Concept explainers
The reactions do not occur in aqueous solutions. Balance their equations by the half-equation method, as suggested in Are You Wondering 5-2.
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Chapter 5 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
- A 1.345-g sample of a compound of barium and oxygen was dissolved in hydrochloric acid to give a solution of barium ion, which was then precipitated with an excess of potassium chromate to give 2.012 g of barium chromate, BaCrO4. What is the formula of the compound?arrow_forward1. Sometimes a reaction can fall in more than one category. Into what category (or categories) does the reaction of Ba(OH)2(aq) + H+PO4(aq) fit? acid-base and oxidation-reduction oxidation-reduction acid-base and precipitation precipitationarrow_forward3.14 A number of compounds are used in cement, and reactions among them occur when water is added. In one, CaO reacts with Al2O3 and water to form Ca3Al2(OH)12. Write a bal- anced chemical equation for this process.arrow_forward
- Chlorine gas was first prepared in 1774 by C. W. Scheele by oxidizing sodium chloride with manganese(IV) oxide. The reaction is NaCl(aq) + H2SO4(aq) + MnO2(s) Na2SO4(aq) + MnCl2(aq) + H2O(l) + Cl2 (g) Balance this equation.arrow_forwardPhosphoric acid is prepared by dissolving phosphorus(V) oxide, P4O10, in water. What is the balanced equation for this reaction? How many grams of P4O10 are required to make 1.19 L of aqueous solution containing 5.50% phosphoric acid by mass? The density of the solution is 1.025 g/mL.arrow_forwardTriiodide ions are generated in solution by the following (unbalanced) reaction in acidic solution: IO3(aq) + I(aq) I3(aq) Triiodide ion concentration is determined by titration with a sodium thiosulfate (Na2S2O3) solution. The products are iodide ion and tetrathionate ion (S4O6). a. Balance the equation for the reaction of IO3 with I ions. b. A sample of 0.6013 g of potassium iodate was dissolved in water. Hydrochloric acid and solid potassium iodide were then added. What is the minimum mass of solid KI and the minimum volume of 3.00 M HQ required to convert all of the IO3 ions to I ions? c. Write and balance the equation for the reaction of S2O32 with I3 in acidic solution. d. A 25.00-mL sample of a 0.0100 M solution of KIO. is reacted with an excess of KI. It requires 32.04 mL of Na2S2O3 solution to titrate the I3 ions present. What is the molarity of the Na2S2O3 solution? e. How would you prepare 500.0 mL of the KIO3 solution in part d using solid KIO3?arrow_forward
- One of the ways to remove nitrogen monoxide gas, a serious source of air pollution, from smokestack emissions is by reaction with ammonia gas, NH3. The products of the reaction, N2 and H2O, are not toxic. Write the balanced equation for this reaction. Assign an oxidation number to each element in the reactants and products, and indicate which element is oxidized and which is reduced.arrow_forwardWhen organic compounds containing sulfur are burned, sulfur dioxide is produced. The amount of SO2formed can be determined by the reaction with hydrogen peroxide: H2O2(aq)+SO2(g)H2SO4(aq) The resulting sulfuric acid is then titrated with a standard NaOH solution. A 1 .302-g sample of coal is burned, and the SO2is collected in a solution of hydrogen peroxide. It took 28.44 mL of a 0.1000 M NaOH solution to titrate the resulting sulfuric acid. Calculate the mass percent of sulfur in the coal sample. Sulfuric acid has two acidic hydrogens.arrow_forwardWhen 10. L of water is added to 3.0 L of 6.0 M H2SO4, what is the molarity of the resulting solution? Assume the volumes are additive.arrow_forward
- (a) Butane gas, C4H10, can burn completely in air [use O2(g) as the other reactant] to give carbon dioxide gas and water vapor. Write a balanced equation for this combustion reaction. (b) Write a balanced chemical equation for the complete combustion of C3H7BO3, a gasoline additive. The products of combustion are CO2(g), H2O(g), and B2O3(s).arrow_forwardWhen organic compounds containing sulfur are burned, sulfurdioxide is produced. The amount of SO2 formed can be determined by the reaction with hydrogen peroxide: H2O2(aq)+SO2(g)H2SO4(aq) The resulting sulfuric acid is then titrated with a standard NaOH solution. A 1.302-g sample of coal is burned and the SO2 is collected in a solution of hydrogen peroxide. It took 28.44 mL of a 0.1000-M NaOH solution to titrate the resulting sulfuric acid. Calculate the mass percent of sulfur in the coal sample. Sulfuric acid has two acidic hydrogens.arrow_forwardPotassium permanganate (KMnO4) solutions are used for the determination of Fe2+ in samples of unknown concentration. As a laboratory assistant, you are supposed to prepare 500 mL of a 0.1000 M KMnO4 solution. What mass of KMnO4, in grams, do you need?arrow_forward
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