© Macmillan Learning95DECHhGlycolysis intermediateOther compound2-H-C-O-PO3C=OHO-C-HHHO.-CH2OHOHMAnswer Banka five-carbon phosphorylated compoundCooCH₂MacBook ProfructoseResources203PO,-20₂ PO-CH₂H₂C-OPOO-OHOHOHA00Σ

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Answered: © Macmillan Learning 95 DEC H h…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter21: Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions

Section21.SE: Something Extra

Problem 41MP

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Q2 CH,OH CH,OPO,2- H H OH H OH 0-PO,2- но но OH H. OH OH Glucose-1-phosphate Glucose-6-phosphate Calculate the standard free-energy change (AG°) fo the reaction catalyzed by the enzyme phosphoglucomutase. When at standard temperature (25 °C) and pressure, the equilibrium of each molecule is 1 mM glucose 1-phosphate and 19 mM glucose 6-phosphate. HINT: at 25 °C, RT = 2.479 kJ/mol
(H) = Na2CO3' H₂O
H-C -OH CH₂OPO₂²- 3-phosphoglycerate ATP ADP Arrow-pushing Instructions AC XT H-C-OH :O: CH₂OPO3²- =C² H-C-OH -O OPO3² Enz-SH 3 CH₂OPO3²- 1,3-bisphosphoglycerate ADP PO S-Enz H-C-OH CH₂OPO3²- One step in the gluconeogenesis pathway for the biosynthesis of glucose is the partial reduction of 3-phosphoglycerate to give glyceraldehyde 3-phosphate. The process occurs by phosphorylation with ATP to give 1,3-bisphosphoglycerate, reaction with a thiol group on the enzyme to give an enzyme-bound thioester, and reduction with NADH. Draw curved arrows to show the movement of electrons in this step of the reaction mechanism. [Enzyme-bound thioester] NADH/H* NAD*, Enz-SH H H-C-OH CH₂OPO3²- Glyceraldehyde 3-phosphate :Ö: H-C-OH CH₂OPO3²- ADP 29
wtgers Whch y hde in pntace to ac the futs by the Syt mechariount 5888
Isomerization of glucose 1-phosphate to glucose 6-phosphate is energetically favorable. At 37°&delta G° = –1.42 log10K deltaG° = –1.74 kcal/mole at 37°C?
Isoleucine, another of the twenty amino acids found in proteins, is metabolized by a pathway that includes the following step. Propose a mechanism.
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The dynamic process by which both forms of a- and B-D-glucopyranose in solution change slowly into an equilibrium mixture of both is known as (choose the name). OH OH Но но НО HO OH OH OH OH a-D-glucopyranose 36% B-D-glucopyranose 64% OA Acetylation O B. Enediol Rearrangement OC Mutarotation O D. Acetal Formation O E Epimerization
Acetolactate synthase transfers the acyl group of pyruvate to alpha-ketobutyrate. This is the first step in the biosynthesis of the amino acid isoleucine. Propose a mechanism for this reaction.
The following molecule has a glycosidic bond that is best described as HỌ – CH2 НО HỌ – CH2 HO OH O ОН alpha-1,4-glycosidic bond beta-1,6-glycosidic band alpha-1,6-glycosidic bond beta-1,4-glycosidic bond ОН OH OH.H2O
Macmillan Learning X Chapter 12 HW - General, Organic, and E Ubiquinone, or coenzyme Q, is an electron acceptor in the electron transport chain. H3CO. CH3 (CH2CH=C-CH2)10H H3CO ubiquinone CH3 Modify the molecule so that it represents the reduced form of ubiquinone. You may need to add or remove atoms or bonds. Let the letter X represent the (CH2CH=C(CH3)CH2)10H group. Select / Draw Templates Groups More C 0 H о 0 Erase Q2Q
Identify the products of the two reactions of glucose. COOH HOH Н НО H Н HOH Н- -OH CH₂OH Н НО CH2OH -OH H- H -Н -OH OH CH₂OH Cu2+/OH- CHO O НО н H OH H-+ -OH CH₂OH Н но- Н- Н- CHO HOH но- Н- -Н -ОН H-OH CHO CHO -ОН -Н -ОН -ОН CH2OH Answer Bank 0 CH3 H— НО -OH -H H-OH H-OH CH₂OH H₂/Pt CHO H-OH HO-H H -ОН H OH COOH CH₂OH =0 HO-H H- Н -ОН -OH CH₂OH

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© Macmillan Learning 95 DEC H h Glycolysis intermediate Other compound 2- H-C-O-PO3 C=O HO-C-H H HO. -CH2 OH OH M Answer Bank a five-carbon phosphorylated compound Coo CH₂ MacBook Pro fructose Resources 203PO, -20₂ PO-CH₂ H₂C-OPO O-OH OH OH A 00 Σ