Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 7, Problem 7.15QE
Interpretation Introduction
Interpretation:
The energy-level diagram for a multielectron atom for
Concept Introduction:
The attraction between opposite signs occurs when an electron gets closer to the nucleus. This attraction force at a distance of
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For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3)
→
Give the expression for the acceptable rate.
→
→
(A).
d[N205]
dt
==
2k,k₂[N₂O₂]
k₁+k₁₂
(B).
d[N2O5]
=-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³
dt
(C).
d[N2O5]
=-k₁[N₂O] + k [NO] - k₂[NO] [NO]
d[N2O5]
(D).
=
dt
= -k₁[N2O5] - k¸[NO][N₂05]
dt
Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3)
→
Give the expression for the acceptable rate.
→
→
(A).
d[N205]
dt
==
2k,k₂[N₂O₂]
k₁+k₁₂
(B).
d[N2O5]
=-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³
dt
(C).
d[N2O5]
=-k₁[N₂O] + k [NO] - k₂[NO] [NO]
d[N2O5]
(D).
=
dt
= -k₁[N2O5] - k¸[NO][N₂05]
dt
Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
R lactam or lactone considering as weak acid or weak base and why
Chapter 7 Solutions
Chemistry: Principles and Practice
Ch. 7 - Prob. 7.1QECh. 7 - Prob. 7.2QECh. 7 - Prob. 7.3QECh. 7 - Prob. 7.4QECh. 7 - Prob. 7.5QECh. 7 - Prob. 7.6QECh. 7 - Prob. 7.7QECh. 7 - Prob. 7.8QECh. 7 - Prob. 7.9QECh. 7 - Prob. 7.10QE
Ch. 7 - Prob. 7.11QECh. 7 - Prob. 7.12QECh. 7 - Why is the Heisenberg uncertainty principle an...Ch. 7 - Prob. 7.14QECh. 7 - Prob. 7.15QECh. 7 - Prob. 7.16QECh. 7 - Prob. 7.17QECh. 7 - Prob. 7.18QECh. 7 - Prob. 7.19QECh. 7 - Prob. 7.20QECh. 7 - Prob. 7.21QECh. 7 - Prob. 7.22QECh. 7 - An AM radio station broadcasts at a frequency of...Ch. 7 - An FM radio station broadcasts at a frequency of...Ch. 7 - Prob. 7.25QECh. 7 - Prob. 7.26QECh. 7 - Prob. 7.27QECh. 7 - Prob. 7.28QECh. 7 - This laser emits green light with a wavelength of...Ch. 7 - Prob. 7.30QECh. 7 - What is the energy (in kJ) of 1 mol of photons...Ch. 7 - Prob. 7.32QECh. 7 - Prob. 7.33QECh. 7 - Prob. 7.34QECh. 7 - Prob. 7.35QECh. 7 - Prob. 7.36QECh. 7 - Prob. 7.37QECh. 7 - Prob. 7.38QECh. 7 - Prob. 7.39QECh. 7 - Prob. 7.40QECh. 7 - Prob. 7.41QECh. 7 - Prob. 7.42QECh. 7 - Prob. 7.43QECh. 7 - Prob. 7.44QECh. 7 - Prob. 7.45QECh. 7 - Prob. 7.46QECh. 7 - Prob. 7.47QECh. 7 - Prob. 7.48QECh. 7 - Prob. 7.49QECh. 7 - Prob. 7.50QECh. 7 - Prob. 7.51QECh. 7 - Prob. 7.52QECh. 7 - Prob. 7.53QECh. 7 - Prob. 7.54QECh. 7 - (a) How many subshells are present in the n = 4...Ch. 7 - Prob. 7.56QECh. 7 - Prob. 7.57QECh. 7 - Prob. 7.58QECh. 7 - In what region of space is the probability of...Ch. 7 - Prob. 7.60QECh. 7 - Prob. 7.61QECh. 7 - Prob. 7.62QECh. 7 - Sketch an orbital contour that is expected for an...Ch. 7 - Prob. 7.64QECh. 7 - Prob. 7.65QECh. 7 - Prob. 7.66QECh. 7 - Prob. 7.67QECh. 7 - Prob. 7.68QECh. 7 - Prob. 7.69QECh. 7 - Prob. 7.70QECh. 7 - Prob. 7.71QECh. 7 - Prob. 7.72QECh. 7 - Prob. 7.73QECh. 7 - Prob. 7.74QECh. 7 - Prob. 7.75QECh. 7 - Prob. 7.76QECh. 7 - Prob. 7.77QECh. 7 - Prob. 7.78QECh. 7 - Prob. 7.79QECh. 7 - What are the four quantum numbers of the highest...Ch. 7 - Prob. 7.81QECh. 7 - Prob. 7.82QECh. 7 - Prob. 7.83QECh. 7 - Prob. 7.84QECh. 7 - Prob. 7.85QECh. 7 - Prob. 7.86QECh. 7 - Prob. 7.87QECh. 7 - Prob. 7.88QECh. 7 - Prob. 7.89QECh. 7 - Prob. 7.90QECh. 7 - Prob. 7.91QECh. 7 - Prob. 7.92QECh. 7 - Prob. 7.93QECh. 7 - Prob. 7.94QECh. 7 - Prob. 7.95QECh. 7 - Prob. 7.96QECh. 7 - Prob. 7.97QECh. 7 - Use the aufbau procedure to obtain the electron...Ch. 7 - Prob. 7.99QECh. 7 - Prob. 7.100QECh. 7 - Prob. 7.101QECh. 7 - Prob. 7.102QECh. 7 - Prob. 7.103QECh. 7 - A baseball weighs 142 g. A professional pitcher...
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- 81. a. Propose a mechanism for the following reaction: OH CH2=CHCHC=N b. What is the product of the following reaction? HO H₂O N=CCH2CH2CH OH HO CH3CCH=CH2 H₂O C=N 82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium uliaarrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HEarrow_forwardPredicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.arrow_forward
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- A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardGiven a complex reaction with rate equation v = k1[A] + k2[A]2, what is the overall reaction order?arrow_forwardPlease draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forward
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