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A KMnO4(eq) solution is to be standardized by titration against
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General Chemistry: Principles and Modern Applications (11th Edition)
- For a product to be called vinegar, it must contain at least 5.0% acetic acid, HC2H3O2, by mass. A 10.00-g sample of a raspberry vinegar is titrated with 0.1250 M Ba(OH)2 and required 37.50 mL for complete neutralization. Can the product be called a vinegar?arrow_forwardCalcium in blood or urine can be determined by precipitation as calcium oxalate, CaC2O4. The precipitate is dissolved in strong acid and titrated with potassium permanganate. The equation for reaction is 2MnO4(aq)+6H+(aq)+5H2C2O4(aq)2Mn2+(aq)+10CO2(g)+8H2O A 24-hour urine sample is collected from an adult patient, reduced to a small volume, and titrated with 26.2 mL of 0.0946 M KMnO4. How many grams of calcium oxalate are in the sample? Normal range for Ca2+ output for an adult is 100 to 300 mg per 24 hour. Is the sample within the normal range?arrow_forward1. Sometimes a reaction can fall in more than one category. Into what category (or categories) does the reaction of Ba(OH)2(aq) + H+PO4(aq) fit? acid-base and oxidation-reduction oxidation-reduction acid-base and precipitation precipitationarrow_forward
- 2. Equal amounts (moles) of acetic acid(aq) and sodium sulfite, Na2SO3(aq), are mixed. The resulting solution is acidic basic neutralarrow_forwardArsenic acid, H3AsO4, is a poisonous acid that has been used in the treatment of wood to prevent insect damage. Arsenic acid has three acidic protons. Say you take a 25.00-mL sample of arsenic acid and prepare it for titration with NaOH by adding 25.00 mL of water. The complete neutralization of this solution requires the addition of 53.07 mL of 0.6441 M NaOH solution. Write the balanced chemical reaction for the titration, and calculate the molarity of the arsenic acid sample.arrow_forwardTriiodide ions are generated in solution by the following (unbalanced) reaction in acidic solution: IO3(aq) + I(aq) I3(aq) Triiodide ion concentration is determined by titration with a sodium thiosulfate (Na2S2O3) solution. The products are iodide ion and tetrathionate ion (S4O6). a. Balance the equation for the reaction of IO3 with I ions. b. A sample of 0.6013 g of potassium iodate was dissolved in water. Hydrochloric acid and solid potassium iodide were then added. What is the minimum mass of solid KI and the minimum volume of 3.00 M HQ required to convert all of the IO3 ions to I ions? c. Write and balance the equation for the reaction of S2O32 with I3 in acidic solution. d. A 25.00-mL sample of a 0.0100 M solution of KIO. is reacted with an excess of KI. It requires 32.04 mL of Na2S2O3 solution to titrate the I3 ions present. What is the molarity of the Na2S2O3 solution? e. How would you prepare 500.0 mL of the KIO3 solution in part d using solid KIO3?arrow_forward
- A 25.0-mL sample of vinegar (which contains the weak acid acetic acid, CH3CO2H) requires 28.33 mL of a 0.953 M solution of NaOH for titration to the equivalence point. What is the mass of acetic acid (molar mass = 60.05 g/mol), in grams, in the vinegar sample, and what is the concentration of acetic acid in the vinegar? CH3CO2H(aq) + NaOH(aq) NaCH3CO2(aq) + H2O(l)arrow_forwardThe active ingredients of an antacid tablet contained only magnesium hydroxide and aluminum hydroxide. Complete neutralization of a sample of the active ingredients required 48.5 mL of 0.187 M hydrochloric acid. The chloride salts from this neutralization were obtained by evaporation of the filtrate from the titration; they weighed 0. 4200 g. What was the percentage by mass of magnesium hydroxide in the active ingredients of the antacid tablet?arrow_forwardA 0.608-g sample of fertilizer contained nitrogen as ammonium sulfate, (NH4)2SO4. It was analyzed for nitrogen by heating with sodium hydroxide. (NH4)2SO4(s)+2NaOH(aq)Na2SO4(aq)+2H2O(l)+2NH3(g) The ammonia was collected in 46.3 mL of 0.213 M HCl (hydrochloric acid), with which it reacted. NH3(g)+HCl(aq)NH4Cl(aq) This solution was titrated for excess hydrochloric acid with 44.3 mL of 0.128 M NaOH. NaOH(aq)+HCl(aq)NaCl(aq)+H2O(l) What is the percentage of nitrogen in the fertilizer?arrow_forward
- Glycerol (C3H8O3) is commonly used as an additive to moisturizers. The amount of glycerol added can be determined by titration with permanganate in basic solution. 14MnO4(aq)+C3H8O3(aq)+20OH(aq)14MnO42(aq)+3CO32(aq)+14H2O How many milliliters of 6.15 M KMnO4 are required to completely react with 7.25 mL of an aqueous solution of glycerol (d=1.144g/mL) that is 51.6% by mass?arrow_forwardPotassium hydrogen phthalate (abbreviated as KHP) has the molecular formula KHC8H4O4 and a molar mass of 204.22 g/mol. KHP has one acidic hydrogen. A solid sample of KHP is dissolved in 50 mL of water and titrated to the equivalence point with 22.90 mL of a 0.5010 M NaOH solution. How many grams of KHP were used in the titration?arrow_forwardA 8.50 g sample of KCl is dissolved in 66.0 mL of water. The resulting solution is then added to 72.0 mL of a 0.280 M CaCl2(aq) solution. Assuming that the volumes are additive, calculate the concentrations of each ion present in the final solution.arrow_forward
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