Scientists have suggested two different mechanisms for the same reaction. The elementary steps foreach suggestion are shown below:Proposal 1) (1) 2 A → C (2) C + D → A + B  Proposal 2)(1) 2 A + E → A2(2) A2 + D → A + B + E A) What is the overall balanced equation for this reaction? B) What is (are) the intermediate(s) in this reaction? Proposal 1) Proposal 2)C) What is the predicted rate law for proposal 1, elementary step 1? D) What is the predicted rate law for proposal 1, elementary step 2? E) What is the predicted rate law for proposal 2, elementary step 1? F) What is the predicted rate law for proposal 2, elementary step 2? G) If the observed rate law for this reaction was found to be Rate = k [A]2, which proposal is correct and whichstep is the slow step?

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 75GQ
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Scientists have suggested two different mechanisms for the same reaction. The elementary steps for
each suggestion are shown below:
Proposal 1) 
(1) 2 A → C 
(2) C + D → A + B 

Proposal 2)
(1) 2 A + E → A2
(2) A2 + D → A + B + E

A) What is the overall balanced equation for this reaction?

B) What is (are) the intermediate(s) in this reaction?

Proposal 1) Proposal 2)
C) What is the predicted rate law for proposal 1, elementary step 1?

D) What is the predicted rate law for proposal 1, elementary step 2?

E) What is the predicted rate law for proposal 2, elementary step 1?

F) What is the predicted rate law for proposal 2, elementary step 2?

G) If the observed rate law for this reaction was found to be Rate = k [A]2, which proposal is correct and which
step is the slow step?

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