a) Interpretation: How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown. Concept introduction: Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond. To show: How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Question

Indicate how to find the energy difference between two levels in cm-1, knowing that its value is 2.5x10-25 joules.

Answer 1

Question

Chapter 9.SE, Problem 43AP

Interpretation Introduction

a)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Interpretation Introduction

b)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond while reduction with Li in liquid deuterated ammonia yields trans alkenes with the two deuterium atoms arranged on the opposite sides of the double bond.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Interpretation Introduction

c)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkyne as the product is to be shown.

Concept introduction:

Deuterium incorporated alkynes can be prepared first by converting them in to alkynides by treating with NaNH₂ in NH₃ and then treating the alkynide obtained with D₃O⁺.

To show:

How to carry out the reaction given which yields deuterium incorporated alkyne as the product.

Interpretation Introduction

d)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkynes can be prepared first by converting them in to alkynides by treating with NaNH₂ in NH₃ and then treating the alkynide obtained with D₃O⁺. The alkyne thus obtained when treated with deuterium in the presence of Lindlar catalyst yield an alkene with deuterium atom on both carbons.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

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Answer 2

Question

Chapter 9.SE, Problem 43AP

Interpretation Introduction

a)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Interpretation Introduction

b)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond while reduction with Li in liquid deuterated ammonia yields trans alkenes with the two deuterium atoms arranged on the opposite sides of the double bond.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Interpretation Introduction

c)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkyne as the product is to be shown.

Concept introduction:

Deuterium incorporated alkynes can be prepared first by converting them in to alkynides by treating with NaNH₂ in NH₃ and then treating the alkynide obtained with D₃O⁺.

To show:

How to carry out the reaction given which yields deuterium incorporated alkyne as the product.

Interpretation Introduction

d)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkynes can be prepared first by converting them in to alkynides by treating with NaNH₂ in NH₃ and then treating the alkynide obtained with D₃O⁺. The alkyne thus obtained when treated with deuterium in the presence of Lindlar catalyst yield an alkene with deuterium atom on both carbons.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Expert Solution & Answer

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Answer 3

Question

Chapter 9.SE, Problem 43AP

Interpretation Introduction

a)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Interpretation Introduction

b)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond while reduction with Li in liquid deuterated ammonia yields trans alkenes with the two deuterium atoms arranged on the opposite sides of the double bond.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Interpretation Introduction

c)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkyne as the product is to be shown.

Concept introduction:

Deuterium incorporated alkynes can be prepared first by converting them in to alkynides by treating with NaNH₂ in NH₃ and then treating the alkynide obtained with D₃O⁺.

To show:

How to carry out the reaction given which yields deuterium incorporated alkyne as the product.

Interpretation Introduction

d)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkynes can be prepared first by converting them in to alkynides by treating with NaNH₂ in NH₃ and then treating the alkynide obtained with D₃O⁺. The alkyne thus obtained when treated with deuterium in the presence of Lindlar catalyst yield an alkene with deuterium atom on both carbons.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Expert Solution & Answer

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Answer 4

Question

Chapter 9.SE, Problem 43AP

Interpretation Introduction

a)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Interpretation Introduction

b)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond while reduction with Li in liquid deuterated ammonia yields trans alkenes with the two deuterium atoms arranged on the opposite sides of the double bond.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Interpretation Introduction

c)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkyne as the product is to be shown.

Concept introduction:

Deuterium incorporated alkynes can be prepared first by converting them in to alkynides by treating with NaNH₂ in NH₃ and then treating the alkynide obtained with D₃O⁺.

To show:

How to carry out the reaction given which yields deuterium incorporated alkyne as the product.

Interpretation Introduction

d)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkynes can be prepared first by converting them in to alkynides by treating with NaNH₂ in NH₃ and then treating the alkynide obtained with D₃O⁺. The alkyne thus obtained when treated with deuterium in the presence of Lindlar catalyst yield an alkene with deuterium atom on both carbons.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Expert Solution & Answer

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Answer 5

Chapter 9.SE, Problem 43AP

Interpretation Introduction

a)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Interpretation Introduction

b)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond while reduction with Li in liquid deuterated ammonia yields trans alkenes with the two deuterium atoms arranged on the opposite sides of the double bond.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Interpretation Introduction

c)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkyne as the product is to be shown.

Concept introduction:

Deuterium incorporated alkynes can be prepared first by converting them in to alkynides by treating with NaNH₂ in NH₃ and then treating the alkynide obtained with D₃O⁺.

To show:

How to carry out the reaction given which yields deuterium incorporated alkyne as the product.

Interpretation Introduction

d)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkynes can be prepared first by converting them in to alkynides by treating with NaNH₂ in NH₃ and then treating the alkynide obtained with D₃O⁺. The alkyne thus obtained when treated with deuterium in the presence of Lindlar catalyst yield an alkene with deuterium atom on both carbons.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Answer 6

Chapter 9.SE, Problem 43AP

Interpretation Introduction

a)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Answer 7

Chapter 9.SE, Problem 43AP

Interpretation Introduction

a)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Answer 8

Interpretation Introduction

b)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond while reduction with Li in liquid deuterated ammonia yields trans alkenes with the two deuterium atoms arranged on the opposite sides of the double bond.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Answer 9

Interpretation Introduction

b)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts. Use of deuterium in the presence of Lindlar catalyst yields cis alkenes with the two deuterium atoms arranged on the same side of the double bond while reduction with Li in liquid deuterated ammonia yields trans alkenes with the two deuterium atoms arranged on the opposite sides of the double bond.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Answer 10

Interpretation Introduction

c)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkyne as the product is to be shown.

Concept introduction:

Deuterium incorporated alkynes can be prepared first by converting them in to alkynides by treating with NaNH₂ in NH₃ and then treating the alkynide obtained with D₃O⁺.

To show:

How to carry out the reaction given which yields deuterium incorporated alkyne as the product.

Answer 11

Interpretation Introduction

c)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkyne as the product is to be shown.

Concept introduction:

Deuterium incorporated alkynes can be prepared first by converting them in to alkynides by treating with NaNH₂ in NH₃ and then treating the alkynide obtained with D₃O⁺.

To show:

How to carry out the reaction given which yields deuterium incorporated alkyne as the product.

Answer 12

Interpretation Introduction

d)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkynes can be prepared first by converting them in to alkynides by treating with NaNH₂ in NH₃ and then treating the alkynide obtained with D₃O⁺. The alkyne thus obtained when treated with deuterium in the presence of Lindlar catalyst yield an alkene with deuterium atom on both carbons.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Answer 13

Interpretation Introduction

d)

Interpretation:

How to carry out the reaction given which yields deuterium incorporated alkene as the product is to be shown.

Concept introduction:

Deuterium incorporated alkynes can be prepared first by converting them in to alkynides by treating with NaNH₂ in NH₃ and then treating the alkynide obtained with D₃O⁺. The alkyne thus obtained when treated with deuterium in the presence of Lindlar catalyst yield an alkene with deuterium atom on both carbons.

To show:

How to carry out the reaction given which yields deuterium incorporated alkene as the product.

Answer 14

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Answer 15

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Answer 25

Ch. 9.1 - Prob. 1P Ch. 9.1 - Prob. 2P Ch. 9.3 - What products would you expect from the following...Ch. 9.4 - Prob. 4P Ch. 9.4 - Prob. 5P Ch. 9.4 - Prob. 6P Ch. 9.4 - Prob. 7P Ch. 9.5 - Using any alkyne needed, how would you prepare the...Ch. 9.7 - The pKa of acetone, CH3COCH3, is 19.3. Which of...Ch. 9.8 - Prob. 10P

Solution Summary: The author explains how deuterium incorporated alkenes can be prepared from alkynes by reduction in the presence of catalysts.

Chapter 9 Solutions