KProblem 21 of 24SubmitDraw the missing organic structuresin the following multistep synthesis.Show the final product atphysiological pH (pH = 7.4). Ignoreany inorganic byproducts formed.H0NH3Select toDrawHCNH+, H2OSelect toDrawSelect toDrawΔ

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Answered: K Problem 21 of 24 Submit Draw the…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter24: Amines And Heterocycles

Section24.SE: Something Extra

Problem 75AP

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I I I Draw the missing organic structures in the following multistep synthesis. Show all structures at physiological pH (pH = 7.4). Ignore any inorganic byproducts formed. H3N, (BOC)₂0 Et3N O Select to Draw O Q DCC + + H3N₁ ···||| O CH3OH, H+ Select to Draw I
1
Nitration of methyl benzoate: Weight of filler paper: 0.682g Mp product: 76-77 C Nitration of Acetanilide: Weight of filler paper: 0.691g Weight of filler paper product: 1.232g Mp product: 212-214 C Compound MM (g/mol) ortho mp (oC) meta mp (oC) para mp (oC) Nitroacetanilide 180.16 94 155 214-217 Methyl nitrobenzoate 181.15 -13 78-80 94-96 Theoretical yield of acetanilde: 0.6664g Theoretical yield of methyl benzoate: 0.7317g find theoretical yield of methyl nitrobenzoate percent yield of your methyl nitrobenzoate and melting point of your methyl nitrobenzoate
Isoleucine, another of the twenty amino acids found in proteins, is metabolized by a pathway that includes the following step. Propose a mechanism.
As far back as the 16th century, South American Incas chewed the leaves of the coca bush, Erythroxylon coca, to combat fatigue. Chemical studies of Erythroxylon coca by Friedrich WĂ¶hler in 1862 resulted in the discovery of cocaine, C17H21NO4, as the active component. Basic hydrolysis of cocaine leads to methanol, benzoic acid, and another compound called ecgonine, C9H15NO3. Oxidation of ecgonine with CrO3 yields a keto acid that readily loses CO2 on heating, giving tropinone. (a) What is a likely structure for the keto acid? (b) What is a likely structure for ecgonine, neglecting stereochemistry? (c) What is a likely structure for cocaine, neglecting stereochemistry?
Acid-catalyzed hydrolysis of a nitrile to give a carboxylic acid occurs by initial protonation of the nitrogen atom, followed by nucleophilic addition of water. Review the mechanism of base-catalyzed nitrile hydrolysis in Section 20-7 and then predict the products for each reaction below and write all of the steps involved in the acid-catalyzed reaction, using curved arrows to represent electron flow in each step.
1) CO2 (s) g) Ph(CH:)MgBr 2) 11 (aq) H'(aq)/A h) 6-Bromohexanoic Acid + NACN- 1) NaOEt/ELOH i) PhCOHC-CH2 + CH:(CO Et) 2) H (aq), A,-CO. Butanoic Acid 1 equivalent Bry/P H.NEt k) Methyl Benzoate NaOMe/MEOHI I) 2 (Ph) CHCOOME -
conjugate base acid Consider the reaction AH + H2O 5 A: + H3O+. For the following named acids: a) draw the structure of the acid, b) give the approximate pKa value of the acid in multiples of 5, and c) draw the structure of the conjugate base. pKa sec-Butyl ammonium ion Cyclohexanone pKa iso-Butyl alcohol pKa N-ethylcarbamic acid pKa
Describe the reaction to form the catalyst L-prolinamide. (reaction is added below) .
Heating compound X with aqueous formaldehyde forms Y (C17H23NO), which has been converted to a mixture of lupinine and epilupinine, alkaloids isolated from lupin, a perennial ornamental plant commonly seen on the roadside in parts of Alaska. Identify Y and explain how it is formed. HO но CH=0 one step NH2 C,,H23NO lupinine epilupinine Ph
i just want an answer in #6
Write complete mechanisms for the Reactions Below Need answer step by step

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K Problem 21 of 24 Submit Draw the missing organic structures in the following multistep synthesis. Show the final product at physiological pH (pH = 7.4). Ignore any inorganic byproducts formed. H 0 NH3 Select to Draw HCN H+, H2O Select to Draw Select to Draw Δ