
Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 12, Problem 8DQ
Interpretation Introduction
Interpretation:Trend of second ionization energy from sodium to argon should be determined.
Concept introduction:Ionization energy represents removal of outermost valence electron from gaseous atom. It can be represented by I .
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In the following reaction, what quantity in moles of CH₃OH are required to give off 4111 kJ of heat? 2 CH₃OH (l) + 3 O₂ (g) → 2 CO₂ (g) + 4 H₂O(g) ∆H° = -1280. kJ
Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
2600
2400
2200
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1400
1200
1000
800
Potential Energy (kJ)
600
400
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0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
Chapter 12 Solutions
Chemical Principles
Ch. 12 - Prob. 1DQCh. 12 - Prob. 2DQCh. 12 - Prob. 3DQCh. 12 - The first four ionization energies for elements X...Ch. 12 - Prob. 5DQCh. 12 - Prob. 6DQCh. 12 - Prob. 7DQCh. 12 - Prob. 8DQCh. 12 - Prob. 9DQCh. 12 - Prob. 10DQ
Ch. 12 - Prob. 11DQCh. 12 - Prob. 12DQCh. 12 - Prob. 13DQCh. 12 - Prob. 14DQCh. 12 - Prob. 15DQCh. 12 - Prob. 16DQCh. 12 - Prob. 17DQCh. 12 - Is the following statement true or false: The...Ch. 12 - Which is higher in energy: the 2s or 2p orbital in...Ch. 12 - Prove mathematically that it is more energetically...Ch. 12 - Microwave radiation has a wavelength on the order...Ch. 12 - Consider the following waves representing...Ch. 12 - Prob. 23ECh. 12 - Human color vision is “produced” by the nervous...Ch. 12 - One type of electromagnetic radiation has a...Ch. 12 - Carbon absorbs energy at a wavelength of 150. nm....Ch. 12 - Prob. 27ECh. 12 - X rays have wavelengths on the order of 110-10m...Ch. 12 - The work function of an element is the energy...Ch. 12 - Ionization energy is the energy required to remove...Ch. 12 - It takes 208.4 kJ of energy to remove 1 mole of...Ch. 12 - What experimental evidence supports the quantum...Ch. 12 - Explain the photoelectric effect.Ch. 12 - Calculate the de Broglie wavelength for each of...Ch. 12 - Neutron diffraction is used in determining the...Ch. 12 - Calculate the velocities of electrons with de...Ch. 12 - An atom of a particular element is traveling at 1%...Ch. 12 - Characterize the Bohr model of the atom. In the...Ch. 12 - Prob. 39ECh. 12 - Consider only the transitions involving the first...Ch. 12 - Calculate the longest and shortest wavelengths of...Ch. 12 - Prob. 42ECh. 12 - Assume that a hydrogen atom’s electron has been...Ch. 12 - What is the maximum wavelength of light capable...Ch. 12 - An electron is excited from the ground state to...Ch. 12 - Does a photon of visible light (=400700nm)...Ch. 12 - An excited hydrogen atom emits light with a...Ch. 12 - An excited hydrogen atom with an electron in the n...Ch. 12 - Consider an electron for a hydrogen atom in an...Ch. 12 - Prob. 50ECh. 12 - One of the emission spectral lines for Be3+ has a...Ch. 12 - The Heisenberg uncertainty principle can be...Ch. 12 - Using the Heisenberg uncertainty principle,...Ch. 12 - We can represent both probability and radial...Ch. 12 - Prob. 55ECh. 12 - Calculate the wavelength of the electromagnetic...Ch. 12 - An electron in a one-dimensional box requires a...Ch. 12 - An electron in a 10.0-nm one-dimensional box is...Ch. 12 - Prob. 59ECh. 12 - What is the total probability of finding a...Ch. 12 - Which has the lowest (ground-state) energy, an...Ch. 12 - What are quantum numbers? What information do...Ch. 12 - How do 2p orbitals differ from each other? How do...Ch. 12 - Identify each of the following orbitals, and...Ch. 12 - Which of the following orbital designations are...Ch. 12 - Prob. 66ECh. 12 - The following sets of quantum numbers are not...Ch. 12 - How many orbitals can have the designation 5p,...Ch. 12 - How many electrons in an atom can have the...Ch. 12 - Prob. 70ECh. 12 - Prob. 71ECh. 12 - From the diagrams of 2p and 3p orbitals in Fig....Ch. 12 - Prob. 73ECh. 12 - Prob. 74ECh. 12 - Total radial probability distributions for the...Ch. 12 - The relative orbital levels for the hydrogen atom...Ch. 12 - What is the difference between core electrons and...Ch. 12 - Prob. 78ECh. 12 - Prob. 79ECh. 12 - The elements of Si, Ga, As, Ge, Al, Cd, S, and Se...Ch. 12 - Write the expected electron configurations for the...Ch. 12 - Write the expected electron configurations for...Ch. 12 - Prob. 83ECh. 12 - Using Fig. 12.29, list elements (ignore the...Ch. 12 - Prob. 85ECh. 12 - Prob. 86ECh. 12 - Prob. 87ECh. 12 - Prob. 88ECh. 12 - Prob. 89ECh. 12 - Prob. 90ECh. 12 - Prob. 91ECh. 12 - Prob. 92ECh. 12 - Prob. 93ECh. 12 - Prob. 94ECh. 12 - Prob. 95ECh. 12 - A certain oxygen atom has the electron...Ch. 12 - Prob. 97ECh. 12 - Prob. 98ECh. 12 - Prob. 99ECh. 12 - Explain why the first ionization energy tends to...Ch. 12 - Prob. 101ECh. 12 - The radius trend and the ionization energy trend...Ch. 12 - Prob. 103ECh. 12 - Prob. 104ECh. 12 - In each of the following sets, which atom or ion...Ch. 12 - Prob. 106ECh. 12 - Prob. 107ECh. 12 - Prob. 108ECh. 12 - Prob. 109ECh. 12 - Prob. 110ECh. 12 - Prob. 111ECh. 12 - Consider the following ionization energies for...Ch. 12 - Prob. 113ECh. 12 - Prob. 114ECh. 12 - Prob. 115ECh. 12 - Prob. 116ECh. 12 - Prob. 117ECh. 12 - Prob. 118ECh. 12 - Prob. 119ECh. 12 - Prob. 120ECh. 12 - Prob. 121ECh. 12 - Prob. 122ECh. 12 - Prob. 123ECh. 12 - Prob. 124ECh. 12 - Prob. 125ECh. 12 - Prob. 126ECh. 12 - Prob. 127ECh. 12 - Prob. 128AECh. 12 - Prob. 129AECh. 12 - Prob. 130AECh. 12 - Prob. 131AECh. 12 - Prob. 132AECh. 12 - Prob. 133AECh. 12 - Prob. 134AECh. 12 - Prob. 135AECh. 12 - Prob. 136AECh. 12 - Prob. 137AECh. 12 - Prob. 138AECh. 12 - Prob. 139AECh. 12 - An unknown element is a nonmetal and has a...Ch. 12 - Prob. 141AECh. 12 - Using data from this chapter, calculate the change...Ch. 12 - Answer the following questions, assuming that ms...Ch. 12 - Prob. 144AECh. 12 - Prob. 145AECh. 12 - Prob. 146AECh. 12 - The figure below represents part of the emission...Ch. 12 - Prob. 148AECh. 12 - Prob. 149AECh. 12 - Prob. 150AECh. 12 - Prob. 151AECh. 12 - Prob. 152AECh. 12 - Prob. 153AECh. 12 - Identify the following three elements. a. The...Ch. 12 - Prob. 155AECh. 12 - Prob. 156AECh. 12 - Prob. 157AECh. 12 - Prob. 158CPCh. 12 - The ground state ionization energy for the one...Ch. 12 - When the excited electron in a hydrogen atom falls...Ch. 12 - Prob. 161CPCh. 12 - The following numbers are the ratios of second...Ch. 12 - Prob. 163CPCh. 12 - Prob. 164CPCh. 12 - Prob. 165CPCh. 12 - Prob. 166CPCh. 12 - The ionization energy for a 1s electron in a...Ch. 12 - Without looking at data in the text, sketch a...
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