Write structure, in line or condensed notation, for the major products) of the following reactions (include stereochemistry where appropriate): Br2 H₂O
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- Which type of reaction – addition, elimination, rearrangement, substitution,- best describes each of the following? OLi (а) MeLi + Me H (Б) Me2NOH + (c) to (d) H2O -ОН +Predict the products of halogenations, oxidations, reductions, and cleavages of alkenes, including the orientation (regiochemistry) and the stereochemistry of the reaction.Write the structures of the following organic halogen compounds :(i) 4-tert-Butyl-3-iodoheptane(ii) 4-Bromo-3-methylpent-2-ene
- (d) EtO 1. Name each compound, showing stereochemistry where relevant: (a) Ph Ph (b) CH3(CH2);CN (c) NHCH, (d) EtO OEt (e) CI ClCompounds with more than one hydroxyl group can react with thionyl chloride differently from simple alcohols. In the reaction with thionyl chloride, the butane-1,2-diol gave a single organic product with 85% yield, according to the following balanced equation: (Suggest a reasonable structure for this product and make a mechanism to justify your reasoning using curved arrows to describe the motion of electrons)(b) Calculate the pH of 0.0005 mol dm-3 ethanois acid when its pKa = 4.75 CH;COOH() -> CH;COO (a H(a + Ka = pH =
- Which type of reaction – addition, elimination, rearrangement, substitution,- best describes each of the following? OLi (a) MeLi (b) Me2NOH (c) (d) H2O -OH +Which of the following is true for the reactions of alkyl halides? (a) The characteristic reactions of alkyl halides are oxidation and reduction.(b) The characteristic reactions of alkyl halides are elimination and substitutionc. The characteristic reactions of alkyl halides are addition and substitutiond. Characteristic reactions of alkyl halides are addition and elimination.Draw the structure of the predominant form of CF3CH2OH (pK a = 12.4) at pH = 6.
- (A) what is the hybridization of the nitrogen in each of the following compounds? (B) how does hybridization affect the availability of the lone pair and the basicity of each compound?The compound whose structure is shown here is acetyl acetone. It exists in two forms:the enol form and the keto form The molecule reacts with OH–to form an anion, [CH3COCHCOCH3] (often abbreviatedacac–for acetylacetonate ion). One or the most interesting aspects of this anion is thatone or more of them can react with transition metal cations to give stable, highlycolored compounds (a) Are the keto and enol forms of acetylacetone resonance forms? Explain youranswer.(b) What is the hybridization or each atom (except H) in the enol form? What changesin hybridization occur when it is transformed into the keto form?(c) What are the electron-pair geometry and molecular geometry around each C atomin the keto and enol forms? What changes in geometry occur when the keto formchanges to the enol form?(d) Draw three possible resonance structures for the acac–ion.(e) Is cis-trans isomerism possible in either the enol or the keto form of acetylacetone?(f) Is the enol form of acetylacetone polar?…. Predict the products of the following reactions. When more than one product is expected, predict which will be the major product?