The IUPAC name for the ester given has to be assigned. Concept Introduction: For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group. Rules to obtain IUPAC name and common name for an ester: Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word. Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group. Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”. To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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Answer 1

Question

Chapter 16, Problem 16.89EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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2. Provide a complete retrosynthetic analysis and a complete forward synthetic scheme to make the following target molecule from the given starting material. You may use any other reagents necessary. Br

146. Use the following data for NH3(g) at 273 K to determine B2p (T) at 273 K. P (bar) 0.10 0.20 0.30 0.40 0.50 0.60 (Z -1)/10-4 1.519 3.038 4.557 6.071 7.583 9.002 0.70 10.551

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Answer 2

Question

Chapter 16, Problem 16.89EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

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Answer 3

Question

Chapter 16, Problem 16.89EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Expert Solution & Answer

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Answer 4

Question

Chapter 16, Problem 16.89EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Expert Solution & Answer

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Answer 5

Chapter 16, Problem 16.89EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 6

Chapter 16, Problem 16.89EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 7

Chapter 16, Problem 16.89EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The IUPAC name for the ester given has to be assigned.

Concept Introduction:

For naming an ester, it can be structurally viewed in a way that contains an acyl group and an alkyl group.

Rules to obtain IUPAC name and common name for an ester:

Alkyl part appears first in the IUPAC name and it is followed by the acyl part of ester as a separate word.

Name of the alkyl part in the ester is just a name of R group. It can be alkyl, cycloalkyl, or aryl group.

Acyl part present in the ester is named by considering the acid name and replacing the suffix “-ic acid” with “-ate”.

To obtain the common name the alkyl part name is the same while the acyl part name is derived from the common name of the acid by replacing the suffix “-ic acid” with “-ate”.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 16.1 - Prob. 1QQ Ch. 16.1 - Prob. 2QQ Ch. 16.1 - Prob. 3QQ Ch. 16.1 - Prob. 4QQ Ch. 16.1 - Prob. 5QQ Ch. 16.2 - Prob. 1QQ Ch. 16.2 - Prob. 2QQ Ch. 16.2 - Prob. 3QQ Ch. 16.2 - Prob. 4QQ Ch. 16.2 - Prob. 5QQ

Solution Summary: The author explains that the IUPAC name for the ester given has to be assigned.

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