Predict the major organic product of the reaction.H₂N.1 eq. Ac₂OOHSelect Draw Templates MoreC H NErase+ACO¯

Structure of the Major Organic Product: O || H3C-C-NH-C-C-OH | CH(CH3)2…

Answered: Predict the major organic product of…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution

Section16.SE: Something Extra

Problem 30MP: The carbocation electrophile in a Friede1-Crafts reaction can be generated by an alternate means...

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103. The major product formed in the following reaction sequence Me Me Me Me Me OMe OMe JE JE + + (a) (i) Hg(OAc)2, MeOH (ii) NaBH4, MeOH (c) Me OMe + Me OMe 'OMe (b) (d) Me ...OMe + Me 'OMe OMe
THE MECHANISM: Step 1: In aqueous acid, the first step is proton transfer to the carbon-carbon double bond. H BOH H Hydronium ion RCH₂ R' Conjugate acid of ketone 1-Hexyne draw structure... +RCH= SÖH Enol Step 2: The conjugate acid of the ketone transfers a proton from oxygen to a water molecule, yielding a ketone. ¹H- H + :0: R' H Water H :O: +RCH- H Water 1. R'₂BH 2. H₂O₂, NaOH RCH₂ Ketone R' R' H Conjugate acid of ketone +ÖH + Hexanal H H-O: H Hydronium ion H
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Predict the major organic product of the reaction. H₂N. 1 eq. Ac₂O OH Select Draw Templates More C H N Erase +ACO¯