1 Matter: Its Properties And Measurement 2 Atoms And The Atomic Theory 3 Chemical Compounds 4 Chemical Reactions 5 Introduction To Reactions In Aqueous Solutions 6 Gases 7 Thermochemistry 8 Electrons In Atoms 9 The Periodic Table And Some Atomic Properties 10 Chemical Bonding I: Basic Concepts 11 Chemical Bonding Ii: Valence Bond And Molecular Orbital Theories 12 Intermolecular Forces: Liquids And Solids 13 Spontaneous Change: Entropy And Gibbs Energy 14 Solutions And Their Physical Properties 15 Principles Of Chemical Equilibrium 16 Acids And Bases 17 Additional Aspects Of Acid–base Equilibria 18 Solubility And Complex-ion Equilibria 19 Electrochemistry 20 Chemical Kinetics 21 Chemistry Of The Main-group Elements I: Groups 1, 2, 13, And 14 22 Chemistry Of The Main-group Elements Ii: Groups 18, 17, 16, 15, And Hydrogen 23 The Transition Elements 24 Complex Ions And Coordination Compounds 25 Nuclear Chemistry 26 Structures Of Organic Compounds 27 Reactions Of Organic Compounds expand_more
Chapter Questions expand_more
Problem 1E: Using information from this chapter, indicate wheeler each of the following substances in aqueous... Problem 2E: Select the (a) best and (b) poorest electrical conductors from the following solutions, and explain... Problem 3E: What response would you expect in the apparatus of Figure 5-4 if the solution tested were 1.0 M HCI?... Problem 4E: NH2(aq) conducts electric current only weakly. The same is true for CH2COOH(aq) . When these... Problem 5E: Sketches (a-c) are molecular views of the solute in an aqueous solution. For each of the sketches,... Problem 6E Problem 7E: Determine the concentration of the ion indicated in each solution.... Problem 8E: Which solution has the greatest [SO42] ? a. 0.075MH2SO4; b. 0.22MMgSO4; c. 0.15MNa2SO4; d.... Problem 9E: A solution is prepared by dissolving 0.132gBa(OH)2.8H2Oin275mL of water solution. What is [OH] in... Problem 10E Problem 11E Problem 12E Problem 13E: Which of the following aqueous solutions has the highest concentration of K-? a. 0.0850MK2SO4; b. a... Problem 14E Problem 15E Problem 16E: If 18.2 mL H2O evaporates from 1.00 L of a solution containing 15.5mgK2SO4/mL, what is K1] in the... Problem 17E Problem 18E: Assuming the volumes are additive, what he [NO3] in a solution obtained by mixing 275 mL of 0.283 M... Problem 19E: Complete each of the following as net ionic equation, indicating whether precipitate forms. If no... Problem 20E Problem 21E Problem 22E: Predict in each case whether a reaction is likely to occur. If so, write a net ionic equation. a.... Problem 23E: What reagent solution might you use to separate the cations the following matures, that is, with one... Problem 24E Problem 25E Problem 26E Problem 27E: Complete each of the following as a net ionic equation. If no reaction occurs, so state. a.... Problem 28E: Every antacid one or more ingredients capable of reacting with excess (HCI). The essential... Problem 29E Problem 30E Problem 31E: Which solutions would you use to precipitate Mg24 from an aqueous solution of MgCl2? Explain your... Problem 32E Problem 33E: Assign oxidation states to the elements involved in the following reactions. Indicate which are... Problem 34E: Explain why these reactions cannot occur as written. a.... Problem 35E Problem 36E Problem 37E: Balance these equations for redox reactions occurring in acidic solution. a. MnO4+IMn2++I2(s) b.... Problem 38E: Balance these equations for redox reactions occurring in acidic solution. a. P4(s)+NO3H2PO4+NO(g) b.... Problem 39E: Balance these equations for redox reactions in basic solution. a. MnO2(s)+CIO3MnO4+CI b.... Problem 40E: Balance these equations for redox reactions occurring in basic solution. a.... Problem 41E: Balance these equations for disproportionation reactions. a. CI2(g)CI+CIO3 (basic solution) b.... Problem 42E Problem 43E Problem 44E Problem 45E: The following reactions do not occur in aqueous solutions. Balance their equations by the... Problem 46E: The reactions do not occur in aqueous solutions. Balance their equations by the half-equation... Problem 47E: What are the oxidizing and reducing agents in the following redox reactions? a.... Problem 48E: Thiosulfate ion, S2O32 , is a reducing agent can be oxidized to different products, depending on the... Problem 49E: What volume of 0.0962 N NaOH is required to exactly neutralize 10.00 mL of 0.128 M HCI? Problem 50E Problem 51E Problem 52E: How many milliliters of 0.0750MBa(OH)2 are required to titrate 200.0 mL of 0.0165 M HNO2 ? Problem 53E: An NaOH(aq) solution cannot be made up to an exact concentration simply by weighing out the required... Problem 54E: Household ammonia, used as a window cleaner and for other cleaning purposes, isNH2(aq). The NH2... Problem 55E Problem 56E Problem 57E Problem 58E: A 7.55 g sample of Na2CO2(s) is added to 125 mL of a vinegar that is 0.762 M CH2COOH . Will the... Problem 59E Problem 60E Problem 61E Problem 62E Problem 63E: A KMnO4(eq) solution is to be standardized by titration against AS2C2 (s). A 0.1078 g sample of... Problem 64E Problem 65E: An iron ore sample weighing0.6132 g dissolved HCl(aq), and the iron is obtained as Fe24(aq) . This... Problem 66E: The concentration of Mn2+(aq) can be determined by titration with MnO4(aq) in basic solution. A... Problem 67E: The titration of 5.00 mL of a saturated solution of sodium oxalate, Na2C2O4, at 25C requires 25.8 mL... Problem 68E Problem 69IAE Problem 70IAE: Following are some laboratory methods occasionally used for the preparation of small quantities of... Problem 71IAE Problem 72IAE: You have a solution that is 0.0250 M Ba(OH) and the following pieces of equipment:1.00, 5.00, 10.00,... Problem 73IAE Problem 74IAE Problem 75IAE Problem 76IAE: An unknown whitesolid consists of two compounds, each containing a different cation. As suggested in... Problem 77IAE: Balance these equations for reactions in acidic solution. a. IBr+BrO+H+IO3+Br+H2O b.... Problem 78IAE Problem 79IAE: A method of producing phosphine, PH2, from elemental phosphorus, P4, involves heating the P4, with... Problem 80IAE Problem 81IAE Problem 82IAE: A piece of marble (assume it is pure CaCO2) reacts with 200 L of 2.52 M HCI. After dissolution of... Problem 83IAE: The reaction below can be used as laboratory method of preparing small quantities of CI2(g) . If a... Problem 84IAE: Refer to Example 5-10. Suppose that the KMnO4(aq) were standardized by reaction with AS2O2 instead... Problem 85IAE Problem 86IAE: A 0.4324 g sample of a potassium hydroxidelithium hydroxide mixture requires 28.28 ml of 0.3520 M... Problem 87IAE Problem 88IAE Problem 89IAE: The active ingredients h a particular antacid tablets are aluminum hydroxide, Al(OH)2, and magnesium... Problem 90IAE Problem 91IAE Problem 92IAE: Copper refining traditionally involves "roasting" insoluble sulfide ores (CuS) with oxygen.... Problem 93IAE Problem 94FP: Sodium cyclopentadienide, NaC2H2, is a common reducing agent in the chemical laboratory, but there... Problem 95FP: Manganese is derived from pyrolusiteore, an impure manganese dioxide. In the procedure used to... Problem 96FP Problem 97FP Problem 98FP Problem 99SAE Problem 100SAE Problem 101SAE Problem 102SAE Problem 103SAE Problem 104SAE Problem 105SAE Problem 106SAE Problem 107SAE Problem 108SAE: When aqueous sodium carbonate, Na2CO2, is treated with dilute hydrochloric acid, HCI, the products... Problem 109SAE Problem 110SAE: Consider the following redox reaction: 4NO(g)+3O2(g)+2H2O(I)4N03(aq)+4H+(aq) a. Which species is... Problem 111SAE: Balance the following oxidation—reduction equations. a. Cl2(aq)Cl-(aq)+CIO-(aq) (basic solution) b.... Problem 112SAE Problem 113SAE: What is the simplest ratio a:b when the equation below is property balanced?... Problem 114SAE: In the half-reaction in which NpO2+ is converted to Np4+ , the number of electrons appearing in the... Problem 115SAE: Which list of compounds contains a nonelectrolyte, a weak electrolyte, and e strong electrolyte?... Problem 116SAE Problem 117SAE: Which list of compounds contains two soluble compounds and an insoluble one? a. HgBr2,MnSO4,Na2C2O4;... Problem 118SAE: Classify each of the blowing statements as true or false. a. Barium chloride, BaCl2, is a weak... Problem 119SAE: Which of the following reactions are oxidation- reduction reactions? a. H2CO3(aq)H2O(I)+CO2(g) b.... Problem 120SAE Problem 121SAE format_list_bulleted