Write the mechanism for all combinations ofreactions given in this handout (attached below).Include stereochemistry when possible. Write and AlkenesAlkenesReagents!HBrH3otHB5/ROOR, HydroborationMercurationH₂|ptBr2, Br/HeBrL/CH₂OHCH₂OH/H+, Dihydronylation

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Answered: Write the mechanism for all…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter13: Substitution

Section: Chapter Questions

Problem 8CTQ

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Draw structural formulas for all of the enol forms of the carbonyl compound below
3c）Referring to the intermediates you drew in problem below explain in detail why no meta product is obtained in the Friedel-Crafts alkylation of chlorobenzene. Draw all pertinent resonance structures to support your argument.
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d) In any Friedel-Crafts alkylation reaction starting with benzene and using one equivalent of the alkylating reagent, there is a always a small amount of disubstituted product which is formed. By contrast, such outcomes are not typically observed for any halogenation reactions starting from benzene and similarly using EAS chemistry. Please explain the basis for this apparent dichotomy.
(b) Discuss about the stability factors of the reaction intermediates, which involved in a name reaction "Wittig rearrangement".
3. For the following variants of the rearrangement reactions we have covered in class, propose a feasible step-by-step mechanism for each of them. (a) NaOMe MeOH
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Give detailed mechanism Solution with explanation needed...don't give Handwritten answer
[References] Draw the expected major organic product of the Sharpless epoxidation of each allylic alcohol using (-)-diethyl tartrate as the chiral catalyst. (a) (b) All hydrogen atoms are implied. If a chiral atom is attached to a hydrogen atom, you should not show the hydrogen atom but use either a wedge or a dashed bond. Apply formal charges where appropriate. Omit lone pairs and radical electrons from your answer. • Omit + signs between structures. ● HO O HO -OCH3 کر ? ChemDoodle Previous Next

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Write the mechanism for all combinations of reactions given in this handout (attached below). Include stereochemistry when possible. Write and Alkenes Alkenes Reagents! HBr H3ot HB5/ROOR, Hydroboration Mercuration H₂|pt Br2 , Br/He BrL/CH₂OH CH₂OH/H+, Dihydronylation