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- Problem 5.30 Page 204 State how each pair of compounds is related. Are they enantiomers, diastereomers, constitutional isomers, or identical? Br а. HO, and Br но b. and С. HO- and OH HO d. Он and OH но HOPage 203 Problem 5.29 Draw all possible stereoisomers for each compound. Label pairs of enantiomers and diastereomers. a. b. но c.Problem 5.23 Which compounds are meso compounds? a. HO.. "ОН н b. он Он Br C. Br 5.
- Problem 5.24 Draw a meso compound for each of the following molecules. CI a. Br- Br CI b.HO HO. с. NH2 H2NProblem 5.24 Draw a meso compound for each of the following molecules. a. Br CI Br b. HO OH c. H₂N NH₂Chemistry 5.66 A mixture contains equal amounts of compounds A-D. D B C A a. Which compounds alone are optically active? b. If the mixture was subjected to fractional distillation, how many fractions would be obtained? c. How many of these fractions would be optically active?
- Drawn are four isomeric dimethylcyclopropanes. A B C D a. How are the compounds in each pair related (enantiomers, diastereomers, constitutional isomers): A and B; A and C; B and C; C and D? b. Label each compound as chiral or achiral. c. Which compounds, alone, would be optically active? d. Which compounds have a plane of symmetry? e. f. g. How do the boiling points of the compounds in each pair compare: A and B; B and C; C and D? Which of the compounds are meso compounds? Would an equal mixture of compounds C and D be optically active? What about an equal mixture of B and C?Label each stereogenic center as R or S (parts d, e and f please)Label each stereogenic center as R or S (Questions a, b and c please)
- 5.50 Label each stereogenic center as R or S. I H а. NH2 b. CI c. Br I- H. O H,N H d. HO HO е. f. g. OH H. h. H2N Dage 217Drawn are four isomeric dimethylcyclopropane. a. How are the compounds in each pair related (enantiomers, diastereomers,constitutional isomers): A and B; A and C; B and C; C and D?b. Label each compound as chiral or achiral.c. Which compounds, alone, would be optically active?d. Which compounds have a plane of symmetry?e. Which of the compounds are meso compounds?f. Would an equal mixture of compounds C and D be optically active? Whatabout an equal mixture of B and C?g. How many stereogenic centers are there for each compound?Select the choice that best describes the relationship of the pair of compounds. .F F IF F. CH3 H The compounds are: enantiomers not isomeric constitutional isomers the same compound