General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Chapter 5, Problem 81IAE
Interpretation Introduction
Interpretation:
The mass percent of sulfuric acid H2SO4 in the given sample of battery acid needs to be deduced from its titration with Ba(OH)2.
Concept introduction:
- Titration is a method of quantitative analysis which is used to determine the concentration of unknown solutions. A titrant of known concentration is added to an analyte of known volume in the presence of a suitable indicator until the equivalence point is reached which is indicated by a change in the color of the analyte.
- In a titration, equivalence point is the point at which the amount of titrant added is just sufficient to neutralize the amount of analyte taken.
- Concentration of a solution is expressed in terms of molarity which is the ratio of the moles of solute divided by the volume of the solution in liters.
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When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.
Q6: Using acetic acid as the acid, write the balanced chemical equation for the protonation of
the two bases shown (on the -NH2). Include curved arrows to show the mechanism.
O₂N-
O₂N.
-NH2
-NH2
a) Which of the two Bronsted bases above is the stronger base? Why?
b) Identify the conjugate acids and conjugate bases for the reactants.
c) Identify the Lewis acids and bases in the reactions.
Chapter 5 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 5 - Using information from this chapter, indicate...Ch. 5 - Select the (a) best and (b) poorest electrical...Ch. 5 - What response would you expect in the apparatus of...Ch. 5 - NH2(aq) conducts electric current only weakly. The...Ch. 5 - Sketches (a-c) are molecular views of the solute...Ch. 5 - Prob. 6ECh. 5 - Determine the concentration of the ion indicated...Ch. 5 - Which solution has the greatest [SO42] ? a....Ch. 5 - A solution is prepared by dissolving...Ch. 5 - Prob. 10E
Ch. 5 - Prob. 11ECh. 5 - Prob. 12ECh. 5 - Which of the following aqueous solutions has the...Ch. 5 - Prob. 14ECh. 5 - Prob. 15ECh. 5 - If 18.2 mL H2O evaporates from 1.00 L of a...Ch. 5 - Prob. 17ECh. 5 - Assuming the volumes are additive, what he [NO3]...Ch. 5 - Complete each of the following as net ionic...Ch. 5 - Prob. 20ECh. 5 - Prob. 21ECh. 5 - Predict in each case whether a reaction is likely...Ch. 5 - What reagent solution might you use to separate...Ch. 5 - Prob. 24ECh. 5 - Prob. 25ECh. 5 - Prob. 26ECh. 5 - Complete each of the following as a net ionic...Ch. 5 - Every antacid one or more ingredients capable of...Ch. 5 - Prob. 29ECh. 5 - Prob. 30ECh. 5 - Which solutions would you use to precipitate Mg24...Ch. 5 - Prob. 32ECh. 5 - Assign oxidation states to the elements involved...Ch. 5 - Explain why these reactions cannot occur as...Ch. 5 - Prob. 35ECh. 5 - Prob. 36ECh. 5 - Balance these equations for redox reactions...Ch. 5 - Balance these equations for redox reactions...Ch. 5 - Balance these equations for redox reactions in...Ch. 5 - Balance these equations for redox reactions...Ch. 5 - Balance these equations for disproportionation...Ch. 5 - Prob. 42ECh. 5 - Prob. 43ECh. 5 - Prob. 44ECh. 5 - The following reactions do not occur in aqueous...Ch. 5 - The reactions do not occur in aqueous solutions....Ch. 5 - What are the oxidizing and reducing agents in the...Ch. 5 - Thiosulfate ion, S2O32 , is a reducing agent can...Ch. 5 - What volume of 0.0962 N NaOH is required to...Ch. 5 - Prob. 50ECh. 5 - Prob. 51ECh. 5 - How many milliliters of 0.0750MBa(OH)2 are...Ch. 5 - An NaOH(aq) solution cannot be made up to an exact...Ch. 5 - Household ammonia, used as a window cleaner and...Ch. 5 - Prob. 55ECh. 5 - Prob. 56ECh. 5 - Prob. 57ECh. 5 - A 7.55 g sample of Na2CO2(s) is added to 125 mL of...Ch. 5 - Prob. 59ECh. 5 - Prob. 60ECh. 5 - Prob. 61ECh. 5 - Prob. 62ECh. 5 - A KMnO4(eq) solution is to be standardized by...Ch. 5 - Prob. 64ECh. 5 - An iron ore sample weighing0.6132 g dissolved...Ch. 5 - The concentration of Mn2+(aq) can be determined by...Ch. 5 - The titration of 5.00 mL of a saturated solution...Ch. 5 - Prob. 68ECh. 5 - Prob. 69IAECh. 5 - Following are some laboratory methods occasionally...Ch. 5 - Prob. 71IAECh. 5 - You have a solution that is 0.0250 M Ba(OH) and...Ch. 5 - Prob. 73IAECh. 5 - Prob. 74IAECh. 5 - Prob. 75IAECh. 5 - An unknown whitesolid consists of two compounds,...Ch. 5 - Balance these equations for reactions in acidic...Ch. 5 - Prob. 78IAECh. 5 - A method of producing phosphine, PH2, from...Ch. 5 - Prob. 80IAECh. 5 - Prob. 81IAECh. 5 - A piece of marble (assume it is pure CaCO2) reacts...Ch. 5 - The reaction below can be used as laboratory...Ch. 5 - Refer to Example 5-10. Suppose that the KMnO4(aq)...Ch. 5 - Prob. 85IAECh. 5 - A 0.4324 g sample of a potassium hydroxidelithium...Ch. 5 - Prob. 87IAECh. 5 - Prob. 88IAECh. 5 - The active ingredients h a particular antacid...Ch. 5 - Prob. 90IAECh. 5 - Prob. 91IAECh. 5 - Copper refining traditionally involves "roasting"...Ch. 5 - Prob. 93IAECh. 5 - Sodium cyclopentadienide, NaC2H2, is a common...Ch. 5 - Manganese is derived from pyrolusiteore, an impure...Ch. 5 - Prob. 96FPCh. 5 - Prob. 97FPCh. 5 - Prob. 98FPCh. 5 - Prob. 99SAECh. 5 - Prob. 100SAECh. 5 - Prob. 101SAECh. 5 - Prob. 102SAECh. 5 - Prob. 103SAECh. 5 - Prob. 104SAECh. 5 - Prob. 105SAECh. 5 - Prob. 106SAECh. 5 - Prob. 107SAECh. 5 - When aqueous sodium carbonate, Na2CO2, is treated...Ch. 5 - Prob. 109SAECh. 5 - Consider the following redox reaction:...Ch. 5 - Balance the following oxidation—reduction...Ch. 5 - Prob. 112SAECh. 5 - What is the simplest ratio a:b when the equation...Ch. 5 - In the half-reaction in which NpO2+ is converted...Ch. 5 - Which list of compounds contains a nonelectrolyte,...Ch. 5 - Prob. 116SAECh. 5 - Which list of compounds contains two soluble...Ch. 5 - Classify each of the blowing statements as true or...Ch. 5 - Which of the following reactions are oxidation-...Ch. 5 - Prob. 120SAECh. 5 - Prob. 121SAE
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- Q5: For the two reactions below: a) Use curved electron-pushing arrows to show the mechanism for the reaction in the forward direction. Redraw the compounds to explicitly illustrate all bonds that are broken and all bonds that are formed. b) Label Bronsted acids and bases in the left side of the reactions. c) For reaction A, which anionic species is the weakest base? Which neutral compound is the stronger acid? Is the forward or reverse reaction favored? d) Label Lewis acids and bases, nucleophiles and electrophiles in the left side of the reactions. A. 용 CH3OH я хон CH3O OH B. HBr CH3ONa NaBr CH3OHarrow_forwardpotential energy Br b) Translate the Newman projection below to its wedge-and-dash drawing. F H. OH CH3 CI c) Isopentane (2-methylbutane) is a compound containing a branched carbon chain. Draw a Newman projection of six conformations about the C2-C3 bond of isopentane. On the curve of potential energy versus angle of internal rotation for isopentane, label each energy maximum and minimum with one of the conformations. 0° 。 F A B D C angle of internal rotation E F 360° (=0°) JDownlarrow_forwardQ7: Identify the functional groups in these molecules a) CH 3 b) Aspirin: HO 'N' Capsaicin HO O CH3 CH 3arrow_forward
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