactions 1 and 2 Reaction 4 ○ Reaction 1arrow_forward
- Select all possible products from the following reaction: NaOH H₂O a) b) ОН HO O HO HO e) ОН f) O HO g) h) + OHarrow_forward3. Draw diagrams to represent the conjugation in these molecules. Draw two types of diagram: a. Show curly arrows linking at least two different ways of representing the molecule b. Indicate with dotted lines and partial charges (where necessary) the partial double bond (and charge) distribution H₂N* H₂N -NH2arrow_forwardQuestion 2 of 25 point Question Attempt 3 of Ulimited Draw the structure for 3-chloro-4-ethylheptane. Part 2 of 3 Click and drag to start drawing a structure. Draw the structure for 1-chloro-4-ethyl-3-lodooctane. Click and drag to start drawing a structure. X G X B c Part 3 of 30 Draw the structure for (R)-2-chlorobutane. Include the stereochemistry at all stereogenic centers. Check Click and drag to start drawing a structure. G X A 。 MacBook Pro G P Save For Later Submit Assignment Privacyarrow_forward
Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning