please help I only have an hour left! The ratio of reactivity of tertiary:secondary:primary hydrogen atoms ina bromination reaction at 400 K is 1600:82:1.Using this information, calculate the percentage of 1-bromo-2-methylpropane that would be expected in a monochlorination reactionof of 2-methylpropane.ХаBrBr2hv%123☑Br456C789+/-0x10

Approach to Solving the Question:Determine the molecule's hydrogen type and quantity (primary,…

Answered: The ratio of reactivity of…

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter8: Haloalkanes, Halogenation, And Radical Reactions

Section: Chapter Questions

Problem 8.18P

See similar textbooks

Similar questions

(b) Predict the suitable solvent (H2O or CH3COCH3) to increase the reaction of bromopropane (CH3CH2CH2B1) with sodium hydroxide (NaOH). Two reactions are shown below: NaOH, 55 °C CH;CH,CH,Br CH;CH,CH,OH + NaBr H,O (i) NaOH, 55 °C CH;CH,CH,Br CH;CH,CH,OH NaBr H,C CH (ii)
2. For each of the chemical substitution reactions below identify the major products and whether the reaction is likely an SN1 or SN2. CN SN2 Br NACN ethanol-water NalN 0- Br CN CH,OH / H2O он но SNI Nal (1 equiv.) cl CI acetone SN2 SN' CH;CH,OH 25°C 3. For each of the following compounds provide appropriate reactants and solvent SN2 systems to synthesize them by a substitution reaction. Show which type of substitution: SN1 or Sn2. cannor undero Br NH2 Br NACN NH3 açetone CN ,2 can Br OH HBr SMper NASH Br DMSO -SH Nut SN nappiny
10:28 „9. A Shop D O ? 86%Ï AIATS For Two Year Medic. A 53 /180 02:56 hr min Mark for Review Products of the following reaction CH3 – CH = C- CH2 – CH3- (1) O2/ ether (i)Zn/H2O CH3 are CH3 – CH + CH3 -C-CH2 – CH3 CH — CH-HO— CH2 — CНз CH3 -C-CH3 +HC-CH2 – CH3 CH3 — С—СH, — СН, +НСH Clear Response II III
Reasoning from Hammond’s postulate, predict the regioselectivity of radical fluorination relative to that of radical chlorination and bromination.
Soft matter and interfacial chemistry:
(b) Predict the suitable solvent (H2O or CH3COCH:) to increase the reaction of bromopropane (CH3CH2CH2B1) with sodium hydroxide (NaOH). Two reactions are shown below: NaOH, 55 °C CH;CH,CH,Br CH;CH,CH,OH + + NaBr H,O (i) NaOH, 55 °C CH;CH,CH,Br CH;CH,CH,OH + NaBr (ii) H,C- CH3
Write down the common (not IUPAC) names of the organic molecules that would be released if this molecule were hydrolyzed: CH₂ E CH CH,−O O || 11 O -(CH₂)7-CH=CH-CH₂-CH=CH-CH₂-CH=CH-CH₂-CH3 (CH₂)7 -CH=CH-CH₂-CH=CH-CH₂-CH=CH-CH₂-CH3 -(CH₂)16-CH3 Separate each name with a comma. You will find useful information in the ALEKS Data resource. a × Y Ś
Comment on the difference between the enthalpy of combustion values of anthracene, napthalene, and phenathrene. delta H anthracene = -7063.8±5.3 kJ/mol delta H napthalene = -5160. ± 20. kJ/mol delta H phenanthrene is -7040. ± 30. kJ/mol
4G 08:44 The following presented reaction scheme lead to the synthesis of which major product from benzene, assuming separation of products is possible? So 1 HaOH Product CI Product HSO. 2 H,0 FeCl GA Meta-Chlorophenol U& para-ChloroSulfenic acid 4C Para Chiorophenol Da Meta-chloroaniline Add a caption... > Status (Custom)
10:29 0. O ? 86% AIATS For Two Year Medic. A 61 /180 (02:55 hr min Mark for Review When 2-Methylpropene undergoes oxidation in the presence of acidic K2Cr2O7, the products obtained are CH3 – CH + CO2 CH3 — СH — С—ОН-СО, CH, -C =0+CO2 +H2O CH3 CH; – CH2 – CH + CO2 + H20 Clear Response III
7. The reaction of methoxide anion with bromoethane to yield the ether ethyl methyl ether and the bromide anon (Br-) is an excellent example of a general reaction type called Sy2 (substitution nucleophilic bimolecular): CH,0+ CH,СH-Br a CH3-0-CH,СH; + Br- a. Change in enthalpy is -103 kJ/mol; the change in entropy is + 0.025 kJ/mol-K. Calculate DG at 300K. b. Is the reaction endergonic or exergonic? c. Is the reaction endothermic or exothermic? d. Use curved arrows to show the complete mechanism. Reaction of 2-methyl-1-butene with H-Cl could yield TWO alkyl chloride products. Draw and name 8. them.
Alkoxides R-O- can be used to synthesize alkenes as exemplified by the reaction shov below, where the symbol (et) indicates that the substance is dissolved in ethanol (CH;CH,OH) used as solvent: Br (1) + HO Br(et) (et) + (et) CH,CH,OH t-but-Br Ethoxide Isobutylene 9. The table to the right shows the results for the initial rate of this reaction when performed under different conditions (four different trials) at 25 °C. What is the rate law for this reaction? a) Rate = k [t-but-Br] b) Rate = k [t-but-Br] [ethoxide] c) Rate = k [t-but-Br]? d) Rate = k [ethoxide]? Trial Initial Initial Initial Rate (M/s) [t-but-Br] [Ethoxide] [isobutylene] 1 0.08 M 0.04 M 6.8 x 10-8 13.6 x 10-8 6.8 x 10-8 13.6 х 10-8 2 0.16 M 0.04 M 3 0.08 M 0.08 M 4 0.16 M 0.08 M

SEE MORE QUESTIONS

Recommended textbooks for you

Organic Chemistry

Chemistry

ISBN:

9781305580350

Author:

William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:

Cengage Learning

Organic Chemistry

Chemistry

ISBN:

9781305580350

Author:

William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:

Cengage Learning

SEE MORE TEXTBOOKS