Write structure, in line or condensed notation, for the major products) of the following reactions (include stereochemistry where appropriate): Br2 H₂O
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- Predict the products of halogenations, oxidations, reductions, and cleavages of alkenes, including the orientation (regiochemistry) and the stereochemistry of the reaction.Na, NH3 H3C-C=C-CH3 CH3 H3C° Alkynes are reduced to trans alkenes by a process called dissolving metal reduction. The reaction uses sodium or lithium metal as the reducing agent and liquid ammonia as the solvent. The method is specific in the formation of trans alkenes from alkynes. The method involves two successive transfers of single electrons from the alkali metal to the triple bond, with abstraction of protons from the ammonia solvent. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions .CH3 H-NH2 CH3 :NH2 H3C H3C(d) EtO 1. Name each compound, showing stereochemistry where relevant: (a) Ph Ph (b) CH3(CH2);CN (c) NHCH, (d) EtO OEt (e) CI Cl
- (b) Calculate the pH of 0.0005 mol dm-3 ethanois acid when its pKa = 4.75 CH;COOH() -> CH;COO (a H(a + Ka = pH =Which type of reaction – addition, elimination, rearrangement, substitution,- best describes each of the following? OLi (a) MeLi (b) Me2NOH (c) (d) H2O -OH +Draw the structure of the predominant form of CF3CH2OH (pK a = 12.4) at pH = 6.
- (a) (b) HO N N-H Catalytic H+ (-H₂O) ? (c) NH2 HO N (d)An unknown hydrocarbon Q has a formula C6H12. Q reacts with osmium tetroxide to give a diol R when oxidized with KMnQ4 in an acidic medium Q gives two products. One product is propanoic acid and the other is ketone S. Provide reaction equations to identify the possible structures of Q, R and S.The rate law for addition of Br2 to an alkene is first orderin Br2 and first order in the alkene. Does this informationsuggest that the mechanism of addition of Br2 to analkene proceeds in the same manner as for addition of HBr?Explain.
- (b) (1-chloromethyl)cyclopentane, CeH11CI reacts with aqueous sodium hydroxide, NaOH to produce a primary alcohol AA. When CeH11Cl is added with magnesium, Mg in ether, an organometallic compound BB is formed. When compound BB reacts with ethanal, CH3CHO, a secondary alcohol cCis formed. The molecular structure of CeH11Cl is given below. (1-klorometil)siklopentana, CoH1,CI bertindak balas dengan akues natrium hidroksida, NaOH bagi menghasilkan satu alkohol primer AA. Apabila CeH11CI ditambah dengan magnesium, Mg dalam eter, sebatian organologam BB terbentuk. Apabila sebatian BB bertindak balas dengan etanal, CH;CHO, satu alkohol sekunder CC dihasilkan. Struktur molekul bagi CsH11CI diberikan di bawah. .CI (1-chloromethyl)cyclopentane (i) Draw the structural formula for compound AA through Cc. Lukiskan formula struktur bagi sebatian AA sehingga C. (ii) What is the type of reaction to produce compound AA? Apakah jenis tindak balas untuk menghasilkan sebatian AA?4. Propose structures for alkenes that yield the following products on treatment with acidic KMnO4: (a) (CH3)2C=0 + CO2 (b) 2 equiv CH3CH2CO2H 5. Show the structure of Teflon by drawing several repeating units. The monomer unit is tetrafluoroethylene, F2C=CF2. 6. Draw resonance structures for the following species: (a) CH2 + (b) H. :0: (c) H. H HPredict the products of additions, oxidations, reductions, and cleavages of alkynes, including the orientation of the reaction (regiochemistry) and the stereochemistry.