Chemistry: Principles and Practice
Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
bartleby

Concept explainers

bartleby

Videos

Question
Book Icon
Chapter 7, Problem 7.54QE

(a)

Interpretation Introduction

Interpretation:

The notation of subshell if n is 1, l is 1, ml is 0, and ms is 1/2 has to be determined. Also, the reason for not allowed combination has to be determined.

Concept Introduction:

The acceptable wave function is characterized by a set of four quantum numbers. These quantum numbers are related to the shape, size of the electron wave and the location of the electron in space.

1. These quantum numbers are represented by n, l, ml, and ms. The quantum number n is known as principal quantum number and it allowed values are all positive whole numbers. The quantum number l is known as angular momentum quantum number and its allowed values are all positive integer from 0 to n1.

2. The notation of subshell is used to determine by a combination of both principal quantum number and angular quantum number. In notation, numerical values of n is used while value of l denotes the respective subshell. The table for the l values is as follows:

l0123456Subshellspdfghi

3. The quantum number ml is known as the magnetic quantum number. It tells about the orbitals present in the subshell and its allowed values lie between l to +l include 0.

4. The quantum number ms is known as the electron spin quantum number. It represents the spin of the electron and its allowed values are +1/2 and 1/2.

(a)

Expert Solution
Check Mark

Answer to Problem 7.54QE

The given combination of quantum numbers is not allowed.

Explanation of Solution

The value of principal quantum number (n) is 1.

If the value of angular momentum quantum number (l) is 1 then the subshell is p.

The value of magnetic quantum number (ml) is 0.

The value of electron spin quantum number (ms) is 1/2.

Since value of l must be lesser than n but here both values are equal to 1 thus the given combination of quantum numbers is not allowed.

(b)

Interpretation Introduction

Interpretation:

The notation of subshell if n is 4, l is 2, ml is 2, and ms is +1/2 has to be determined. Also, the reason for not allowed combination has to be determined.

Concept Introduction:

Refer to part (a).

(b)

Expert Solution
Check Mark

Answer to Problem 7.54QE

The given combination of quantum numbers is not allowed.

Explanation of Solution

The value of principal quantum number (n) is 4.

If the value of angular momentum quantum number (l) is 2 then the subshell is d.

The value of magnetic quantum number (ml) is 2.

The value of electron spin quantum number (ms) is +1/2.

Since the value of l is lesser than n and ml is also in the range of l to +l, thus it is an allowed combination.

Therefore, the notation of subshell is 4d.

(c)

Interpretation Introduction

Interpretation:

The notation of subshell if n is 2, l is 0, ml is 0, and ms is +1/2 has to be determined. Also, the reason for not allowed combination has to be determined.

Concept Introduction:

Refer to part (a).

(c)

Expert Solution
Check Mark

Answer to Problem 7.54QE

The notation of subshell is 2s.

Explanation of Solution

The value of principal quantum number (n) is 2.

If the value of angular momentum quantum number (l) is 0 then the subshell is s.

The value of magnetic quantum number (ml) is 0.

The value of electron spin quantum number (ms) is +1/2.

Since the value of l is lesser than n and ml is also in the range of l to +l, thus it is an allowed combination.

Therefore, the notation of subshell is 2s.

(d)

Interpretation Introduction

Interpretation:

The notation of subshell if n is 3, l is 0, ml is 1, and ms is 1/2 has to be determined. Also, the reason for not allowed combination has to be determined.

Concept Introduction:

Refer to part (a).

(d)

Expert Solution
Check Mark

Answer to Problem 7.54QE

The given combination of quantum numbers is not allowed.

Explanation of Solution

The value of principal quantum number (n) is 3.

If the value of angular momentum quantum number (l) is 0 then the subshell is s.

The value of magnetic quantum number (ml) is 1.

The value of electron spin quantum number (ms) is 1/2.

Since the value of l is lesser than n but the value of ml greater than the value of l thus the given combination is not allowed.

(e)

Interpretation Introduction

Interpretation:

The notation of subshell if n is 3, l is 2, ml is 0, and ms is +1/2 has to be determined. Also, the reason for not allowed combination has to be determined.

Concept Introduction:

Refer to part (a).

(e)

Expert Solution
Check Mark

Answer to Problem 7.54QE

The notation of subshell is 3d.

Explanation of Solution

The value of principal quantum number (n) is 3.

If the value of angular momentum quantum number (l) is 2 then the subshell is d.

The value of magnetic quantum number (ml) is 0.

The value of electron spin quantum number (ms) is +1/2.

Since the value of l is lesser than n and ml is also in the range of 2 to +2, thus it is an allowed combination.

Therefore, the notation of subshell is 3d.

(f)

Interpretation Introduction

Interpretation:

The notation of subshell if n is 6, l is 0, ml is 0, and ms is +1/2 has to be determined. Also, the reason for not allowed combination has to be determined.

Concept Introduction:

Refer to part (a).

(f)

Expert Solution
Check Mark

Answer to Problem 7.54QE

The notation of subshell is 6s.

Explanation of Solution

The value of principal quantum number (n) is 6.

If the value of angular momentum quantum number (l) is 0 then the subshell is s.

The value of magnetic quantum number (ml) is 0.

The value of electron spin quantum number (ms) is +1/2.

Since the value of l is lesser than n and ml is also in the range of l to +l, thus it is an allowed combination.

Therefore, the notation of subshell is 6s.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Students have asked these similar questions
3) Determine if the pairs are constitutional isomers, enantiomers, diastereomers, or mesocompounds. (4 points)
In the decomposition reaction in solution B → C, only species C absorbs UV radiation, but neither B nor the solvent absorbs. If we call At the absorbance measured at any time, A0 the absorbance at the beginning of the reaction, and A∞ the absorbance at the end of the reaction, which of the expressions is valid? We assume that Beer's law is fulfilled.
> You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: 1. ☑ CI 2. H3O+ O Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. Explanation Check ? DO 18 Ar B © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility

Chapter 7 Solutions

Chemistry: Principles and Practice

Ch. 7 - Prob. 7.11QECh. 7 - Prob. 7.12QECh. 7 - Why is the Heisenberg uncertainty principle an...Ch. 7 - Prob. 7.14QECh. 7 - Prob. 7.15QECh. 7 - Prob. 7.16QECh. 7 - Prob. 7.17QECh. 7 - Prob. 7.18QECh. 7 - Prob. 7.19QECh. 7 - Prob. 7.20QECh. 7 - Prob. 7.21QECh. 7 - Prob. 7.22QECh. 7 - An AM radio station broadcasts at a frequency of...Ch. 7 - An FM radio station broadcasts at a frequency of...Ch. 7 - Prob. 7.25QECh. 7 - Prob. 7.26QECh. 7 - Prob. 7.27QECh. 7 - Prob. 7.28QECh. 7 - This laser emits green light with a wavelength of...Ch. 7 - Prob. 7.30QECh. 7 - What is the energy (in kJ) of 1 mol of photons...Ch. 7 - Prob. 7.32QECh. 7 - Prob. 7.33QECh. 7 - Prob. 7.34QECh. 7 - Prob. 7.35QECh. 7 - Prob. 7.36QECh. 7 - Prob. 7.37QECh. 7 - Prob. 7.38QECh. 7 - Prob. 7.39QECh. 7 - Prob. 7.40QECh. 7 - Prob. 7.41QECh. 7 - Prob. 7.42QECh. 7 - Prob. 7.43QECh. 7 - Prob. 7.44QECh. 7 - Prob. 7.45QECh. 7 - Prob. 7.46QECh. 7 - Prob. 7.47QECh. 7 - Prob. 7.48QECh. 7 - Prob. 7.49QECh. 7 - Prob. 7.50QECh. 7 - Prob. 7.51QECh. 7 - Prob. 7.52QECh. 7 - Prob. 7.53QECh. 7 - Prob. 7.54QECh. 7 - (a) How many subshells are present in the n = 4...Ch. 7 - Prob. 7.56QECh. 7 - Prob. 7.57QECh. 7 - Prob. 7.58QECh. 7 - In what region of space is the probability of...Ch. 7 - Prob. 7.60QECh. 7 - Prob. 7.61QECh. 7 - Prob. 7.62QECh. 7 - Sketch an orbital contour that is expected for an...Ch. 7 - Prob. 7.64QECh. 7 - Prob. 7.65QECh. 7 - Prob. 7.66QECh. 7 - Prob. 7.67QECh. 7 - Prob. 7.68QECh. 7 - Prob. 7.69QECh. 7 - Prob. 7.70QECh. 7 - Prob. 7.71QECh. 7 - Prob. 7.72QECh. 7 - Prob. 7.73QECh. 7 - Prob. 7.74QECh. 7 - Prob. 7.75QECh. 7 - Prob. 7.76QECh. 7 - Prob. 7.77QECh. 7 - Prob. 7.78QECh. 7 - Prob. 7.79QECh. 7 - What are the four quantum numbers of the highest...Ch. 7 - Prob. 7.81QECh. 7 - Prob. 7.82QECh. 7 - Prob. 7.83QECh. 7 - Prob. 7.84QECh. 7 - Prob. 7.85QECh. 7 - Prob. 7.86QECh. 7 - Prob. 7.87QECh. 7 - Prob. 7.88QECh. 7 - Prob. 7.89QECh. 7 - Prob. 7.90QECh. 7 - Prob. 7.91QECh. 7 - Prob. 7.92QECh. 7 - Prob. 7.93QECh. 7 - Prob. 7.94QECh. 7 - Prob. 7.95QECh. 7 - Prob. 7.96QECh. 7 - Prob. 7.97QECh. 7 - Use the aufbau procedure to obtain the electron...Ch. 7 - Prob. 7.99QECh. 7 - Prob. 7.100QECh. 7 - Prob. 7.101QECh. 7 - Prob. 7.102QECh. 7 - Prob. 7.103QECh. 7 - A baseball weighs 142 g. A professional pitcher...
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Text book image
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Text book image
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Text book image
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
Text book image
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
The Bohr Model of the atom and Atomic Emission Spectra: Atomic Structure tutorial | Crash Chemistry; Author: Crash Chemistry Academy;https://www.youtube.com/watch?v=apuWi_Fbtys;License: Standard YouTube License, CC-BY